Citation: CHEN Qi-Hao, JING Zhao-Yang, SONG You. Magnetostructural Correlation and Antisymmetric Exchange of Spin Frustrated Triangular [Cu₃] in Zero-Dimensional and Three-Dimensional Structure[J]. Chinese Journal of Inorganic Chemistry, ;2020, 36(4): 659-665. doi: 10.11862/CJIC.2020.066 shu

Magnetostructural Correlation and Antisymmetric Exchange of Spin Frustrated Triangular [Cu₃] in Zero-Dimensional and Three-Dimensional Structure

State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210023, China

Corresponding author: JING Zhao-Yang, MF1724017@smail.nju.edu.cn
Received Date: 24 September 2019
Revised Date: 12 November 2019

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Quantum spin liquids are the third type of magnetism that has just been confirmed in recent years besides ferromagnets and antiferromagnets. They have attracted much attention in the fields of physics and materials because they are expected to explain the mechanism of high temperature superconductors and to change the storage mode of computer hard disk information. Spin frustration, as the smallest unit of quantum spin liquids, may be the key to solve many problems of quantum spin liquids. Based on the reported three-nuclear copper complexes, [Cu₃(μ₃-OH)(μ-OPz)₃(NO₃)₂(H₂O)₂]·CH₃OH (1) (HOPz=methyl(2-pyrazinyl)ketone oxime), we synthesized a three-dimensional metal-organic framework (MOF), {[Ag(HOPz)Cu₃(μ₃-OH)(NO₃)₃(OPz)₂Ag(NO₃)]·6H₂O]}_n (2). Their magnetic properties were analyzed in detail from the perspective of spin frustration by comparison. The magnetic studies indicate that there exists a strong antiferromagnetic interactions between spins and antisymmetric exchanges. The magnetic data are fitted and the magnetostructural correlation is studied by Hamiltonian containing isotropic and antisymmetric exchanges. The best fitting parameters obtained are:J_av=-426 cm^-1, g_⊥=1.83, g_//=2.00 for 1 and J_av=-401 cm^-1, g_⊥=1.85, g_//=2.00 for 2.
- antisymmetric exchange,
- copper,
- magnetic properties,
- spin frustration,
- triangular clusters
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Magnetostructural Correlation and Antisymmetric Exchange of Spin Frustrated Triangular [Cu3] in Zero-Dimensional and Three-Dimensional Structure

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通讯作者: 陈斌, bchen63@163.com

Magnetostructural Correlation and Antisymmetric Exchange of Spin Frustrated Triangular [Cu₃] in Zero-Dimensional and Three-Dimensional Structure