Citation: MA Kai, LIN Ning. Three-Dimensional Porous Carbon Prepared by Molten Salt Zinc-Thermal Method as Anode for High Performance Potassium Ion Batteries[J]. Chinese Journal of Inorganic Chemistry, ;2020, 36(3): 415-420. doi: 10.11862/CJIC.2020.058 shu

Three-Dimensional Porous Carbon Prepared by Molten Salt Zinc-Thermal Method as Anode for High Performance Potassium Ion Batteries

MA Kai ,
LIN Ning ^,

School of Chemistry and Materials Science, University of Science and Technology of China, Hefei 230026, China

Corresponding author: LIN Ning, ningl@mail.ustc.edu.cn
Received Date: 1 July 2019
Revised Date: 24 September 2019

Figures(4)

Three-dimensional (3D) porous carbon materials are successfully prepared by molten salt zinc-thermal method using sucrose as precursor and used as anode materials for potassium ion batteries. The prepared 3D porous carbon has a large number of interconnected channels, which can effectively alleviate the volume effect of the electrode during the charge-discharge cycling process, improve the infiltration of electrolyte to the electrode, shorten the diffusion path of K⁺. Therefore, it shows excellent cycle stability and rate performance. 3D porous carbon electrode delivers the specific capacity of 174.6 mAh·g^-1 after 2 500 cycles at current density of 0.5 A·g^-1 and 170 mAh·g^-1 at a high rate of 4.4 A·g^-1.
- zinc-thermal,
- 3D porous carbon,
- rate performance,
- cycle stability,
- potassium ion batteries
1. [1]
  Wu X, Leonard D P, Ji X. Chem. Mater., 2017, 29(12):5031- 5042 doi: 10.1021/acs.chemmater.7b01764
2. [2]
  Bie X, Kubota K, Hosaka T, et al. J. Mater. Chem. A, 2017, 5(9):4325-4330 doi: 10.1039/C7TA00220C
3. [3]
  Komaba S, Hasegawa T, Dahbi M, et al. Electrochem. Commun., 2015, 60:172-175 doi: 10.1016/j.elecom.2015.09.002
4. [4]
  Li H, Wang Z, Chen L, et al.Adv.Mater., 2009, 21(45):4593- 4607 doi: 10.1002/adma.200901710
5. [5]
  Nagaura T, Tozawa K. Progress in Batteries & Solar Cells. Brunswick: JEC Press, 1990:209
6. [6]
  Nishi Y.. Chem. Rec., 2001, 1(5):406-413 doi: 10.1002/tcr.1024
7. [7]
  Li T, Lin N, Han Y, et al. ACS Appl. Mater. Interfaces, 2018, 10(49):42469-42474 doi: 10.1021/acsami.8b16481
8. [8]
  Yi Z, Qian Y, Tian J, et al. J. Mater. Chem. A, 2019, 7(19): 12283-12291 doi: 10.1039/C9TA02204J
9. [9]
  Jian Z, Luo W, Ji X.. J. Am. Chem. Soc., 2015, 137(36):11566- 11569 doi: 10.1021/jacs.5b06809
10. [10]
  Yan K, Lu Z, Lee H W, et al. Nat. Energy, 2016, 1(3):16010 doi: 10.1038/nenergy.2016.10
11. [11]
  Luo W, Wan J, Ozdemir B, et al. Nano Lett., 2015, 15(11): 7671-7677 doi: 10.1021/acs.nanolett.5b03667
12. [12]
  Xing Z, Qi Y, Jian Z, et al. ACS Appl. Mater. Interfaces, 2016, 9(5):4343-4351
13. [13]
  Jian Z, Hwang S, Li Z, et al. Adv. Funct. Mater., 2017, 27 (26):1700324 doi: 10.1002/adfm.201700324
14. [14]
  Yi Z, Wang W, Qian Y, et al. ACS Sustainable Chem. Eng., 2018, 6(11):14230-14238 doi: 10.1021/acssuschemeng.8b02880
15. [15]
  Li Y, Jiang S, Qian Y, et al. Chem. Commun., 2019, 55(47): 6751-6754 doi: 10.1039/C9CC02971K
16. [16]
  Li W H, Ning Q L, Xi X T, et al. Adv. Mater., 2019, 31(4): 1804766 doi: 10.1002/adma.201804766
17. [17]
  Wang Y Y, Hou B H, Ning Q L, et al. Nanotechnology, 2019, 30(21):214002 doi: 10.1088/1361-6528/ab043a
18. [18]
  Wang P, Ye H, Yin Y X, et al. Adv. Mater., 2019, 31(4): 1805134 doi: 10.1002/adma.201805134
19. [19]
  Xiong P, Zhao X, Xu Y.. ChemSusChem, 2018, 11(1):202-208 doi: 10.1002/cssc.201701759
20. [20]
  Liu D, Huang X, Qu D, et al. Nano Energy, 2018, 52:1-10 doi: 10.1016/j.nanoen.2018.07.023
21. [21]
  Chen C, Wang Z, Zhang B, et al. Energy Storage Mater., 2017, 8:161-168 doi: 10.1016/j.ensm.2017.05.010
22. [22]
  Wang J, Polleux J, Lim J, et al. J. Phys. Chem. C, 2007, 111 (40):14925-14931 doi: 10.1021/jp074464w
23. [23]
  Conway B E, Birss V, Wojtowicz J. J. Power Sources, 1997, 66(1/2):1-14
24. [24]
  Li P, Hwang J Y, Park S M, et al. J. Mater. Chem. A, 2018, 6(26):12551-12558 doi: 10.1039/C8TA03340D
1. [1]
  Jianbao Mei , Bei Li , Shu Zhang , Dongdong Xiao , Pu Hu , Geng Zhang . Enhanced Performance of Ternary NASICON-Type Na_3.5-xMn_0.5V_1.5-xZr_x(PO₄)₃/C Cathodes for Sodium-Ion Batteries. Acta Physico-Chimica Sinica, 2024, 40(12): 2407023-. doi: 10.3866/PKU.WHXB202407023
2. [2]
  Zhuo WANG , Xiaotong LI , Zhipeng HU , Junqiao PAN . Three-dimensional porous carbon decorated with nano bismuth particles: Preparation and sodium storage properties. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 267-274. doi: 10.11862/CJIC.20240223
3. [3]
  Huayan Liu , Yifei Chen , Mengzhao Yang , Jiajun Gu . Strategies for enhancing capacity and rate performance of two-dimensional material-based supercapacitors. Acta Physico-Chimica Sinica, 2025, 41(6): 100063-. doi: 10.1016/j.actphy.2025.100063
4. [4]
  Jie WU , Zhihong LUO , Xiaoli CHEN , Fangfang XIONG , Li CHEN , Biao ZHANG , Bin SHI , Quansheng OUYANG , Jiaojing SHAO . Critical roles of AlPO₄ coating in enhancing cycling stability and rate capability of high voltage LiNi_0.5Mn_1.5O₄ cathode materials. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 948-958. doi: 10.11862/CJIC.20240400
5. [5]
  Xuyang Wang , Jiapei Zhang , Lirui Zhao , Xiaowen Xu , Guizheng Zou , Bin Zhang . Theoretical Study on the Structure and Stability of Copper-Ammonia Coordination Ions. University Chemistry, 2024, 39(3): 384-389. doi: 10.3866/PKU.DXHX202309065
6. [6]
  Xiaoning TANG , Junnan LIU , Xingfu YANG , Jie LEI , Qiuyang LUO , Shu XIA , An XUE . Effect of sodium alginate-sodium carboxymethylcellulose gel layer on the stability of Zn anodes. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1452-1460. doi: 10.11862/CJIC.20240191
7. [7]
  Doudou Qin , Junyang Ding , Chu Liang , Qian Liu , Ligang Feng , Yang Luo , Guangzhi Hu , Jun Luo , Xijun Liu . Addressing Challenges and Enhancing Performance of Manganese-based Cathode Materials in Aqueous Zinc-Ion Batteries. Acta Physico-Chimica Sinica, 2024, 40(10): 2310034-. doi: 10.3866/PKU.WHXB202310034
8. [8]
  Yingtong Shi , Guotong Xu , Guizeng Liang , Di Lan , Siyuan Zhang , Yanru Wang , Daohao Li , Guanglei Wu . PEG-VN改性PP隔膜用于高稳定性高效率锂硫电池. Acta Physico-Chimica Sinica, 2025, 41(7): 100082-. doi: 10.1016/j.actphy.2025.100082
9. [9]
  Xiaoning TANG , Shu XIA , Jie LEI , Xingfu YANG , Qiuyang LUO , Junnan LIU , An XUE . Fluorine-doped MnO₂ with oxygen vacancy for stabilizing Zn-ion batteries. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1671-1678. doi: 10.11862/CJIC.20240149
10. [10]
  Qinjin DAI , Shan FAN , Pengyang FAN , Xiaoying ZHENG , Wei DONG , Mengxue WANG , Yong ZHANG . Performance of oxygen vacancy-rich V-doped MnO₂ for high-performance aqueous zinc ion battery. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 453-460. doi: 10.11862/CJIC.20240326
11. [11]
  Mingxuan Qi , Lanyu Jin , Honghe Yao , Zipeng Xu , Teng Cheng , Qi Chen , Cheng Zhu , Yang Bai . 钙钛矿太阳能电池在反向偏压下的电学失效及稳定性研究进展. Acta Physico-Chimica Sinica, 2025, 41(8): 100088-. doi: 10.1016/j.actphy.2025.100088
12. [12]
  Pengyang FAN , Shan FAN , Qinjin DAI , Xiaoying ZHENG , Wei DONG , Mengxue WANG , Xiaoxiao HUANG , Yong ZHANG . Preparation and performance of rich 1T-MoS₂ nanosheets for high-performance aqueous zinc ion battery cathode materials. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 675-682. doi: 10.11862/CJIC.20240339
13. [13]
  Xuewei BA , Cheng CHENG , Huaikang ZHANG , Deqing ZHANG , Shuhua LI . Preparation and luminescent performance of Sr_1-xZrSi₂O₇∶xDy³⁺ phosphor with high thermal stability. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 357-364. doi: 10.11862/CJIC.20240096
14. [14]
  Zeyi Yan , Ruitao Liu , Xinyu Qi , Yuxiang Zhang , Lulu Sun , Xiangyuan Li , Anchao Feng . Exploration of Suspension Polymerization: Preparation and Fluorescence Stability of Perovskite Polystyrene Microbeads. University Chemistry, 2025, 40(4): 72-79. doi: 10.12461/PKU.DXHX202405110
15. [15]
  Ruiqing LIU , Wenxiu LIU , Kun XIE , Yiran LIU , Hui CHENG , Xiaoyu WANG , Chenxu TIAN , Xiujing LIN , Xiaomiao FENG . Three-dimensional porous titanium nitride as a highly efficient sulfur host. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 867-876. doi: 10.11862/CJIC.20230441
16. [16]
  Yang LIU , Lijun WANG , Hongyu WANG , Zhidong CHEN , Lin SUN . Surface and interface modification of porous silicon anodes in lithium-ion batteries by the introduction of heterogeneous atoms and hybrid encapsulation. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 773-785. doi: 10.11862/CJIC.20250015
17. [17]
  Fengqiao Bi , Jun Wang , Dongmei Yang . Specialized Experimental Design for Chemistry Majors in the Context of “Dual Carbon”: Taking the Assembly and Performance Evaluation of Zinc-Air Fuel Batteries as an Example. University Chemistry, 2024, 39(4): 198-205. doi: 10.3866/PKU.DXHX202311069
18. [18]
  Qingtang ZHANG , Xiaoyu WU , Zheng WANG , Xiaomei WANG . Performance of nano Li₂FeSiO₄/C cathode material co-doped by potassium and chlorine ions. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1689-1696. doi: 10.11862/CJIC.20240115
19. [19]
  Shitao Fu , Jianming Zhang , Cancan Cao , Zhihui Wang , Chaoran Qin , Jian Zhang , Hui Xiong . Study on the Stability of Purple Cabbage Pigment. University Chemistry, 2024, 39(4): 367-372. doi: 10.3866/PKU.DXHX202401059
20. [20]
  Zhaoxuan ZHU , Lixin WANG , Xiaoning TANG , Long LI , Yan SHI , Jiaojing SHAO . Application of poly(vinyl alcohol) conductive hydrogel electrolytes in zinc ion batteries. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 893-902. doi: 10.11862/CJIC.20240368

Get Citation

PDF

XML

Metrics

PDF Downloads(12)
Abstract views(713)
HTML views(141)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142