Citation: LI Yu, ZHAO Zhen-Yu, ZOU Xun-Zhong, FENG An-Sheng, GU Jin-Zhong. Syntheses, Crystal Structures, Luminescent and Magnetic Properties of 2D Manganese(Ⅱ) and Zinc(Ⅱ) Coordination Polymers Based on an Ether-Bridged Tetracarboxylic Acid[J]. Chinese Journal of Inorganic Chemistry, ;2020, 36(2): 377-384. doi: 10.11862/CJIC.2020.042 shu

Syntheses, Crystal Structures, Luminescent and Magnetic Properties of 2D Manganese(Ⅱ) and Zinc(Ⅱ) Coordination Polymers Based on an Ether-Bridged Tetracarboxylic Acid

1.
Guangdong Research Center for Special Building Materials and Its Green Preparation Technology/Foshan Research Center for Special Functional Building Materials and Its Green Preparation Technology, Guangdong Industry Polytechnic, Guangzhou 510300, China
2.
School of Intelligent Manufacturing and Equipment, Shenzhen Institute of Information Technology, Shenzhen, Guangdong 518172, China
3.
College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou 730000, China

Corresponding author: ZHAO Zhen-Yu, gujzh@lzu.edu.cn GU Jin-Zhong, yxpzzy01@163.com
Received Date: 26 July 2019
Revised Date: 6 November 2019

Figures(10)

Two 2D manganese(Ⅱ) and zinic(Ⅱ) coordination polymers, namely {[Mn₂(μ₆-L)(phen)₂]·5H₂O}_n (1) and {[Zn₂(μ₇-L)(py)]·H₂O}_n (2), have been constructed hydrothermally using H₄L (H₄L=3, 3', 4, 5'-diphenyl ether tetra-carboxylic acid), phen (phen=1, 10-phenanthroline), py (py=pyridine), and manganese or zinc chlorides. Single-crystal X-ray diffraction analyses revealed that two complexes crystallize in the triclinic or monoclinic systems, space groups P1 or I2/a. Both complexes feature a 2D sheet structure based on Mn₄ or Zn₂ subunits. The luminescent and magnetic properties for two complexes were also investigated. The results of fluorescence and magnetic studies show that complex 2 can emit blue fluorescence at room temperature, and antiferromagnetic interactions exist between adjacent Mn(Ⅱ) ions in polymer 1.
- coordination polymer,
- ether-bridged tetracarboxylic acid,
- luminescent properties,
- magnetic properties
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沈阳化工大学材料科学与工程学院沈阳 110142