Citation: XIONG Wen-Xu, ZHANG Xue-Qian, HUANG Wei-Wei. Preparation of Cathode Composites Pillar[5]quinone/CMK-3 for High-Capacity Lithium-Ion Batteries[J]. Chinese Journal of Inorganic Chemistry, ;2020, 36(2): 269-275. doi: 10.11862/CJIC.2020.033 shu

Preparation of Cathode Composites Pillar[5]quinone/CMK-3 for High-Capacity Lithium-Ion Batteries

1.
School of Environmental and Chemical Engineering, Yanshan University, Qinhuangdao, Hebei 066004, China
2.
State Key Laboratory of Metastable Materials Science and Technology, Yanshan University, Qinhuangdao, Hebei 066004, China

Corresponding author: HUANG Wei-Wei, huangweiwei@ysu.edu.cn
Received Date: 29 July 2019
Revised Date: 9 December 2019

Figures(8)

Quinone compound called pillar[5]quinone (P5Q) was chosen as cathode to explore lithium storage performance. Experimental data indicated that the initial capacity reached 431 mAh·g^-1, displaying 100% utilization rate of active sites. Nevertheless, P5Q was easily dissolved when exposed to the electrolyte, which resulted in rapid decay of capacity. For addressing this issue, encapsulation method was employed. We chose CMK-3 as porous carbon material in this study for its uniform pores and moderate pore size. Herein, P5Q was filled into the holes of CMK-3, and then obtaining the P5Q/CMK-3 nanocomposites. The experiment results showed that the pouring method effectively slowed the dissolution of P5Q in electrolyte. After 100 cycles, the discharge capacity of P5Q/CMK-3 composites maintained at 300 mAh·g^-1, the retention was as high as 71%, and coulombic efficiency was around 100% during the test period.
- pillar[5]quinone,
- immobilization,
- lithium-ion battery,
- high capacity
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沈阳化工大学材料科学与工程学院沈阳 110142