Citation: YANG Qing-Xiang, LEI Li-Ling, WANG Qing-Qing, WANG Fang-Cao, WANG Cong, DONG Meng-Guo, LI Yin-Ping, CHEN Zhi-Jun. Synthesis and Catalytic Performance for Oxidative Cyclization Reaction of Oil-Dispersible Core-Shell Fe₃O₄@MnO Nanocomposites[J]. Chinese Journal of Inorganic Chemistry, ;2020, 36(2): 385-391. doi: 10.11862/CJIC.2020.032 shu

Synthesis and Catalytic Performance for Oxidative Cyclization Reaction of Oil-Dispersible Core-Shell Fe₃O₄@MnO Nanocomposites

School of Material and Chemical Engineering, Henan Provincial Key Laboratory of Surface and Interface Science, Zhengzhou University of Light Industry, Zhengzhou 450002, China

Corresponding author: CHEN Zhi-Jun, chenzj@zzuli.edu.cn
Received Date: 20 August 2019
Revised Date: 9 December 2019

Figures(6)

A new type oil-soluble core-shell structure Fe₃O₄@MnO nanocomposites with diameter about 15 nm was prepared through two-phase seed mediate method with Mn-oleate precursors. The as-prepared nanocomposites with core-shell structure were monodispersed and uniform. The products exhibited high and recyclable catalytic activity for the oxidative cyclization reaction of 2-hydroxyacetophenone and 1, 2-diaminobenzene. Compared with other reported catalysts used in this kind of cyclization reaction, the as-prepared Fe₃O₄@MnO nanocomposites are green, cheap and more suitable for large scale industrial applications.
- Fe₃O₄@MnO,
- nanocomposite,
- magnetic materials,
- oil-dispersible,
- oxidative cyclization reaction,
- catalytic
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沈阳化工大学材料科学与工程学院沈阳 110142

Synthesis and Catalytic Performance for Oxidative Cyclization Reaction of Oil-Dispersible Core-Shell Fe3O4@MnO Nanocomposites

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通讯作者: 陈斌, bchen63@163.com

Synthesis and Catalytic Performance for Oxidative Cyclization Reaction of Oil-Dispersible Core-Shell Fe₃O₄@MnO Nanocomposites