Citation: ZHANG Qi-Long, WANG Jia-Zhong, YANG Xiao-Sheng, ZHU Bi-Xue. Synthesis and Crystal Structure of Ni(Ⅱ)/Cu(Ⅱ)/Mn(Ⅲ) Complexes with Asymmetric Salen Ligand[J]. Chinese Journal of Inorganic Chemistry, ;2020, 36(1): 132-138. doi: 10.11862/CJIC.2020.030 shu

Synthesis and Crystal Structure of Ni(Ⅱ)/Cu(Ⅱ)/Mn(Ⅲ) Complexes with Asymmetric Salen Ligand

1.
State Key Laboratory of Functions and Applications of Medicinal Plants, Guizhou Medical University, Guiyang 550014, China
2.
School of Basic Medical Sciences, Guizhou Medical University, Guiyang 550025, China
3.
China Tobacco Guizhou Industrial Co., Ltd., Guiyang 550009, China
4.
Key laboratory of Macrocycle and Supramolecular Chemistry, Guizhou Medical University, Guiyang 550025, China

Corresponding author: ZHANG Qi-Long, gzuqlzhang@126.com
Received Date: 11 July 2019
Revised Date: 17 October 2019

Figures(8)

Reaction of (1R, 2R)-diaminocyclohexane with 2-hydroxy-1-naphthaldehyde and 3, 5-di-tert-butyl sali-cylaldehyde gave an asymmetric salen ligand H₂L. Then H₂L conducted the coordination reaction with Ni(OAc)₂·4H₂O, Cu(OAc)₂·H₂O and Mn(OAc)₂·4H₂O, and three mononuclear complex of[Ni(L)]·CH₂Cl₂ (1), [Cu(L)] (2) and[Mn(L)(Cl)]·CH₂Cl₂ (3) were obtained. The compounds were characterized by ¹H NMR, FT-IR and elemental analysis respectively and the crystal structure of ligand and three complexes were measured through X-ray single crystal diffraction technology. The ligand H₂L belongs to the orthorhombic system, P2₁2₁2₁ space group. Complex 1 belongs to the monoclinic system, P2₁/c space group, and the structures of complex 2 and 1 are similar. Complex 3 belongs to the triclinic system, P1 space group.
- asymmetric salen ligand,
- complex,
- synthesis,
- crystal structure
1. [1]
  LI Yun-Tong, DONG Jing-Wen, LU Yao, et al. Chinese J. Inorg. Chem., 2018, 34(6):1192-1198
2. [2]
  Mahapatra P, Ghosh S, Giri S, et al. Inorg. Chem., 2017, 56:5105-5121 doi: 10.1021/acs.inorgchem.7b00253
3. [3]
  XU Da-Qian, SUN Qiang-Sheng, XIA Chun -Gu, et al. SCIENTIA SINICA Chimica, 2018, 48(12):1619-1626
4. [4]
  ZOU Xiao-Chuan, SHI Kai-Yun, WANG Cun, et al. Chinese J. Inorg. Chem., 2016, 32(9):1585-1595
5. [5]
  WANG Yi-Fan, FAN Yi-Mei, JIAN Jun, et al. Acta Chim. Sinica, 2017, 75(7):715-722
6. [6]
  ZHANG Hui, ZENG Li-Li, WANG Yue-Kui, et al. Acta Phys.-Chim. Sin., 2015, 31(12):2229-2250 doi: 10.3866/PKU.WHXB201510301
7. [7]
  Brewer R A G, Kokot E, Mockler G M, et al. Inorg. Chem., 1985, 24:127-134 doi: 10.1021/ic00196a003
8. [8]
  Elder R C, Jr Blubaugh E A, Heinmann W R, et al. Inorg. Chem., 1983, 22:2777-2779 doi: 10.1021/ic00161a028
9. [9]
  Forni G A, Druta F V, Tessore F, et al. Inorg. Chem., 2007, 46:884-895 doi: 10.1021/ic062035r
10. [10]
  Kanis D R, Ratner M A, Marks T J, et al. J. Am. Chem. Soc., 1992, 114:10338-10357 doi: 10.1021/ja00052a035
11. [11]
  Apurba B, Drew M G B, Ghosh A. Polyhedron, 2010, 29:1029-1034 doi: 10.1016/j.poly.2009.12.006
12. [12]
  Gradinaru A, Forni A, Druta V, et al. Inorg. Chem., 2007, 46:884-895 doi: 10.1021/ic062035r
13. [13]
  Lakma A, Hossain S M, Leusen J V, et al. Dalton Trans., 2019, 48:7766-7777 doi: 10.1039/C9DT01041F
14. [14]
  WANG Jia-Zhong, GU Jing-Chi, ZHANG Xue-Cheng, et al. Chinese J. Inorg. Chem., 2012, 28(2):321-325
15. [15]
  Sheldrick G M. SHELX-97, University of Göttingen, Germany, 1997.
1. [1]
  Xinting XIONG , Zhiqiang XIONG , Panlei XIAO , Xuliang NIE , Xiuying SONG , Xiuguang YI . Synthesis, crystal structures, Hirshfeld surface analysis, and antifungal activity of two complexes Na(Ⅰ)/Cd(Ⅱ) assembled by 5-bromo-2-hydroxybenzoic acid ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1661-1670. doi: 10.11862/CJIC.20240145
2. [2]
  Jing WU , Puzhen HUI , Huilin ZHENG , Pingchuan YUAN , Chunfei WANG , Hui WANG , Xiaoxia GU . Synthesis, crystal structures, and antitumor activities of transition metal complexes incorporating a naphthol-aldehyde Schiff base ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2422-2428. doi: 10.11862/CJIC.20240278
3. [3]
  Lifang HE , Wenjie TANG , Yaoze LUO , Mingsheng LIANG , Jianxin TANG , Yuxuan WU , Fuxing ZHANG , Xiaoming ZHU . Synthesis, structure, and anticancer activity of two dialkyltin complexes constructed based on 2, 2′-bipyridin-6, 6′-dicarboxylic acid. Chinese Journal of Inorganic Chemistry, 2025, 41(8): 1601-1609. doi: 10.11862/CJIC.20250012
4. [4]
  Hongjie SHEN , Haozhe MIAO , Yuhe YANG , Yinghua LI , Deguang HUANG , Xiaofeng ZHANG . Synthesis, crystal structure, and fluorescence properties of two Cu(Ⅰ) complexes based on pyridyl ligand. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 855-863. doi: 10.11862/CJIC.20250009
5. [5]
  Xiaotong LU , Pan ZHANG , Zijie ZHAO , Lei HUANG , Hongwei ZUO , Lili LIANG . Antitumor and antibacterial activities of pyridyl Schiff base indium and dysprosium complexes. Chinese Journal of Inorganic Chemistry, 2025, 41(8): 1523-1532. doi: 10.11862/CJIC.20250073
6. [6]
  Hexing SONG , Zan SUN . Synthesis, crystal structure, Hirshfeld surface analysis, and fluorescent sensing for Fe³⁺ of an Mn(Ⅱ) complex based on 1-naphthalic acid. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 885-892. doi: 10.11862/CJIC.20240402
7. [7]
  Xiaoqi LAN , Wei LI , Long JING , Mengyu SU , Xiaoling LUO , Zheng LIU , Qun TANG . Synthesis, crystal structure, and spectral properties of transition-metal-organic frameworks based on thiophene carboxylic acid ligands. Chinese Journal of Inorganic Chemistry, 2026, 42(2): 309-316. doi: 10.11862/CJIC.20250212
8. [8]
  Yahui HAN , Jinjin ZHAO , Ning REN , Jianjun ZHANG . Synthesis, crystal structure, thermal decomposition mechanism, and fluorescence properties of benzoic acid and 4-hydroxy-2, 2′: 6′, 2″-terpyridine lanthanide complexes. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 969-982. doi: 10.11862/CJIC.20240395
9. [9]
  Haitang WANG , Yanni LING , Xiaqing MA , Yuxin CHEN , Rui ZHANG , Keyi WANG , Ying ZHANG , Wenmin WANG . Construction, crystal structures, and biological activities of two Ln^Ⅲ₃ complexes. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1474-1482. doi: 10.11862/CJIC.20240188
10. [10]
  Yuxin CHEN , Yanni LING , Yuqing YAO , Keyi WANG , Linna LI , Xin ZHANG , Qin WANG , Hongdao LI , Wenmin WANG . Construction, structures, and interaction with DNA of two Sm^Ⅲ₄ complexes. Chinese Journal of Inorganic Chemistry, 2025, 41(6): 1141-1150. doi: 10.11862/CJIC.20240258
11. [11]
  Changqing MIAO , Fengjiao CHEN , Wenyu LI , Shujie WEI , Yuqing YAO , Keyi WANG , Ni WANG , Xiaoyan XIN , Ming FANG . Crystal structures, DNA action, and antibacterial activities of three tetranuclear lanthanide-based complexes. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2455-2465. doi: 10.11862/CJIC.20240192
12. [12]
  Jingjing QING , Fan HE , Zhihui LIU , Shuaipeng HOU , Ya LIU , Yifan JIANG , Mengting TAN , Lifang HE , Fuxing ZHANG , Xiaoming ZHU . Synthesis, structure, and anticancer activity of two complexes of dimethylglyoxime organotin. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1301-1308. doi: 10.11862/CJIC.20240003
13. [13]
  Yingchun ZHANG , Yiwei SHI , Ruijie YANG , Xin WANG , Zhiguo SONG , Min WANG . Dual ligands manganese complexes based on benzene sulfonic acid and 2, 2′-bipyridine: Structure and catalytic properties and mechanism in Mannich reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1501-1510. doi: 10.11862/CJIC.20240078
14. [14]
  Xiaoling LUO , Pintian ZOU , Xiaoyan WANG , Zheng LIU , Xiangfei KONG , Qun TANG , Sheng WANG . Synthesis, crystal structures, and properties of lanthanide metal-organic frameworks based on 2, 5-dibromoterephthalic acid ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1143-1150. doi: 10.11862/CJIC.20230271
15. [15]
  Linjie ZHU , Xufeng LIU . Synthesis, characterization and electrocatalytic hydrogen evolution of two di-iron complexes containing a phosphine ligand with a pendant amine. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 939-947. doi: 10.11862/CJIC.20240416
16. [16]
  Jiaming Xu , Yu Xiang , Weisheng Lin , Zhiwei Miao . Research Progress in the Synthesis of Cyclic Organic Compounds Using Bimetallic Relay Catalytic Strategies. University Chemistry, 2024, 39(3): 239-257. doi: 10.3866/PKU.DXHX202309093
17. [17]
  Xuyu WANG , Xinran XIE , Dengke CAO . Photoreaction characteristics and luminescence modulation in phosphine-anthracene-based Au(Ⅰ) and Ir(Ⅲ) complexes. Chinese Journal of Inorganic Chemistry, 2025, 41(8): 1513-1522. doi: 10.11862/CJIC.20250113
18. [18]
  Linjie ZHU , Xufeng LIU . Electrocatalytic hydrogen evolution performance of tetra-iron complexes with bridging diphosphine ligands. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 321-328. doi: 10.11862/CJIC.20240207
19. [19]
  Jia JI , Tengqi YAO , Wenqian DENG , Wenjing SHI , Xuan LÜ , Lin TIAN , Xiaoyan XIN , Yinling HOU . Structures, antibacterial activities, and interactions with DNA of two nickel complexes. Chinese Journal of Inorganic Chemistry, 2026, 42(1): 78-86. doi: 10.11862/CJIC.20250141
20. [20]
  Xin MA , Ya SUN , Na SUN , Qian KANG , Jiajia ZHANG , Ruitao ZHU , Xiaoli GAO . A Tb₂ complex based on polydentate Schiff base: Crystal structure, fluorescence properties, and biological activity. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1347-1356. doi: 10.11862/CJIC.20230357

Get Citation

PDF

XML

Metrics

PDF Downloads(84)
Abstract views(6546)
HTML views(1755)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142