Citation: HE Rong, YUN Ya-Pei, SUN Li-Li, SHENG Hong-Ting, DU Yuan-Xin, XIANG Dong, LI Peng, YUAN Xiao-You, ZHU Man-Zhou, HONG Xun, WU Yu-En. Mesoporous SBA-15 Rods Supported Pd₃Cl Catalysts for Sonogashira C-C Coupling[J]. Chinese Journal of Inorganic Chemistry, ;2020, 36(1): 53-61. doi: 10.11862/CJIC.2020.022 shu

Mesoporous SBA-15 Rods Supported Pd₃Cl Catalysts for Sonogashira C-C Coupling

HE Rong ^1,2 ,
YUN Ya-Pei ^1,2 ,
SUN Li-Li ^1,2 ,
SHENG Hong-Ting ^1,2 ,
DU Yuan-Xin ^1,2 ,
XIANG Dong ¹ ,
LI Peng ^1,2,, ,
YUAN Xiao-You ¹ ,
ZHU Man-Zhou ^1,2,, ,
HONG Xun ³ ,
WU Yu-En ³

1.
Department of Chemistry and Centre for Atomic Engineering of Advanced Materials, Anhui Province Key Laboratory of Chemistry for Inorganic/Organic Hybrid Functionalized Materials, Anhui University, Hefei, Anhui 230601, China
2.
Key Laboratory of Structure and Functional Regulation of Hybrid Materials(Anhui University), Ministry of Education, Hefei 230601, China
3.
Center of Advanced Nanocatalysis(CAN) and Department of Chemistry, University of Science and Technology of China, Hefei 230026, China

Corresponding author: LI Peng, peng-li@ahu.edu.cn ZHU Man-Zhou, zmz@ahu.edu.cn
Received Date: 22 September 2019
Revised Date: 7 November 2019

Figures(6)

In this work, atomically precise[Pd₃Cl(PPh₂)₂(PPh₃)₃]⁺ (denoted as Pd₃Cl) nanoclusters with high monodispersity were supported on the rod-like mesoporous SBA-15 by electrostatic attraction strategy. The well-defined Pd₃Cl/SBA-15 catalysts exhibited good catalytic performance and recyclability for Sonogashira C-C coupling reaction under mild condition with environment-friendly water as solvent. Importantly, we investigated the relationship between structures and properties of Pd₃Cl, which demonstrated that the synergistic effect between Pd^δ+ (0 < δ < 2) and the ligand was the key to the catalytic reaction.
- atomically precise nanoclusters,
- SBA-15,
- electrostatic attraction,
- Sonogashira C-C coupling
1. [1]
  Chinchilla R, Najera C. Chem. Rev., 2007, 107(3):874-922 doi: 10.1021/cr050992x
2. [2]
  Biffis A, Centomo P, Zotto A D, et al. Chem. Rev., 2018, 118(4):2249-2295 doi: 10.1021/acs.chemrev.7b00443
3. [3]
  Chinchilla R, Najera C. Chem. Rev., 2014, 114(3):1783-1826 doi: 10.1021/cr400133p
4. [4]
  Yuan B Z, Pan Y Y, Li Y W, et al. Angew. Chem. Int. Ed., 2010, 49(24):4054-4058 doi: 10.1002/anie.201000576
5. [5]
  Lin J Z, Abroshan H, Liu C, et al. J. Catal., 2015, 330:354-361 doi: 10.1016/j.jcat.2015.07.020
6. [6]
  Paterson I, Davies R D M, Marquez R. Angew. Chem. Int. Ed., 2001, 40(3):603-607 doi: 10.1002/1521-3773(20010202)40:3<603::AID-ANIE603>3.0.CO;2-O
7. [7]
  Bagley M C, Dale J W, Merritt E A, et al. Chem. Rev., 2005, 105(2):685-714 doi: 10.1021/cr0300441
8. [8]
  Brunsveld L, Meijer E W, Prince R B, et al. J. Am. Chem. Soc., 2001, 123(33):7978-7984 doi: 10.1021/ja010751g
9. [9]
  Karak M, Barbosa L C A, Hargaden G C. RSC Adv., 2014, 4(96):53442-53466 doi: 10.1039/C4RA09105A
10. [10]
  Nicolaou K C, Bulger P G, Sarlah D. Angew. Chem. Int. Ed., 2005, 44(29):4442-4489 doi: 10.1002/anie.200500368
11. [11]
  Dissanayake K C, Ebukuyo P O, Dhahir Y J, et al. Chem. Commun., 2019, 55(34):4973-4976 doi: 10.1039/C9CC01365B
12. [12]
  Kozell V, McLaughlin M, Strappaveccia G, et al. ACS Sustainable Chem. Eng., 2016, 4(12):7209-7216 doi: 10.1021/acssuschemeng.6b02170
13. [13]
  Seth J, Kona C N, Das S, et al. Nanoscale, 2015, 7(3):872-876 doi: 10.1039/C4NR04239E
14. [14]
  Elhage A, Lanterna A E, Scaiano J C. ACS Sustainable Chem. Eng., 2018, 6(2):1717-1722 doi: 10.1021/acssuschemeng.7b02992
15. [15]
  Zhang X Y, Sun Z C, Wang B, et al. J. Am. Chem. Soc., 2018, 140(3):954-962 doi: 10.1021/jacs.7b09314
16. [16]
  Zhou Y, Li G. Acta Phys. Chim. Sin., 2017, 33(7):1297-1309
17. [17]
  Chakraborty I, Pradeep T. Chem. Rev., 2017, 117(12):8208-8271 doi: 10.1021/acs.chemrev.6b00769
18. [18]
  Jin R C, Zeng C J, Zhou M, et al. Chem. Rev., 2016, 116(18):10346-10413 doi: 10.1021/acs.chemrev.5b00703
19. [19]
  Li G, Jin R C. J. Am. Chem. Soc., 2014, 136(32):11347-11354 doi: 10.1021/ja503724j
20. [20]
  Wang L Q, Shen K Q, Chen M Y, et al. Nanoscale, 2019, 11(29):13767-13772 doi: 10.1039/C9NR04219A
21. [21]
  Yin L X, Liebscher J. Chem. Rev., 2007, 107(1):133-173 doi: 10.1021/cr0505674
22. [22]
  Tukhani M, Panahi F, Khalafi-Nezhad A. ACS Sustainable Chem. Eng., 2018, 6(1):1456-1467 doi: 10.1021/acssuschemeng.7b03923
23. [23]
  Li G, Jiang D E, Liu C, et al. J. Catal., 2013, 306:177-183 doi: 10.1016/j.jcat.2013.06.017
24. [24]
  Gholinejad M, Bahrami M, Nájera C, et al. J. Catal., 2018, 363:81-91 doi: 10.1016/j.jcat.2018.02.028
25. [25]
  Moon J, Jang M, Lee S. J. Org. Chem., 2009, 74(3):1403-1406 doi: 10.1021/jo802290r
26. [26]
  Li Z M, Yang X J, Liu C, et al. Prog. Nat. Sci.:Mater. Int., 2016, 26(5):477-482 doi: 10.1016/j.pnsc.2016.09.007
27. [27]
  Fu F Y, Xiang J, Cheng H, et al. ACS Catal., 2017, 7(3):1860-1867 doi: 10.1021/acscatal.6b02527
28. [28]
  Wang Q, Wang Z C, Zheng T H, et al. Nano Res., 2016, 9(8):2294-2302 doi: 10.1007/s12274-016-1116-8
29. [29]
  Teng J, Chen M Q, Xie Y Y, et al. Chem. Mater., 2018, 30(18):6458-6468 doi: 10.1021/acs.chemmater.8b02884
30. [30]
  Li Z P, Yang X C, Tsumori N, et al. ACS Catal., 2017, 7(4):2720-2724 doi: 10.1021/acscatal.7b00053
31. [31]
  Wang Z C, Chen W, Han Z L, et al. Nano. Res., 2014, 7(9):1254-1262 doi: 10.1007/s12274-014-0488-x
32. [32]
  Li Q, Das A, Wang S X, et al. Chem. Commun., 2016, 52(99):14298-14301 doi: 10.1039/C6CC07825G
33. [33]
  Liu Y Y, Chai X Q, Cai X, et al. Angew. Chem. Int. Ed., 2018, 57(31):9775-9779 doi: 10.1002/anie.201805319
1. [1]
  Wenya Jiang , Jianyu Wei , Kuan-Guan Liu . Atomically precise superatomic silver nanoclusters stabilized by O-donor ligands. Chinese Journal of Structural Chemistry, 2024, 43(9): 100371-100371. doi: 10.1016/j.cjsc.2024.100371
2. [2]
  Luyao Lu , Chen Zhu , Fei Li , Pu Wang , Xi Kang , Yong Pei , Manzhou Zhu . Ligand effects on geometric structures and catalytic activities of atomically precise copper nanoclusters. Chinese Journal of Structural Chemistry, 2024, 43(10): 100411-100411. doi: 10.1016/j.cjsc.2024.100411
3. [3]
  Ziyi Liu , Xunying Liu , Lubing Qin , Haozheng Chen , Ruikai Li , Zhenghua Tang . Alkynyl ligand for preparing atomically precise metal nanoclusters: Structure enrichment, property regulation, and functionality enhancement. Chinese Journal of Structural Chemistry, 2024, 43(11): 100405-100405. doi: 10.1016/j.cjsc.2024.100405
4. [4]
  Qinghong Zhang , Qiao Zhao , Xiaodi Wu , Li Wang , Kairui Shen , Yuchen Hua , Cheng Gao , Yu Zhang , Mei Peng , Kai Zhao . Visible-light-induced ring-opening cross-coupling of cycloalcohols with vinylazaarenes and enones via β-C-C scission enabled by proton-coupled electron transfer. Chinese Chemical Letters, 2025, 36(2): 110167-. doi: 10.1016/j.cclet.2024.110167
5. [5]
  Xian Yan , Huawei Xie , Gao Wu , Fang-Xing Xiao . Boosted solar water oxidation steered by atomically precise alloy nanocluster. Chinese Chemical Letters, 2025, 36(1): 110279-. doi: 10.1016/j.cclet.2024.110279
6. [6]
  Shengkai Li , Yuqin Zou , Chen Chen , Shuangyin Wang , Zhao-Qing Liu . Defect engineered electrocatalysts for C–N coupling reactions toward urea synthesis. Chinese Chemical Letters, 2024, 35(8): 109147-. doi: 10.1016/j.cclet.2023.109147
7. [7]
  Mengli Xu , Zhenmin Xu , Zhenfeng Bian . Achieving Ullmann coupling reaction via photothermal synergy with ultrafine Pd nanoclusters supported on mesoporous TiO2. Chinese Journal of Structural Chemistry, 2024, 43(7): 100305-100305. doi: 10.1016/j.cjsc.2024.100305
8. [8]
  Yuemin Chen , Yunqi Wu , Guoao Wang , Feihu Cui , Haitao Tang , Yingming Pan . Electricity-driven enantioselective cross-dehydrogenative coupling of two C(sp³)-H bonds enabled by organocatalysis. Chinese Chemical Letters, 2024, 35(9): 109445-. doi: 10.1016/j.cclet.2023.109445
9. [9]
  Zhibin Ren , Shan Li , Xiaoying Liu , Guanghao Lv , Lei Chen , Jingli Wang , Xingyi Li , Jiaqing Wang . Penetrating efficiency of supramolecular hydrogel eye drops: Electrostatic interaction surpasses ligand-receptor interaction. Chinese Chemical Letters, 2024, 35(11): 109629-. doi: 10.1016/j.cclet.2024.109629
10. [10]
  Shuai Tang , Zian Wang , Mengyi Zhu , Xinyun Zhao , Xiaoyun Hu , Hua Zhang . Synthesis of organoboron compounds via heterogeneous C–H and C–X borylation. Chinese Chemical Letters, 2025, 36(5): 110503-. doi: 10.1016/j.cclet.2024.110503
11. [11]
  Lei Wan , Yizhou Tong , Xi Lu , Yao Fu . Cobalt-catalyzed reductive alkynylation to construct C(sp)-C(sp³) and C(sp)-C(sp²) bonds. Chinese Chemical Letters, 2024, 35(7): 109283-. doi: 10.1016/j.cclet.2023.109283
12. [12]
  Jiao Li , Chenyang Zhang , Chuhan Wu , Yan Liu , Xuejian Zhang , Xiao Li , Yongtao Li , Jing Sun , Zhongmin Su . Defined organic-octamolybdate crystalline superstructures derived Mo₂C@C as efficient hydrogen evolution electrocatalysts. Chinese Chemical Letters, 2024, 35(6): 108782-. doi: 10.1016/j.cclet.2023.108782
13. [13]
  Junmeng Luo , Qiongqiong Wan , Suming Chen . Chemistry-driven mass spectrometry for structural lipidomics at the C=C bond isomer level. Chinese Chemical Letters, 2025, 36(1): 109836-. doi: 10.1016/j.cclet.2024.109836
14. [14]
  Kebo Xie , Qian Zhang , Fei Ye , Jungui Dai . A multi-enzymatic cascade reaction for the synthesis of bioactive C-oligosaccharides. Chinese Chemical Letters, 2024, 35(6): 109028-. doi: 10.1016/j.cclet.2023.109028
15. [15]
  Chen Li , Ziyuan Zhao , Shouyun Yu . Photoredox-catalyzed C-glycosylation of peptides with glycosyl bromides. Chinese Chemical Letters, 2024, 35(6): 109128-. doi: 10.1016/j.cclet.2023.109128
16. [16]
  Hongjin Shi , Guoyin Yin , Xi Lu , Yangyang Li . Stereoselective synthesis of 2-deoxy-α-C-glycosides from glycals. Chinese Chemical Letters, 2024, 35(12): 109674-. doi: 10.1016/j.cclet.2024.109674
17. [17]
  Xin Li , Jia-Min Lu , Bo Li , Chen Zhao , Bei-Bei Yang , Li Li . Chiroptical sensing for remote chiral amines via a C–H activation reaction. Chinese Chemical Letters, 2025, 36(5): 110310-. doi: 10.1016/j.cclet.2024.110310
18. [18]
  Wenjiang LI , Pingli GUAN , Rui YU , Yuansheng CHENG , Xianwen WEI . C₆₀-MoP-C nanoflowers van der Waals heterojunctions and its electrocatalytic hydrogen evolution performance. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 771-781. doi: 10.11862/CJIC.20230289
19. [19]
  Shulei Hu , Yu Zhang , Xiong Xie , Luhan Li , Kaixian Chen , Hong Liu , Jiang Wang . Rh(Ⅲ)-catalyzed late-stage C-H alkenylation and macrolactamization for the synthesis of cyclic peptides with unique Trp(C7)-alkene crosslinks. Chinese Chemical Letters, 2024, 35(8): 109408-. doi: 10.1016/j.cclet.2023.109408
20. [20]
  Yi Liu , Zhe-Hao Wang , Guan-Hua Xue , Lin Chen , Li-Hua Yuan , Yi-Wen Li , Da-Gang Yu , Jian-Heng Ye . Photocatalytic dicarboxylation of strained C–C bonds with CO₂ via consecutive visible-light-induced electron transfer. Chinese Chemical Letters, 2024, 35(6): 109138-. doi: 10.1016/j.cclet.2023.109138

Get Citation

PDF

XML

Metrics

PDF Downloads(4)
Abstract views(613)
HTML views(53)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Mesoporous SBA-15 Rods Supported Pd3Cl Catalysts for Sonogashira C-C Coupling

Metrics

通讯作者: 陈斌, bchen63@163.com

Mesoporous SBA-15 Rods Supported Pd₃Cl Catalysts for Sonogashira C-C Coupling