Citation: LI Yu, CHEN Yong-Xuan, ZHAO Na, FENG An-Sheng, ZOU Xun-Zhong. Syntheses, Crystal Structures, Luminescent and Magnetic Properties of Two 1D Cadmium(Ⅱ) and Nickel(Ⅱ) Coordination Polymers[J]. Chinese Journal of Inorganic Chemistry, ;2020, 36(1): 192-206. doi: 10.11862/CJIC.2020.017 shu

Syntheses, Crystal Structures, Luminescent and Magnetic Properties of Two 1D Cadmium(Ⅱ) and Nickel(Ⅱ) Coordination Polymers

Guangdong Research Center for Special Building Materials and Its Green Preparation Technology/Foshan Research Center for Special Functional Building Materials and Its Green Preparation Technology, Guangdong Industry Polytechnic, Guangzhou 510300, China

Corresponding author: ZHAO Na, 2017018009@gdip.edu.cn ZOU Xun-Zhong, 2012009035@gdip.edu.cn
Received Date: 15 May 2019
Revised Date: 30 September 2019

Figures(7)

Two 1D cadmium(Ⅱ) and nickel(Ⅱ) coordination polymers, namely {[M₂(μ₃-L)(phen)₃]·5H₂O}_n (M=Cd (1), Ni (2)), were constructed hydrothermally using H₄L (H₄L=3-(2, 4-dicarboxyphenyl)-2, 6-pyridinedicarboxylic acid), phen (phen=1, 10-phenanthroline), and cadmium or nickel chlorides. Single-crystal X-ray diffraction analyses reveal that both compounds are isostructural and crystallize in the orthorhombic system, space group Pbca. Compound 1 or 2 feature a 1D metal-organic chain, which is assembled to a 2D supramolecular network through O-H…O hydrogen bond. The luminescent and magnetic properties for two compounds were also investigated.
- coordination polymer,
- tetracarboxylic acid,
- luminescent properties,
- magnetic properties
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