Citation: CHENG Lin, YANG Jing-Hua, ZHAI Qing-Chao, ZHANG Qing-Song. A Chiral Ag(Ⅰ) Coordination Polymer Based on an α, α-L-Diaryl Prolinol-Pyridine Derivative: Circular Dichroism, SHG Response and Luminescent Property[J]. Chinese Journal of Inorganic Chemistry, ;2020, 36(2): 361-367. doi: 10.11862/CJIC.2020.013 shu

A Chiral Ag(Ⅰ) Coordination Polymer Based on an α, α-L-Diaryl Prolinol-Pyridine Derivative: Circular Dichroism, SHG Response and Luminescent Property

School of Chemistry and Chemical Engineering, Southeast University, Nanjing 211189, China

Corresponding author: CHENG Lin, lcheng@seu.edu.cn
Received Date: 11 July 2019
Revised Date: 3 October 2019

Figures(8)

A chiral α, α-L-diaryl prolinol-pyridine derivative, (S)-bis(4-(pyridin-4-yl)phenyl)(pyrrolidin-2-yl)methanol (L), was synthesized and used to construct a chiral coordination polymer, {[Ag₄(L)₄](NO₃)₄·1.5CH₃OH·1.25H₂O}_n (1), with Ag(Ⅰ). The polymer displayed a one-dimensional ladder-like chain structure, which was characterized by single crystal XRD, PXRD, IR spectra, TGA and luminescent spectra. CD spectra and SHG response of the compounds confirmed that the bulk sample was of structural chirality.
- chiral coordination polymer,
- α, α-L-diaryl prolinol,
- CD spectra,
- luminescent property
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