Citation: SUN Yun-Po, XIE Jian, ZHAO Xin-Bing, ZHUANG Da-Gao, ZHANG Gen-Lin. Prussian Blue Cathode Material: Preparation by Ion-Exchange Method and Electrochemical Potassium-Storage Performance[J]. Chinese Journal of Inorganic Chemistry, ;2020, 36(1): 106-112. doi: 10.11862/CJIC.2020.008 shu

Prussian Blue Cathode Material: Preparation by Ion-Exchange Method and Electrochemical Potassium-Storage Performance

1.
School of Materials Science and Engineering, Zhejiang University, Hangzhou 310027, China
2.
Shanghai Han Xing Science and Technology Co., Ltd., Shanghai 201322, China

Corresponding author: XIE Jian, xiejian1977@zju.edu.cn
Received Date: 4 July 2019
Revised Date: 11 November 2019

Figures(5)

Na-doped K-based Prussian blue (NKPB) material (K_1.9Na_0.1Mn[Fe(CN)₆]·0.4H₂O) was prepared by ion-exchange method using KCl and Na-based Prussian blue (NPB) material(Na_2-xMn[Fe(CN)₆]_z·yH₂O) as the precursors. The electrochemical tests reveal that compared with the K-based Prussian blue (KPB) material K_1.85Mn[Fe(CN)₆]_0.98□_0.02·0.7H₂O (□ is the[Fe(CN)₆] vacancy) prepared by a conversional coprecipitation route, the NKPB prepared by ion-exchange method shows higher capacity (the initial discharge capacity at 0.1C reached 136.3 mAh·g^-1), longer cycle life (the capacity retention after 100 cycles at 0.5C was 96.1%), and better rate capability (the capacities at 5C and 10C were 87.6 and 68.4 mAh·g^-1, respectively). The outstanding electrochemical performance of the NKPB material is ascribed to its high K content, good crystal integrity, Na-ion doping, nanosized particles and the unique open framework structure.
- potassium-ion battery,
- cathode material,
- Prussian blue material,
- ion-exchange method,
- electrochemical performance
1. [1]
  Reinhardt R, Christodoulou I, Gassó-Domingo S, et al. J. Environ. Manage., 2019, 245:432-446 doi: 10.1016/j.jenvman.2019.05.095
2. [2]
  Chu S, Cui Y, Liu N. Nat. Mater., 2016, 16(1):16-22
3. [3]
  Chen M Z, Liu Q N, Wang S W, et al. Adv. Energy Mater., 2019, 9(14):1803609 doi: 10.1002/aenm.201803609
4. [4]
  Wang Y R, Chen R P, Chen T, et al. Energy Storage Mater., 2016, 4:103-129 doi: 10.1016/j.ensm.2016.04.001
5. [5]
  Zhang J D, Liu T T, Cheng X, et al. Nano Energy, 2019, 60:340-361 doi: 10.1016/j.nanoen.2019.03.078
6. [6]
  ZHANG Ning, LIU Yong-Chang, CHEN Cheng-Cheng, et al. Chinese J. Inorg. Chem., 2015, 31(9):1739-1750
7. [7]
  Kubota K, Dahbi M, Hosaka T, et al. Chem. Rec., 2018, 18(4):459-479 doi: 10.1002/tcr.201700057
8. [8]
  Eftekhari A, Jian Z L, Ji X L. ACS Appl. Mater. Interfaces, 2017, 9(5):4404-4419 doi: 10.1021/acsami.6b07989
9. [9]
  Pramudita J C, Sehrawat D, Goonetilleke D, et al. Adv. Energy Mater., 2017, 7(24):1602911 doi: 10.1002/aenm.201602911
10. [10]
  Xu G L, Amine R, Abouimrane A, et al. Adv. Energy Mater., 2018, 8(14):1702403 doi: 10.1002/aenm.201702403
11. [11]
  Kim H, Kim J C, Bianchini M, et al. Adv. Energy Mater., 2018, 8(9):1702384 doi: 10.1002/aenm.201702384
12. [12]
  Bie X F, Kubota K, Hosaka T, et al. J. Mater. Chem. A, 2017, 5(9):4325-4330 doi: 10.1039/C7TA00220C
13. [13]
  Shadike Z, Shi D R, Wang T, et al. J. Mater. Chem. A, 2017, 5(14):6393-6398 doi: 10.1039/C7TA00484B
14. [14]
  Xue L G, Li Y T, Gao H C, et al. J. Am. Chem. Soc., 2017, 139(6):2164-2167 doi: 10.1021/jacs.6b12598
15. [15]
  Shen Z L, Guo S H, Liu C L, et al. ACS Sustainable Chem. Eng., 2018, 6(12):16121-16129 doi: 10.1021/acssuschemeng.8b02758
16. [16]
  Li W J, Han C, Cheng G, et al. Small, 2019:e1900470
17. [17]
  Baioun A, Kellawi H, Falah A. Curr. Nanosci., 2018, 14(3):227-233 doi: 10.2174/1573413714666180103153511
18. [18]
  CHEN Xin, XU Li, SHEN Zhi-Long, et al. Chinese J. Inorg. Chem., 2015, 31(9):1739-1750
19. [19]
  Song J, Wang L, Lu Y H, et al. J. Am. Chem. Soc., 2015, 137(7):2658-2664 doi: 10.1021/ja512383b
20. [20]
  Jiang X L, Liu H J, Song J, et al. J. Mater. Chem. A, 2016, 4(41):16205-16212 doi: 10.1039/C6TA06658E
21. [21]
  Jiang X, Zhang T R, Yang L Q, et al. ChemElectroChem, 2017, 4(9):2237-2242 doi: 10.1002/celc.201700410
22. [22]
  Jiang P, Shao H Z, Chen L, et al. J. Mater. Chem. A, 2017, 5(32):16740-16747 doi: 10.1039/C7TA04172A
23. [23]
  Chen T, Jin G P, Meng G J, et al. J. Environ. Chem. Eng., 2019, 7(1):102799 doi: 10.1016/j.jece.2018.10.070
24. [24]
  Bhatt P, Banerjee S, Anwar S, et al. ACS Appl. Mater. Interfaces, 2014, 6(20):17579-17588 doi: 10.1021/am503526c
25. [25]
  Bie X F, KubotaK, Hosaka T, J. et al. J. Mater. Chem. A, 2017, 5(9):43254330
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1.
沈阳化工大学材料科学与工程学院沈阳 110142