Citation: LI Yu, ZOU Xun-Zhong, FENG An-Sheng, ZHAO Zhen-Yu. Syntheses, Crystal Structures and Magnetic Properties of Two Copper(Ⅱ) Coordination Compounds Based on 5-Bromoisophthalic Acid and 2, 2'-Bipyridine[J]. Chinese Journal of Inorganic Chemistry, ;2020, 36(2): 345-351. doi: 10.11862/CJIC.2020.002 shu

Syntheses, Crystal Structures and Magnetic Properties of Two Copper(Ⅱ) Coordination Compounds Based on 5-Bromoisophthalic Acid and 2, 2'-Bipyridine

1.
Guangdong Research Center for Special Building Materials and Its Green Preparation Technology/Foshan Research Center for Special Functional Building Materials and Its Green Preparation Technology, Guangdong Industry Polytechnic, Guangzhou 510300, China
2.
School of Intelligent Manufacturing and Equipment, Shenzhen Institute of Information Technology, Shenzhen, Guangdong 518172, China

Corresponding author: LI Yu, liyuletter@163.com ZHAO Zhen-Yu, yxpzzy01@163.com
Received Date: 13 June 2019
Revised Date: 17 September 2019

Figures(8)

Zero-dimensional mononuclear copper(Ⅱ) coordination compound and 1D chain copper(Ⅱ) coordination polymer, namely [Cu(BIPA)(2, 2'-bipy)(H₂O)₂]·H₂O (1) and[Cu₃(μ₃-BIPA)₂(μ-OH)₂(2, 2'-bipy)₂]_n (2), were constructed hydrothermally using H₂BIPA (H₂BIPA=5-bromoisophthalic acid), 2, 2'-bipy (2, 2'-bipy=2, 2'-bipyridine), and copper chloride at the n_NaOH:n_{H₂ BIPA} (molar ratio) of 2:1 or 3:1, respectively. Single-crystal X-ray diffraction analyses reveal that both compounds crystallize in the monoclinic system, space groups P2₁/c or P2₁/n, respectively. Compound 1 discloses a discrete monomer structure, which is assembled to a 2D sheet through O-H…O hydrogen bonds. Compound 2 has a chain structure based on Cu₃ unit. The chains are further extended into a 2D sheet by π-π stacking interactions. Structural differences between compounds 1 and 2 are attributed to the different molar ratio between NaOH and H₂BIPA. Magnetic studies for compound 2 demonstrate an antiferromagnetic coupling between the adjacent Cu(Ⅱ) centers within Cu₃ unit.
- copper coordination compound,
- hydrogen bonding,
- 5-bromoisophthalic acid,
- magnetic properties
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