Citation: ZHOU Qi, DUAN De-Dong, FENG Ji-Wei. Preparation of Ni-Co/RuO₂ Composite Electrode and Electrocatalytic Activity for Hydrogen Evolution[J]. Chinese Journal of Inorganic Chemistry, ;2019, 35(12): 2301-2310. doi: 10.11862/CJIC.2019.258 shu

Preparation of Ni-Co/RuO₂ Composite Electrode and Electrocatalytic Activity for Hydrogen Evolution

ZHOU Qi ^1,2,, ,
DUAN De-Dong ² ,
FENG Ji-Wei ²

1.
State Key Laboratory of Advanced Processing and Recycling of Nonferrous Metals, Lanzhou University of Technology, Lanzhou 730050, China
2.
College of Materials Science and Engineering, Lanzhou University of Technology, Lanzhou 730050, China

Corresponding author: ZHOU Qi, zhouxq301@sina.com
Received Date: 21 June 2019
Revised Date: 7 October 2019

Figures(11)

Nanoporous Ni, Co and Ni-Co alloys were prepared by rapid solidification combined with de-alloying. The surface of Ni-Co alloy was modified by RuO₂. The phase analysis and morphology of porous materials were characterized by X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), scanning electron microscope (SEM) and transmission electron microscope (TEM). The electrocatalytic hydrogen evolution performance of the porous electrode was tested by linear sweep voltammetry, multi-potential step, alternating current impedance and potentiostatic electrolysis. The results show that the Ni-Co/RuO₂ composite electrode material has a hydrogen evolution overpotential of 180 mV at a current density of 50 mA·cm^-2. The hydrogen evolution process was controlled by the Volmer-Heyrovsky step, and the exchange current density was 4.42 mA·cm^-2. Compared with nanoporous Ni, nanoporous Co and nanoporous Ni-Co alloy, Ni-Co/RuO₂ composite electrode had the lowest apparent activation energy during hydrogen evolution. After 10 h constant current electrolysis, the potential only increased by 20 mV, showing excellent hydrogen evolution stability.
- de-alloying,
- Ni-Co/RuO₂ composite electrode,
- electrocatalytic hydrogen evolution
1. [1]
  Mohammed-Ibrahim J, Sun X M. Journal of Energy Chemistry, 2019, 34:111-160 doi: 10.1016/j.jechem.2018.09.016
2. [2]
  Wang H, Gao L J. Curr. Opin. Electrochem., 2018, 7:7-14 doi: 10.1016/j.coelec.2017.10.010
3. [3]
  Jamesh M I. J. Power Sources, 2016, 333:213-236 doi: 10.1016/j.jpowsour.2016.09.161
4. [4]
  Eftekhari A. Int. J. Hydrogen Energy, 2017, 42(16):11053-11077 doi: 10.1016/j.ijhydene.2017.02.125
5. [5]
  Schmickler W, Trasatti S. J. Electrochem. Soc., 2006, 153(12):L31-L32 doi: 10.1149/1.2358294
6. [6]
  WANG Yu, SHENG Min-Qi, WENG Wen-Ping, et al. Chinese Journal of Materials Research, 2017, 31(10):773-780 doi: 10.11901/1005.3093.2016.779
7. [7]
  Liu X L, Wang P, Zhang Q Q, et al. Appl. Surf. Sci., 2018, 459:422-429 doi: 10.1016/j.apsusc.2018.08.024
8. [8]
  He H Y, He Z, Shen Q. Int. J. Hydrogen Energy, 2018, 43(48):21835-21843 doi: 10.1016/j.ijhydene.2018.10.023
9. [9]
  Cho J S, Park S K, Jeon K M, et al. Appl. Surf. Sci., 2018, 459:309-317 doi: 10.1016/j.apsusc.2018.07.200
10. [10]
  Ren X P, Ma Q, Ren P Y, et al. Int. J. Hydrogen Energy, 2018, 43(32):15275-15280 doi: 10.1016/j.ijhydene.2018.06.122
11. [11]
  Ganesan V, Kim J, Radhakrishnan S. ChemElectroChem, 2018, 5(13):1644-1651 doi: 10.1002/celc.201800381
12. [12]
  Boppella R, Tan J, Yang W, et al. Adv. Funct. Mater., 2019, 29(6):1-9
13. [13]
  Darband G B, Aliofkhazraei M, Rouhaghdam A S, et al. Appl. Surf. Sci., 2019, 465:846-862 doi: 10.1016/j.apsusc.2018.09.204
14. [14]
  Ye S H, Li G R. Front. Chem. Sci. Eng., 2018, 12(3):473-480
15. [15]
  Edison T N J I, Atchudan R, Lee Y R. Int. J. Hydrogen Energy, 2019, 44(4):2323-2329 doi: 10.1016/j.ijhydene.2018.02.018
16. [16]
  Nazir R, Basak U, Pande S. Colloids Surf. A, 2019, 560:141-148 doi: 10.1016/j.colsurfa.2018.10.009
17. [17]
  Liu W J, Bao J, Guan M L, et al. Dalton Trans., 2017, 46(26):8372-8376 doi: 10.1039/C7DT00906B
18. [18]
  Waghmode B J, Gaikwad A P, Rode C V, et al. ACS Sustainable Chem. Eng., 2018, 6(8):9649-9660 doi: 10.1021/acssuschemeng.7b04788
19. [19]
  Weng T C, Teng H. J. Electrochem. Soc., 2001, 148(4):A368-A373 doi: 10.1149/1.1357171
20. [20]
  Koper M T M. Electrochim. Acta, 2011, 56(28):10645-10651 doi: 10.1016/j.electacta.2011.02.001
21. [21]
  Kong X, Xu K, Zhang C, et al. ACS Catal., 2016, 6(3):1487-1492 doi: 10.1021/acscatal.5b02730
22. [22]
23. [23]
  Zhu L L, Cai Q, Liao F, et al. Electrochem. Commun., 2015, 52:29-33 doi: 10.1016/j.elecom.2015.01.012
1. [1]
  Wenxiu Yang , Jinfeng Zhang , Quanlong Xu , Yun Yang , Lijie Zhang . Bimetallic AuCu Alloy Decorated Covalent Organic Frameworks for Efficient Photocatalytic Hydrogen Production. Acta Physico-Chimica Sinica, 2024, 40(10): 2312014-. doi: 10.3866/PKU.WHXB202312014
2. [2]
  Kai CHEN , Fengshun WU , Shun XIAO , Jinbao ZHANG , Lihua ZHU . PtRu/nitrogen-doped carbon for electrocatalytic methanol oxidation and hydrogen evolution by water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1357-1367. doi: 10.11862/CJIC.20230350
3. [3]
  Hao GUO , Tong WEI , Qingqing SHEN , Anqi HONG , Zeting DENG , Zheng FANG , Jichao SHI , Renhong LI . Electrocatalytic decoupling of urea solution for hydrogen production by nickel foam-supported Co₉S₈/Ni₃S₂ heterojunction. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2141-2154. doi: 10.11862/CJIC.20240085
4. [4]
  Wenjiang LI , Pingli GUAN , Rui YU , Yuansheng CHENG , Xianwen WEI . C₆₀-MoP-C nanoflowers van der Waals heterojunctions and its electrocatalytic hydrogen evolution performance. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 771-781. doi: 10.11862/CJIC.20230289
5. [5]
  Xi YANG , Chunxiang CHANG , Yingpeng XIE , Yang LI , Yuhui CHEN , Borao WANG , Ludong YI , Zhonghao HAN . Co-catalyst Ni₃N supported Al-doped SrTiO₃: Synthesis and application to hydrogen evolution from photocatalytic water splitting. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 440-452. doi: 10.11862/CJIC.20240371
6. [6]
  Qin Li , Huihui Zhang , Huajun Gu , Yuanyuan Cui , Ruihua Gao , Wei-Lin Dai . In situ Growth of Cd_0.5Zn_0.5S Nanorods on Ti₃C₂ MXene Nanosheet for Efficient Visible-Light-Driven Photocatalytic Hydrogen Evolution. Acta Physico-Chimica Sinica, 2025, 41(4): 100031-. doi: 10.3866/PKU.WHXB202402016
7. [7]
  Fangfang WANG , Jiaqi CHEN , Weiyin SUN . CuBi@Cu-MOF composite catalysts for electrocatalytic CO₂ reduction to HCOOH. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 97-104. doi: 10.11862/CJIC.20240350
8. [8]
  Lina Guo , Ruizhe Li , Chuang Sun , Xiaoli Luo , Yiqiu Shi , Hong Yuan , Shuxin Ouyang , Tierui Zhang . 层状双金属氢氧化物的层间阴离子对衍生的Ni-Al₂O₃催化剂光热催化CO₂甲烷化反应的影响. Acta Physico-Chimica Sinica, 2025, 41(1): 2309002-. doi: 10.3866/PKU.WHXB202309002
9. [9]
  Yang WANG , Xiaoqin ZHENG , Yang LIU , Kai ZHANG , Jiahui KOU , Linbing SUN . Mn single-atom catalysts based on confined space: Fabrication and the electrocatalytic oxygen evolution reaction performance. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2175-2185. doi: 10.11862/CJIC.20240165
10. [10]
  Linjie ZHU , Xufeng LIU . Electrocatalytic hydrogen evolution performance of tetra-iron complexes with bridging diphosphine ligands. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 321-328. doi: 10.11862/CJIC.20240207
11. [11]
  Zhengyu Zhou , Huiqin Yao , Youlin Wu , Teng Li , Noritatsu Tsubaki , Zhiliang Jin . Synergistic Effect of Cu-Graphdiyne/Transition Bimetallic Tungstate Formed S-Scheme Heterojunction for Enhanced Photocatalytic Hydrogen Evolution. Acta Physico-Chimica Sinica, 2024, 40(10): 2312010-. doi: 10.3866/PKU.WHXB202312010
12. [12]
  Runhua Chen , Qiong Wu , Jingchen Luo , Xiaolong Zu , Shan Zhu , Yongfu Sun . 缺陷态二维超薄材料用于光/电催化CO₂还原的基础与展望. Acta Physico-Chimica Sinica, 2025, 41(3): 2308052-. doi: 10.3866/PKU.WHXB202308052
13. [13]
  Xin Zhou , Zhi Zhang , Yun Yang , Shuijin Yang . A Study on the Enhancement of Photocatalytic Performance in C/Bi/Bi₂MoO₆ Composites by Ferroelectric Polarization: A Recommended Comprehensive Chemical Experiment. University Chemistry, 2024, 39(4): 296-304. doi: 10.3866/PKU.DXHX202310008
14. [14]
  Zelong LIANG , Shijia QIN , Pengfei GUO , Hang XU , Bin ZHAO . Synthesis and electrocatalytic CO₂ reduction performance of metal-organic framework catalysts loaded with silver particles. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 165-173. doi: 10.11862/CJIC.20240409
15. [15]
  Qing Li , Yumei Feng , Yingjie Yu , Yazhou Chen , Yuhua Xie , Fang Luo , Zehui Yang . Engineering e_g filling of RuO₂ enables a robust and stable acidic water oxidation. Chinese Chemical Letters, 2025, 36(3): 110612-. doi: 10.1016/j.cclet.2024.110612
16. [16]
  Xinyu Miao , Hao Yang , Jie He , Jing Wang , Zhiliang Jin . 调整Keggin型多金属氧酸盐电子结构构建S型异质结用于光催化析氢. Acta Physico-Chimica Sinica, 2025, 41(6): 100051-. doi: 10.1016/j.actphy.2025.100051
17. [17]
  Hongyi Zhang , Zhihong Shi , Zhijun Zhang . A New Strategy for “De-formulized” Calculation of Dynamic Buffer Capacity in Analytical Chemistry Education. University Chemistry, 2024, 39(3): 390-394. doi: 10.3866/PKU.DXHX202309030
18. [18]
  Qin Hu , Liuyun Chen , Xinling Xie , Zuzeng Qin , Hongbing Ji , Tongming Su . Ni掺杂构建电子桥及激活MoS₂惰性基面增强光催化分解水产氢. Acta Physico-Chimica Sinica, 2024, 40(11): 2406024-. doi: 10.3866/PKU.WHXB202406024
19. [19]
  Jianyin He , Liuyun Chen , Xinling Xie , Zuzeng Qin , Hongbing Ji , Tongming Su . ZnCoP/CdLa₂S₄肖特基异质结的构建促进光催化产氢. Acta Physico-Chimica Sinica, 2024, 40(11): 2404030-. doi: 10.3866/PKU.WHXB202404030
20. [20]
  Ran Yu , Chen Hu , Ruili Guo , Ruonan Liu , Lixing Xia , Cenyu Yang , Jianglan Shui . 杂多酸H₃PW₁₂O₄₀高效催化MgH₂储氢. Acta Physico-Chimica Sinica, 2025, 41(1): 2308032-. doi: 10.3866/PKU.WHXB202308032

Get Citation

PDF

XML

Metrics

PDF Downloads(4)
Abstract views(737)
HTML views(173)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Preparation of Ni-Co/RuO2 Composite Electrode and Electrocatalytic Activity for Hydrogen Evolution

Metrics

通讯作者: 陈斌, bchen63@163.com

Preparation of Ni-Co/RuO₂ Composite Electrode and Electrocatalytic Activity for Hydrogen Evolution