Citation: YANG Zong-Fei, MU Qiu-Shui, WANG Ya-Ping, MA Peng-Tao, WANG Jing-Ping, NIU Jing-Yang. Synthesis, Structure and Properties of a Sandwich-Type Polyoxomolybdate Containing Mixed-Valence Antimony[J]. Chinese Journal of Inorganic Chemistry, ;2019, 35(11): 2101-2107. doi: 10.11862/CJIC.2019.245 shu

Synthesis, Structure and Properties of a Sandwich-Type Polyoxomolybdate Containing Mixed-Valence Antimony

Henan Key Laboratory of Polyoxometalate Chemistry, Institute of Molecular and Crystal Engineering, College of Chemistry and Chemical Engineering, Henan University, Kaifeng, Henan 475004, China

Corresponding author: WANG Jing-Ping, jpwang@henu.edu.cn NIU Jing-Yang, jyniu@henu.edu.cn
Received Date: 14 September 2019
Revised Date: 11 October 2019

Figures(5)

A novel heteropolymolybdate containing mixed-valence antimony[(CH₃)₄N]₈Na₄₁H₁₇[(Sb^Ⅲ₃O₃)(Sb^ⅤMo₆O₂₄)₂]₆ ·162H₂O (1) has been successfully synthesized by reaction of (NH₄)₆Mo₇O₂₄·4H₂O, Sb₂O₃ and Sb₂O₅ in a conventional aqueous method. This structure was structurally characterized by single-crystal X-ray diffraction, TG analysis, PXRD and IR spectrum. The results show that compound 1 contains a sandwich polyoxoanion[(Sb₃O₃)(SbMo₆O₂₄)₂]^11-, and further forms a two-dimensional structure through Na⁺ connection. In addition, compound 1 also exhibits intriguing allochroic properties. It can change color from yellowy to cyan yellow/sepia when heated or irradiated by Xe lamp (full wave-band, P=300 W).
- polyoxometalates,
- sandwich type,
- crystal structure,
- allochroic properties
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