Citation: HAN Yong-Fang, CAI Li-Zhen, GUO Guo-Cong. Bi-functional Lanthanide Compounds: Synthesis, Structures, Magnetism and Fluorescence[J]. Chinese Journal of Inorganic Chemistry, ;2019, 35(11): 2117-2124. doi: 10.11862/CJIC.2019.229 shu

Bi-functional Lanthanide Compounds: Synthesis, Structures, Magnetism and Fluorescence

1.
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China
2.
University of Chinese Academy of Sciences, Beijing 100039, China

Corresponding author: CAI Li-Zhen, clz@fjirsm.ac.cn GUO Guo-Cong, gcguo@fjirsm.ac.cn
Received Date: 2 July 2019
Revised Date: 17 September 2019

Figures(7)

Two isostructural lanthanide (Ln) compounds with N-succinopyridine (HL) ligand, namely[Ln(HL)₂(H₂O)₄]Cl₃ (Ln=Pr (1), Eu (2)), have been synthesized and structurally characterized. Both 1 and 2 feature 1D chains with metal ions double-bridged by carboxyl ligands, which are further interconnected through hydrogen bonds to yield a 3D supramolecular architecture. Variable temperature magnetic susceptibility measurements revealed the presence of antiferromagnetic interaction between Pr(Ⅲ) ions for 1 but weak ferromagnetic interactions between Eu(Ⅲ) ions for 2. Solid-state luminescence measurement showed that 2 emitted intense red luminescence, but no characteristic peak of 1 was observed due to the large energy gap of the Pr(Ⅲ) ion.
- lanthanide,
- N-succinopyridine,
- bi-functional compound,
- magnetism,
- luminescence
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1.
沈阳化工大学材料科学与工程学院沈阳 110142