Citation: HAN Yong-Fang, CAI Li-Zhen, GUO Guo-Cong. Bi-functional Lanthanide Compounds: Synthesis, Structures, Magnetism and Fluorescence[J]. Chinese Journal of Inorganic Chemistry, ;2019, 35(11): 2117-2124. doi: 10.11862/CJIC.2019.229 shu

Bi-functional Lanthanide Compounds: Synthesis, Structures, Magnetism and Fluorescence

1.
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China
2.
University of Chinese Academy of Sciences, Beijing 100039, China

Corresponding author: CAI Li-Zhen, clz@fjirsm.ac.cn GUO Guo-Cong, gcguo@fjirsm.ac.cn
Received Date: 2 July 2019
Revised Date: 17 September 2019

Figures(7)

Two isostructural lanthanide (Ln) compounds with N-succinopyridine (HL) ligand, namely[Ln(HL)₂(H₂O)₄]Cl₃ (Ln=Pr (1), Eu (2)), have been synthesized and structurally characterized. Both 1 and 2 feature 1D chains with metal ions double-bridged by carboxyl ligands, which are further interconnected through hydrogen bonds to yield a 3D supramolecular architecture. Variable temperature magnetic susceptibility measurements revealed the presence of antiferromagnetic interaction between Pr(Ⅲ) ions for 1 but weak ferromagnetic interactions between Eu(Ⅲ) ions for 2. Solid-state luminescence measurement showed that 2 emitted intense red luminescence, but no characteristic peak of 1 was observed due to the large energy gap of the Pr(Ⅲ) ion.
- lanthanide,
- N-succinopyridine,
- bi-functional compound,
- magnetism,
- luminescence
1. [1]
  Bi Y, Wang X T, Liao W, et al. Inorg. Chem., 2009, 48(24):11743-11747 doi: 10.1021/ic9017807
2. [2]
  Cucinotta G, Perfetti M, Luzon J, et al. Angew. Chem. Int. Ed., 2012, 51(7):1606-1610 doi: 10.1002/anie.201107453
3. [3]
  Bi Y, Chen C, Zhao Y F, et al. Chem. Sci., 2016, 7(8):5020-5031 doi: 10.1039/C6SC01157H
4. [4]
  Long J, Guari Y, Ferreira R A S, et al. Coord. Chem. Rev., 2018, 363:57-70 doi: 10.1016/j.ccr.2018.02.019
5. [5]
  Liddle S T, Slageren J J. Chem. Soc. Rev., 2015, 44(19):6655-6669 doi: 10.1039/C5CS00222B
6. [6]
  Eliseeva S V, Bunzli J C. Chem. Soc. Rev., 2010, 39(1):189-227 doi: 10.1039/B905604C
7. [7]
  Bunzli J C. Chem. Rev., 2010, 110(5):2729-2755 doi: 10.1021/cr900362e
8. [8]
  Pointillart F, Guennic B L, Cador O, et al. Acc. Chem. Res., 2015, 48(11):2834-2842 doi: 10.1021/acs.accounts.5b00296
9. [9]
  Pointillart F, Cador O, Guennic B L, et al. Coord. Chem. Rev., 2017, 346:150-175 doi: 10.1016/j.ccr.2016.12.017
10. [10]
  Hareri M A, Gavey E L, Regier J, et al. Chem. Commun., 2016, 52(76):11335-11338 doi: 10.1039/C6CC03578G
11. [11]
  Long J, Rouquette J, Thibaud J M, et al. Angew. Chem. Int. Ed., 2015, 54(7):2236-2240 doi: 10.1002/anie.201410523
12. [12]
  Guillou O, Daiguebonne C, Calvez G, et al. Acc. Chem. Res., 2016, 49(5):844-856 doi: 10.1021/acs.accounts.6b00058
13. [13]
  Wu J W, Zhang H B, Du S W. J. Mater. Chem. C, 2016, 4(16):3364-3374 doi: 10.1039/C5TC04432D
14. [14]
  Cai L Z, Wang M S, Zhang M J, et al. CrystEngComm, 2012, 14(19):6196-6200 doi: 10.1039/c2ce25755f
15. [15]
  Cai L Z, Wang M S, Wang S H, et al. CrystEngComm, 2013, 15(38):7670-7679 doi: 10.1039/c3ce41050a
16. [16]
  Kotov V Y, Gorbunova Y G, Kostina S A, et al. Mendeleev Commun., 2001, 11(5):181-182 doi: 10.1070/MC2001v011n05ABEH001464
17. [17]
  CrystalClear, Ver. 1.35, Software User's Guide for the Rigaku R-Axis, and Mercury and Jupiter CCD Automated X-ray Imaging System, Rigaku Molecular Structure Corporation: UT, 2002.
18. [18]
  SHELXTL Reference Manual, Ver. 5, Siemens Energy & Automation Inc.: Madison, WI, 1994.
19. [19]
  Chen F, Wang J, Dong M W, et al. J. Mol. Struct., 2019, 1177:117-123 doi: 10.1016/j.molstruc.2018.09.032
20. [20]
  Yuan G, Zhang C, Shao K Z, et al. Inorg. Chem. Commun., 2019, 99:126-130 doi: 10.1016/j.inoche.2018.11.017
21. [21]
  Wang Y, Xing S H, Bai F Y, et al. Inorg. Chem., 2018, 57(20):12850-12859 doi: 10.1021/acs.inorgchem.8b02050
22. [22]
  Zhou X, Wang H, Jiang S, et al. Inorg. Chem., 2019, 58(6):3780-3788 doi: 10.1021/acs.inorgchem.8b03319
23. [23]
  Wang Z X, Wu Q F, Liu H J, et al. CrystEngComm, 2010, 12(4):1139-1146 doi: 10.1039/B910701K
1. [1]
  Ting WANG , Peipei ZHANG , Shuqin LIU , Ruihong WANG , Jianjun ZHANG . A Bi-CP-based solid-state thin-film sensor: Preparation and luminescence sensing for bioamine vapors. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1615-1621. doi: 10.11862/CJIC.20240134
2. [2]
  Xiaxia LIU , Xiaofang MA , Luxia GUO , Xianda HAN , Sisi FENG . Structure and magnetic properties of Mn(Ⅱ) coordination polymers regulated by N-auxiliary ligands. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 587-596. doi: 10.11862/CJIC.20240269
3. [3]
  Yueyue WEI , Xuehua SUN , Hongmei CHAI , Wanqiao BAI , Yixia REN , Loujun GAO , Gangqiang ZHANG , Jun ZHANG . Two Ln-Co (Ln=Eu, Sm) metal-organic frameworks: Structures, magnetism, and fluorescent sensing sulfasalazine and glutaraldehyde. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2475-2485. doi: 10.11862/CJIC.20240193
4. [4]
  Yanfen PENG , Xinyue WANG , Tianbao LIU , Xiaoshuo WU , Yujing WEI . Syntheses and luminescence of four Cd(Ⅱ)/Zn(Ⅱ) complexes constructed by 1,3‐bis(4H‐1,2,4‐triazole)benzene. Chinese Journal of Inorganic Chemistry, 2025, 41(7): 1416-1426. doi: 10.11862/CJIC.20250018
5. [5]
  Wanting CHEN , Chufei MIAO , Yan LIU , Bobi ZHENG , Xiaoyu ZHENG , Han XU , Jumei TIAN . Syntheses, characterization, and luminescence properties of Yb(Ⅲ)-based one-dimensional chain coordination polymer. Chinese Journal of Inorganic Chemistry, 2025, 41(8): 1672-1680. doi: 10.11862/CJIC.20250013
6. [6]
  Ning LI , Siyu DU , Xueyi WANG , Hui YANG , Tao ZHOU , Zhimin GUAN , Peng FEI , Hongfang MA , Shang JIANG . Preparation and efficient catalysis for olefins epoxidation of a polyoxovanadate-based hybrid. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 799-808. doi: 10.11862/CJIC.20230372
7. [7]
  Huaihao CHEN , Lingwen ZHANG , Yukun CHEN , Jianjun ZHANG . A water-stable metal-organic framework probe for Al³⁺/Ga³⁺/In³⁺ detection. Chinese Journal of Inorganic Chemistry, 2025, 41(12): 2601-2608. doi: 10.11862/CJIC.20250184
8. [8]
  Hao Jiang , Yuan-Yuan He , Hai-Chao Liang , Meng-Jia Shang , Han-Han Lu , Chun-Hua Liu , Yin-Shan Meng , Tao Liu , Yuan-Yuan Zhu . Tuning lanthanide luminescence from bipyridine-bis(oxazoline/thiazoline) tetradentate ligands. Chinese Journal of Structural Chemistry, 2024, 43(9): 100354-100354. doi: 10.1016/j.cjsc.2024.100354
9. [9]
  Xin XIONG , Qian CHEN , Quan XIE . First principles study of the photoelectric properties and magnetism of La and Yb doped AlN. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1519-1527. doi: 10.11862/CJIC.20240064
10. [10]
  Xinxin YU , Yongxing LIU , Xiaohong YI , Miao CHANG , Fei WANG , Peng WANG , Chongchen WANG . Photocatalytic peroxydisulfate activation for degrading organic pollutants over the zero-valent iron recovered from subway tunnels. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 864-876. doi: 10.11862/CJIC.20240438
11. [11]
  Hongjie SHEN , Haozhe MIAO , Yuhe YANG , Yinghua LI , Deguang HUANG , Xiaofeng ZHANG . Synthesis, crystal structure, and fluorescence properties of two Cu(Ⅰ) complexes based on pyridyl ligand. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 855-863. doi: 10.11862/CJIC.20250009
12. [12]
  Tong WANG , Xuefang ZHU , Qi GAO , Hongbo ZHANG , Chao REN , Lixia GE . Luminescence and thermal stability of Tb³⁺-Eu³⁺ doped glass-ceramics containing Na_8.12Y_1.293Si₆O₁₈ crystal phase. Chinese Journal of Inorganic Chemistry, 2025, 41(11): 2237-2250. doi: 10.11862/CJIC.20250137
13. [13]
  Yadan SUN , Xinfeng LI , Qiang LIU , Oshio Hiroki , Yinshan MENG . Structures and magnetism of dinuclear Co complexes based on imine derivatives. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2212-2220. doi: 10.11862/CJIC.20240131
14. [14]
  Jun-Jie Fang , Yun-Peng Xie , Xing Lu . Organooxotin and cobalt/manganese heterometallic nanoclusters exhibiting single-molecule magnetism. Chinese Journal of Structural Chemistry, 2025, 44(4): 100515-100515. doi: 10.1016/j.cjsc.2025.100515
15. [15]
  Hong-Qiang Dong , Shang-Bo Yu , Shu-Meng Wang , Jia-Hao Zhao , Xu-Guan Bai , Shi-Xing Lei , Zhen-Nan Tian , Jia Tian , Kang-Da Zhang , Lu Wang , Zhan-Ting Li , Shigui Chen . Construction of radical halogen-bonded organic frameworks with enhanced magnetism and conductivity. Chinese Chemical Letters, 2025, 36(8): 110730-. doi: 10.1016/j.cclet.2024.110730
16. [16]
  Hai-Ling Wang , Zhong-Hong Zhu , Hua-Hong Zou . Structure and assembly mechanism of high-nuclear lanthanide-oxo clusters. Chinese Journal of Structural Chemistry, 2024, 43(9): 100372-100372. doi: 10.1016/j.cjsc.2024.100372
17. [17]
  Zhengzhong Zhu , Shaojun Hu , Zhi Liu , Lipeng Zhou , Chongbin Tian , Qingfu Sun . A cationic radical lanthanide organic tetrahedron with remarkable coordination enhanced radical stability. Chinese Chemical Letters, 2025, 36(2): 109641-. doi: 10.1016/j.cclet.2024.109641
18. [18]
  Jinjiang Wu , Zhenhua Zhu , Jinkui Tang . Recent advancements of photo-responsive lanthanide single-molecule magnets. Chinese Chemical Letters, 2025, 36(12): 110577-. doi: 10.1016/j.cclet.2024.110577
19. [19]
  Juanjuan Wang , Fang Wang , Bin Qin , Yue Wu , Huan Yang , Xiaolong Li , Lanfang Wang , Xiufang Qin , Xiaohong Xu . Controlled synthesis and excellent magnetism of ferrimagnetic NiFe₂Se₄ nanostructures. Chinese Chemical Letters, 2024, 35(11): 109449-. doi: 10.1016/j.cclet.2023.109449
20. [20]
  Shihong Wu , Ronghui Zhou , Hang Zhao , Peng Wu . Sonoafterglow luminescence for in vivo deep-tissue imaging. Chinese Chemical Letters, 2024, 35(10): 110026-. doi: 10.1016/j.cclet.2024.110026

Get Citation

PDF

XML

Metrics

PDF Downloads(3)
Abstract views(1602)
HTML views(110)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142