Citation: CHEN Hui-Xian, LIU Chun-Yu, ZHOU Xuan, CHEN Min-Min, NI Chun-Yan, LANG Jian-Ping. One-Dimensional Coordination Polymers Based on a Tripyridine Olefin Ligand: Synthesis, Structures and Photoelectronic Properties[J]. Chinese Journal of Inorganic Chemistry, ;2019, 35(11): 2038-2044. doi: 10.11862/CJIC.2019.228 shu

One-Dimensional Coordination Polymers Based on a Tripyridine Olefin Ligand: Synthesis, Structures and Photoelectronic Properties

Suzhou Key Laboratory of Precision Transformation of Resource Molecules, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou, Jiangsu 215123, China

Corresponding author: LIU Chun-Yu, 928483592@qq.com NI Chun-Yan, chunyan89.ok@163.com LANG Jian-Ping, jplang@suda.edu.cn
Received Date: 2 August 2019
Revised Date: 12 September 2019

Figures(6)

The reactions of dipyridin-2-yl-(4-(2-pyridin-4-yl-vinyl)-phenyl)-amine (ppvppa) with various silver(Ⅰ) salts afforded three one-dimensional (1D) coordination polymers {[Ag(ppvppa)]BF₄}_n (1), {[Ag(ppvppa)]PF₆}_n (2) and {[Ag(ppvppa)]NO₃}_n (3). When analogous reactions of ppvppa with Ni(Ⅱ) salt was carried out under solvothermal conditions, another 1D coordination polymer {[Ni(ppvppa)(2, 3-NDC)(H₂O)]·2H₂O}_n (4) was obtained. Complexes 1~4 were characterized by elemental analysis, infrared spectrum (IR), thermogravimetric analysis (TGA), powder X-ray diffraction (PXRD) and single crystal X-ray diffraction. Complexes 1~3 have similar 1D cationic chain structures in which the dimeric[Ag(ppvppa)]₂ units are interconnected by ppvppa ligands. Complex 4 holds a double chain structure in which the[Ni₂(ppvppa)₂(H₂O)₂] units are interlinked by pairs of 2, 3-NDC ligands. In the solid state, Ag(Ⅰ)-based complexes 1~3 showed good luminescent properties while no luminescence was observed for Ni(Ⅱ)-based complex 4. Complexes 1 and 4 as representative samples showed relatively prompt, rapid anodic photocurrent responses, which were steady and reproducible after ten on/off cycles. The photocurrent values were calculated to be 2 μA for 1 and 6 μA for 4, respectively, which were greater than that observed for a blank ITO electrode.
- coordination polymers,
- crystal structures,
- fluorescence properties,
- photocurrent responses
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