Citation: LIU Zhi-Qiang, CAO Shi-Hu, ZHANG Zhe, WU Jun-Feng, ZHAO Yue, SUN Wei-Yin. Metal-Organic Frameworks with 2, 6-Di(1H-imidazol-1-yl)naphthalene and Dicarboxylate Ligands: Synthesis, Crystal Structure and Photoluminescence Sensing Property[J]. Chinese Journal of Inorganic Chemistry, ;2019, 35(11): 2145-2151. doi: 10.11862/CJIC.2019.225 shu

Metal-Organic Frameworks with 2, 6-Di(1H-imidazol-1-yl)naphthalene and Dicarboxylate Ligands: Synthesis, Crystal Structure and Photoluminescence Sensing Property

LIU Zhi-Qiang ^1,2 ,
CAO Shi-Hu ¹ ,
ZHANG Zhe ¹ ,
WU Jun-Feng ¹ ,
ZHAO Yue ² ,
SUN Wei-Yin ^2,,

1.
School of Chemistry and Chemical Engineering, Anhui Province Key Laboratory of Functional Optical, Electrical and Magnetic Materials, Key Laboratory of Functional Coordination Compounds and Nano Materials of Anhui Higher Education Institutes, Anqing Normal University, Anqing, Anhui 246011, China
2.
State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210023, China

Corresponding author: SUN Wei-Yin, sunwy@nju.edu.cn
Received Date: 28 August 2019
Revised Date: 11 September 2019

Figures(6)

Reactions of 2, 6-di(1H-imidazol-1-yl)naphthalene (L) and dicarboxylic acid ligands with corresponding metal salts under solvothermal conditions gave rise to three new metal-organic frameworks (MOFs)[Co(L)(AIP)]·2DMF (1), [Co(L)(AIP)]·DMF (2) and[Co(L)(IDC)(H₂O)₂]·0.5L·H₂O (3) (H₂AIP=5-aminoisophthalic acid, H₂IDC=4, 4'-iminodibenzoic acid). The MOFs have been structurally characterized by single-crystal and powder X-ray diffraction analyses, elemental analyses, infrared spectra (IR) and thermogravimetric analysis (TGA). MOF 1 crystallizes in monoclinic space group C2/c, while 2 and 3 are triclinic space group P1. MOFs 1 and 3 have distinct infinite one-dimensional (1D) chain structures, and 2 is a two-dimensional (2D) network, which are further linked together by hydrogen bonding interactions to give the eventual three-dimensional (3D) supramolecular architectures. Furthermore, the thermal stability and photoluminescence property of the MOFs were investigated, and it was found that 3 can efficiently detect acetone molecules via fluorescent quenching.
- metal-organic frameworks,
- 2, 6-di(1H-imidazol-1-yl)naphthalene,
- crystal structure,
- photoluminescence property
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