Citation: ZHANG Mei-Li, ZHENG Yan-Jin, LIU Min, REN Yi-Xia, WANG Ji-Jiang, CUI Hua-Li, LIU Lin. Crystal Structure and Electrochemistry Properties of Three Co(Ⅱ) Complexes Based on Flexible Phenylenediacetate Ligands[J]. Chinese Journal of Inorganic Chemistry, ;2019, 35(10): 1813-1820. doi: 10.11862/CJIC.2019.214 shu

Crystal Structure and Electrochemistry Properties of Three Co(Ⅱ) Complexes Based on Flexible Phenylenediacetate Ligands

Department of Chemistry and Chemical Engineering, Shaanxi Key Laboratory of Chemical Reaction Engineering, Yan'an University, Yan'an, Shaanxi 716000, China

Corresponding author: ZHANG Mei-Li, ydzml2332041@163.com
Received Date: 12 April 2019
Revised Date: 2 August 2019

Figures(5)

Three new coordination complexes, {[Co_1.5(opda)_1.5(mbib)₂(H₂O)₂]·H₂O}_n (1), {[Co(mpda)(mbib)]·H₂O}_n (2) and {[Co(ppda)(mbib)]·H₂O}_n (3) (H₂opda=1, 2-phenylenediacetic acid, H₂mpda=1, 3-phenylenediacetic acid, H₂ppda=1, 4-phenylenediacetic acid, mbib=1, 3-bis(1-imidazoly)benzene), have been synthesized by using cobalt salt and bis(imidazole) ligand in the presence of different flexible phenylenediacetate blocks under hydrothermal conditions, and characterized by elemental analysis, IR spectroscopy and single-crystal X-ray crystallography. Single-crystal X-ray diffraction analysis revealed that the diverse structures of these complexes are mainly attributed to various coordination geometries of the central cobalt(Ⅱ) cations, coordination modes and conformations of the flexible phenylenediacetic acid and bis(imidazole) ligands. Furthermore, thermal gravimetric analysis (TGA) and the electrochemistry properties of 1~3 are also investigated, and all of them have good cyclic voltammograms.
- coordination polymer,
- crystal structure,
- electrochemistry property
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