Citation: XIONG Jun, TAN Mao-Kun, LÜ Shao-Fang, LI Ming, YANG Shui-Bin. Two Inorganic-Organic Hybrid Crystals Based on[SMo₁₂O₄₀]^2- Polyoxometallates and Supramolecular Cation: Syntheses and Crystal Structures[J]. Chinese Journal of Inorganic Chemistry, ;2019, 35(10): 1805-1812. doi: 10.11862/CJIC.2019.208 shu

Two Inorganic-Organic Hybrid Crystals Based on[SMo₁₂O₄₀]^2- Polyoxometallates and Supramolecular Cation: Syntheses and Crystal Structures

1.
Hubei Key Laboratory of Biomass Fibers and Eco-dyeing & Finishing, College of Chemistry and Chemical Engineering, Wuhan Textile University, Wuhan 430200, China
2.
Hubei Key Laboratory for Processing and Application of Catalytic Materials, College of Chemical Engineering, Huanggang Normal University, Huanggang, Hubei 438000, China

Corresponding author: LI Ming, lim@wtu.edu.cn YANG Shui-Bin, 2416975012@qq.com
Received Date: 4 March 2019
Revised Date: 29 July 2019

Figures(8)

Two inorganic-organic hybrids, [(4-I-Anis)([18]crown-6)]₂[SMo₁₂O₄₀]·CH₃CN (1) and[(3-F-4-Cl-Anis)₂(DB[30]crown-10)] [SMo₁₂O₄₀]·2CH₃CN (2) (4-I-Anis=4-iodoanilinium; 3-F-4-Cl-Anis=3-fluoro-4-chloroanilinium; DB[30]crown-10=dibenzo[30]crown-10) have been synthesized and characterized by infrared spectrum (IR), elemental analysis (EA), powder XRD, thermogravimetric (TG), solid state diffuse reflectance spectra (DRS) and X-ray diffraction. Crystals 1 and 2 are constructed through noncovalent bonding interaction, and the polyoxo-metalates and supramolecular cation arrange alternately. Supramolecular cation forms through the N-H…O hydrogen bonding interaction between the nitrogen atom of anilinium and oxygen atoms of crown ether derivatives. In crystal 1, each polyoxoanion is surrounded by six monovalent supramolecular cations (4-I-Anis)([18]crown-6) and forms hexagonal arrangement in bc plane. In crystal 2, each polyoxoanion is surrounded by four large supramolecular cations (3-F-4-Cl-Anis)₂(DB[30]crown-10) and forms tetragonal arrangement in bc plane. TG measurement indicated that hydrogen bonding interaction plays an important role in maintaining the structural stability of crystals 1 and 2. DRS indicated that there exists charge-transfer interaction between[SMo₁₂O₄₀]^2- polyoxoanions and crown ether based supramolecular cations in crystals 1 and 2.
- inorganic-organic hybrids,
- supramolecular self-assembled,
- polyoxometallates,
- crown ether,
- supramolecular cation
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Two Inorganic-Organic Hybrid Crystals Based on[SMo12O40]2- Polyoxometallates and Supramolecular Cation: Syntheses and Crystal Structures

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通讯作者: 陈斌, bchen63@163.com

Two Inorganic-Organic Hybrid Crystals Based on[SMo₁₂O₄₀]^2- Polyoxometallates and Supramolecular Cation: Syntheses and Crystal Structures