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Citation: MENG Guo-Xiang, TIAN Xiao-Xia, ZHANG Jia-Rui, ZHANG Xiang, HAN Feng-Qing, QU Shao-Bo. Effects of Donor-Doped on Photocatalytic Properties of BaTiO3-Based Nanoparticle[J]. Chinese Journal of Inorganic Chemistry, ;2019, 35(8): 1387-1395. doi: 10.11862/CJIC.2019.183 shu

Effects of Donor-Doped on Photocatalytic Properties of BaTiO3-Based Nanoparticle

  • 1.

    Cadet Brigade 1, School of Aeronautics and Astronautics Engineering, Air Force Engineering University, Xi'an 710051, China

  • 2.

    Department of Basic Sciences, Air Force Engineering University, Xi'an 710051, China

  • 3.

    Cadet Brigade 2, Air and Missile Defense College, Air Force Engineering University, Xi'an 710051, China

Figures(8)

  • Cu2O was synthesized by chemical precipitation, La doped BaTiO3-based powders were synthesized via a hydrothermal method using the Cu2O as the sacrifice template. The structure, morphology and visible light properties have been characterized by X-ray diffraction (XRD), transmission electron microscope (TEM), high-resolution transmission electron microscope (HR-TEM), X-ray photoelectron spectroscopy (XPS), scanning electron micro-graphs (SEM), UV-Vis diffuse reflectance spectrophotometer (UV-Vis DRS). The results showed that the doping of La3+ increased the conductivity and made the range of photo-response broadened, which reduced the band gap of the semiconductor and accelerated the separation of photo-generated electron hole pairs. The surface defects were induced with a facile and effective approach by La3+ ion doping, and the photocatalytic performance of BaTiO3 was improved. However, as the doping amount of La3+ ions increased, the band gap of the semiconductors decreased and the redox ability of the phototgenerated electrons and holes deceased when the dopant was excessive. When the doping amount was 4%(w/w), the photocatalytic performance of the sample was the best, and the degradation efficiency of 4-nitrophenol was 93.2% after 360 min visible light irradiation. The decomposition rate of 4-nitrophenol was still above 86.7% even after 5 cycles, thus artificial catalytic defects of La donor-doped BaTiO3-based nanoparticle could effectively improve the photocatalytic properties.
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    1. [1]

      CAI Tian-Yi, JU Sheng. Acta Phys. Sin., 2018, 67(15):157801  doi: 10.7498/aps.67.20180979

    2. [2]

      Anisimov V I, Zaanen J, Andersen O K. Phys. Rev. B, 1991, 44:943-954  doi: 10.1103/PhysRevB.44.943

    3. [3]

      Yang S Y, Seidel J, Byrnes S J, et al. Nat. Nanotechnol., 2010, 5:143-147  doi: 10.1038/nnano.2009.451

    4. [4]

      Brody P S, Crowne F. J. Mater. Sci., 1975, 4:955-971
       

    5. [5]

      Glass A M, Linde D V D, Negran T J. Appl. Phys. Lett., 1974, 25:233-235  doi: 10.1063/1.1655453

    6. [6]

      Tada H, Jin Q, Nishijima H, et al. Angew. Chem. Int. Ed., 2011, 50(15):3501-3505  doi: 10.1002/anie.201007869

    7. [7]

      Ichiki M, Maeda R, Morikawa Y, et al. Jpn. J. Appl. Phys., 2005, 44(98):6927-6933

    8. [8]

      Xu T G, Zhang L W, Cheng H Y, et al. Appl. Catal. B, 2011, 101(3/4):382-387
       

    9. [9]

      Zhang N, Gao C, Xiong Y. J. Energy Chem., 2019, 37(10):43-57

    10. [10]

      Bai S, Zhang N, Gao C, et al. Nano Energy, 2018, 53(11):296-336
       

    11. [11]

      Sun S D, Yang Z M. Chem. Commun., 2014, 50(56):7403-7415  doi: 10.1039/c4cc00304g

    12. [12]

      LIU Guo-Cun, JIN Zhen, ZHANG Xi-Bin, et al. The Chinese Journal of Nonferrous Metals, 2013, 23(3):1004-0609
       

    13. [13]

      Reddy B P, Sekhar M C, Prakash B P, et al. Ceram. Int., 2018, 44(16):19512-19521  doi: 10.1016/j.ceramint.2018.07.191

    14. [14]

      Venkata S P, Patrick L, Shiva A, et al. J. Adv. Ceram., 2015, 5(3):1550027
       

    15. [15]

      Kurata N, Kuwabara M. J. Ceram. Soc. Jpn., 1997, 105(5):436-439

    16. [16]

      XIA Chang-Tai, ZHONG Wei-Zhuo. J. Inorg. Mater., 1995(3):293-300
       

    17. [17]

      ZHAI Xue-Liang. Journal of the Chinese Ceramic Society, 2000, 28(4):358-360
       

    18. [18]

      WANG Wei-Peng, YANG Hua, XIAN Tao, et al. Chinese Journal of Catalysis, 2012, 33:354-359
       

    19. [19]

      REN Zheng-Ling, LU Chen-Yang, WANG An-Jie, et al. CIESC Journal, 2017, 68(6):2611-2617
       

    20. [20]

      Zhang Y, Deng B, Zhang T R, et al. J. Phys. Chem. C, 2010, 114(11):5073-5079  doi: 10.1021/jp9110037

    21. [21]

      Fang J X, Lebedkin S, Yang S C, et al. Chem. Commun., 2011, 47:5157-5159  doi: 10.1039/c1cc10328h

    22. [22]

      Qin Y, Che R C, Liang C Y, et al. J. Mater. Chem., 2011, 21:3960-3965  doi: 10.1039/c0jm03211e

    23. [23]

      Wang Z Y, Luan D Y, Li C M, et al. J. Am. Chem. Soc., 2010, 132:16271-16277  doi: 10.1021/ja107871r

    24. [24]

      Sun S D, Yang Q, Liang S H, et al. CrystEngComm, 2017, 19:6225-6251  doi: 10.1039/C7CE01530E

    25. [25]

      XIA Chang-Tai, SHI Er-Wei, ZHONG Wei-Zhuo. Chin. Sci. Bull., 1996, 41(5):471-474  doi: 10.3321/j.issn:0023-074X.1996.05.023

    26. [26]

      ZHOU Xue-Nong, CHEN Li-Sha, ZHAO Fang, et al. Journal of Synthetic Crystals, 1997, 26(3/4):362
       

    27. [27]

      MENG Wan-Wan, HU Rui-Sheng, YANG Jun, et al. Chinese Journal of Catalysis, 2016, 8:1283-1292
       

    28. [28]

      XU Qing-Qing, LÜ Liang, YE Dong-Ju, et al. Chinese J. Inorg. Chem., 2017, 33(7):1205-1216
       

    29. [29]

      Kishi H, Kohzu N, Sugino J, et al. J. Eur. Ceram. Soc., 1999, 19(6/7):1043-1046

    30. [30]

      Castro M S, Salgueiro W, Somoza A. J. Phys. Chem. Solids, 2007, 68(7):1315-1323  doi: 10.1016/j.jpcs.2007.02.017

    31. [31]

      Patio E, Stashans A. Comput. Mater. Sci., 2001, 22(3):137-143

    32. [32]

      YU Da-Shu, WANG Li-Qun, FENG Jia-Zhen. Journal of Tianjin Normal University:Natural Science Edition, 2002, 24(4):23-26

    33. [33]

      Smyth D M M, Translated by YAO Xi(姚熹), The Defect Chemistry of Metal Oxides(金属氧化物中的缺陷化学). Xi'an: Xi'an Jiaotong University Press, 2006, 11: 276-277

    34. [34]

      PU Yong-Ping(蒲永平). The Defect Chemistry of Functional Materials(功能材料的缺陷化学). Beijing: Chemical Industry Press, 2008, 4: 60-81

    35. [35]

      LU Yu-Dong, WANG Xin, ZHUANG Zhi-Qiang, et al. Chinese J. Inorg. Chem., 2007, 23(7):1234-1237  doi: 10.3321/j.issn:1001-4861.2007.07.019
       

    36. [36]

      Li G W, Blake G R, Palstra T T. Chem. Soc. Rev., 2017, 46:1693-1706  doi: 10.1039/C6CS00571C

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