Citation: ZHANG Meng-Yuan, YOU Xiao-Long, LIU Li-Jun, Maru Dessie Walle, LI Ya-Juan, LIU You-Nian. Biomass Derived Highly-Ordered Carbon Tube as Cathode Material for High Performance Lithium-Sulfur Batteries[J]. Chinese Journal of Inorganic Chemistry, ;2019, 35(8): 1493-1499. doi: 10.11862/CJIC.2019.178 shu

Biomass Derived Highly-Ordered Carbon Tube as Cathode Material for High Performance Lithium-Sulfur Batteries

ZHANG Meng-Yuan ^1,2,# ,
YOU Xiao-Long ^1,# ,
LIU Li-Jun ¹ ,
Maru Dessie Walle ¹ ,
LI Ya-Juan ^1,2,, ,
LIU You-Nian ^1,2,,

1.
College of Chemistry and Chemical Engineering, Central South University, Changsha 410083, China
2.
Hunan Provincial Key Laboratory of Chemical Power Sources, Central South University, Changsha 410083, China

Corresponding author: LI Ya-Juan, yajuanli@csu.edu.cn LIU You-Nian, liuyounian@csu.edu.cn

Received Date: 11 March 2019
Revised Date: 9 June 2019

Figures(3)

A novel highly ordered carbon tube (OCT) arrays derived from palm tree fiber by carbonization and activation with KOH was prepared and used as hosts for lithium sulfur battery. The OCT possessed large specific area and pore volume, which could effectively store sulfur. The method was clean, facile and low cost. Moreover, the S@OCT composite exhibited admirable electrochemical performances. The S@OCT with 65%(w/w) sulfur delivered an initial discharge capacity of 1 255.2 mAh·g^-1 (1.8 mAh·cm^-2) and retained 756.9 mAh·g^-1 (1.09 mAh·cm^-2) at the current rate of 0.2C after 100 cycles with a high coulomb efficiency. What's more, when tested at 5C, its initial capacity was up to 649.1 mAh·g^-1 (0.93 mA h·cm^-2) and retained 504.2 mAh·g¹ (0.72 mAh·cm^-2) after 100 cycles.
- lithium battery,
- sulfur electrode,
- biomass,
- carbon materials,
- high coulomb efficiency
1. [1]
  Borchardt L, Oschatz M, Kaskel S, et al. Chem. Eur. J., 2016, 22:7324-7351 doi: 10.1002/chem.201600040
2. [2]
  Maru D W, Zeng K, Zhang M Y, et al. J. Mater. Sci., 2018, 53:14608-14618 doi: 10.1007/s10853-018-2670-0
3. [3]
  Sohn H, Gordin M L, Regula M, et al. J. Power Sources, 2016, 302:70-78 doi: 10.1016/j.jpowsour.2015.10.013
4. [4]
  Gueon D, Hwang J, Yang S B, et al. ACS Nano, 2018, 12:226-233 doi: 10.1021/acsnano.7b05869
5. [5]
  Sun L, Wang D, Luo Y, et al. ACS Nano, 2015, 10(1):1300-1308
6. [6]
  Ji X L, Kyu T L, Linda F, et al. Nat. Mater., 2005, 8(6):500-506
7. [7]
  Bruce P G, Freunberger S A, Laurence J, et al. Nat. Mater., 2011, 11(1):19-29
8. [8]
  Shang X N, Guo P Q, Qin T F, et al. Adv. Mater. Interfaces, 2018, 5(7):1602-1610
9. [9]
  Jung J K, Hee S K, Jihoon A, et al. J. Power Sources, 2016, 306:617-622 doi: 10.1016/j.jpowsour.2015.12.093
10. [10]
  Yang W, Yang W, Song A, et al. J. Power Sources, 2017, 348:175-182 doi: 10.1016/j.jpowsour.2017.03.008
11. [11]
  Liu M, Jiang H R, Ren Y X, et al. Electrochim. Acta, 2016, 213:871-878 doi: 10.1016/j.electacta.2016.08.015
12. [12]
  Ghazi Z A, He X, Khattak A M, et al. Adv. Mater., 2017, 29(21):1606817-1606822 doi: 10.1002/adma.201606817
13. [13]
  Li J, Huang Y, Zhang S, et al. ACS Appl. Mater. Interfaces, 2017, 9(8):7499-7504 doi: 10.1021/acsami.7b00065
14. [14]
  Cheng X B, Huang J Q, Zhang Q J. Electrochem. Soc., 2018, 165(1):A6058-A6072 doi: 10.1149/2.0111801jes
15. [15]
  Suriyakumar S, Stephan A M, Angulakshmi N, et al. Electrochim Acta, 2018, 265:151-159 doi: 10.1016/j.electacta.2018.01.155
16. [16]
  Jayaprakash N, Shen J, Moganty S S, et al. Angew. Chem. Int. Ed., 2011, 50(26):5904-5908 doi: 10.1002/anie.201100637
17. [17]
  Xu G Y, Yan Q B, Kushima A, et al. Nano Energy, 2017, 31:568-574 doi: 10.1016/j.nanoen.2016.12.002
18. [18]
  Xu T, Song J, Gordin M L, et al. ACS Appl. Mater. Interfaces, 2013, 5(21):11355-11362 doi: 10.1021/am4035784
19. [19]
  Zhang Y Z, Zong X L, Zhan L, et al. Electrochim. Acta, 2018, 284:89-97 doi: 10.1016/j.electacta.2018.05.144
20. [20]
  Li X Y, Fu N Q, Zou J Z, et al. Mater. Lett., 2017, 209:505-508 doi: 10.1016/j.matlet.2017.08.083
21. [21]
  Maneerung T, Liew J, Dai Y J, et al. Bioresour. Technol., 2016, 200:350-359 doi: 10.1016/j.biortech.2015.10.047
22. [22]
  Li H, Riisager A, Saravanamurugan S, et al. ACS Catal., 2017, 8(1):148-187
23. [23]
  Xu X, Meng Z, Zhu X L, et al. J. Power Sources, 2018, 380:12-17 doi: 10.1016/j.jpowsour.2018.01.057
24. [24]
  Liu M, Chen Y, Chen K, et al. BioResources, 2014, 10(1):155-168
25. [25]
  Qu Y H, Zhang Z A, Zhang X H, et al. Carbon, 2015, 84(1):399-408
26. [26]
  Geng Z, Xiao Q F, Wang D B, et al. Electrochim. Acta, 2016, 202:131-139 doi: 10.1016/j.electacta.2016.03.176
27. [27]
  Chen F, Yang J, Bai T, et al. Electrochim. Acta, 2016, 192:99-109 doi: 10.1016/j.electacta.2016.01.192
28. [28]
  Zhang J, Xiang J Y, Dong Z M, et al. Electrochim. Acta, 2014, 116(2):146-151
29. [29]
  Zhao C J, Liu G Q, et al. Chem. Eng. J., 2018, 334:1270-1280 doi: 10.1016/j.cej.2017.11.069
30. [30]
  Zhang H M, Chen J Y, Li Y B, et al. Electrochim. Acta, 2015, 165:7-13 doi: 10.1016/j.electacta.2015.02.240
31. [31]
  You X L, Liu L J, Zhang M Y, et al. Mater. Lett., 2018, 217:167-170 doi: 10.1016/j.matlet.2018.01.096
32. [32]
  Li Y J, Zhan H, Liu S Q, et al. J. Power Sources, 2010, 195(9):2945-2949 doi: 10.1016/j.jpowsour.2009.11.004
33. [33]
  Li H P, Sun L C, Zhao Y, et al. Electrochim. Acta, 2019, 295:822-828 doi: 10.1016/j.electacta.2018.11.012
34. [34]
  Wang Z Y, Wang L, Liu S, et al. Adv. Funct. Mater., 2019, 1:1901051-1901061
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