Citation: ZHANG Meng-Yuan, YOU Xiao-Long, LIU Li-Jun, Maru Dessie Walle, LI Ya-Juan, LIU You-Nian. Biomass Derived Highly-Ordered Carbon Tube as Cathode Material for High Performance Lithium-Sulfur Batteries[J]. Chinese Journal of Inorganic Chemistry, ;2019, 35(8): 1493-1499. doi: 10.11862/CJIC.2019.178 shu

Biomass Derived Highly-Ordered Carbon Tube as Cathode Material for High Performance Lithium-Sulfur Batteries

ZHANG Meng-Yuan ^1,2,# ,
YOU Xiao-Long ^1,# ,
LIU Li-Jun ¹ ,
Maru Dessie Walle ¹ ,
LI Ya-Juan ^1,2,, ,
LIU You-Nian ^1,2,,

1.
College of Chemistry and Chemical Engineering, Central South University, Changsha 410083, China
2.
Hunan Provincial Key Laboratory of Chemical Power Sources, Central South University, Changsha 410083, China

Corresponding author: LI Ya-Juan, yajuanli@csu.edu.cn LIU You-Nian, liuyounian@csu.edu.cn

Received Date: 11 March 2019
Revised Date: 9 June 2019

Figures(3)

A novel highly ordered carbon tube (OCT) arrays derived from palm tree fiber by carbonization and activation with KOH was prepared and used as hosts for lithium sulfur battery. The OCT possessed large specific area and pore volume, which could effectively store sulfur. The method was clean, facile and low cost. Moreover, the S@OCT composite exhibited admirable electrochemical performances. The S@OCT with 65%(w/w) sulfur delivered an initial discharge capacity of 1 255.2 mAh·g^-1 (1.8 mAh·cm^-2) and retained 756.9 mAh·g^-1 (1.09 mAh·cm^-2) at the current rate of 0.2C after 100 cycles with a high coulomb efficiency. What's more, when tested at 5C, its initial capacity was up to 649.1 mAh·g^-1 (0.93 mA h·cm^-2) and retained 504.2 mAh·g¹ (0.72 mAh·cm^-2) after 100 cycles.
- lithium battery,
- sulfur electrode,
- biomass,
- carbon materials,
- high coulomb efficiency
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