Citation: YAO Shou-Guang, DOU Fei, XING Ru-Yue, CHENG Jie, XIAO Min. Rate Performance Analysis of Ni_1-xMn_x(OH)₂ as Cathode Material for Zinc-Nickel Single Flow Battery[J]. Chinese Journal of Inorganic Chemistry, ;2019, 35(8): 1403-1410. doi: 10.11862/CJIC.2019.177 shu

Rate Performance Analysis of Ni_1-xMn_x(OH)₂ as Cathode Material for Zinc-Nickel Single Flow Battery

YAO Shou-Guang ^1,, ,
DOU Fei ^1,2 ,
XING Ru-Yue ^1,2 ,
CHENG Jie ^2,3 ,
XIAO Min ¹

1.
School of Energy and Power Engineering, Jiangsu University of Science and Technology, Zhenjiang, Jiangsu 212003, China
2.
Zhangjiagang Smartgrid Fanghua Electrical Energy Storage Research Institute Co., Ltd., Suzhou, Jiangsu 215600, China
3.
Zhejiang Yuyuan Energy Storage Technology Co., Ltd., Huzhou, Zhejiang 313100, China

Corresponding author: YAO Shou-Guang, zjyaosg@126.com
Received Date: 30 March 2019
Revised Date: 30 June 2019

Figures(8)

Manganese-doped Ni_1-xMn_x(OH)₂ (x=0.1, 0.2, 0.3, 0.4) was prepared by buffer solution method. X-ray diffraction (XRD) measurements showed that the samples were mainly composed of β phase when x=0.1 and 0.2. Scanning electron microscopy (SEM) measurements and nitrogen adsorption-desorption showed that the Mn doped samples were finer and more porous than commercial β-Ni(OH)₂ samples without Mn. The constant current charge-discharge tests show that the material of Ni_0.8Mn_0.2(OH)₂ exhibited a high specific discharge capacity of 288.8 mAh·g^-1 at 800 mA·g^-1 when the specific discharge capacity of commercial β-Ni(OH)₂ was 198.7 mAh·g^-1. In addition, the electrodes have excellent cycle performance. When the Mn content x is 0.2, the material maintained a specific discharge capacity of 276 mAh·g^-1 after circulating 580 cycles at 800 mA·g^-1 with an attenuation rate of 4.1%, the attenuation rates of the others were 46.1% (commercial β-Ni(OH)₂), 13.0% (x=0.1), 22.6% (x=0.3) and 34.1% (x=0.4). This indicated that Mn doped Ni(OH)₂ can improve the cycling stability of nickel electrodes at high current density, and greatly reduce the cost of nickel electrodes.
- buffer solution method,
- Ni_1-xMn_x(OH)₂,
- rate performance,
- cyclic stability
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1.
沈阳化工大学材料科学与工程学院沈阳 110142

Rate Performance Analysis of Ni1-xMnx(OH)2 as Cathode Material for Zinc-Nickel Single Flow Battery

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Rate Performance Analysis of Ni_1-xMn_x(OH)₂ as Cathode Material for Zinc-Nickel Single Flow Battery