Citation: LIU Dong-Hai, WANG Jun-Ming, FAN Wei-Chao, FANG Jin-Gang, ZHU Xiao-Jun, MENG Chui-Zhou. "Top-Down" Method Derived Few-Layer Graphite as Cathode Material for High-Capacity Aluminum-Ion Battery[J]. Chinese Journal of Inorganic Chemistry, ;2019, 35(8): 1411-1418. doi: 10.11862/CJIC.2019.171 shu

"Top-Down" Method Derived Few-Layer Graphite as Cathode Material for High-Capacity Aluminum-Ion Battery

LIU Dong-Hai ^1,2,, ,
WANG Jun-Ming ^1,2 ,
FAN Wei-Chao ^1,2 ,
FANG Jin-Gang ^1,2 ,
ZHU Xiao-Jun ^1,2 ,
MENG Chui-Zhou ^1,2,3,,

1.
State Key Laboratory of Coal-Based Low-Carbon Energy, Langfang, Hebei 065001, China
2.
ENN Research & Development Co., Ltd, Langfang, Hebei 065001, China
3.
School of Mechanical Engineering, Hebei University of Technology, Tianjin 300130, China

Corresponding author: LIU Dong-Hai, liudonghaic@enn.cn MENG Chui-Zhou, 2018108@hebut.edu.cn
Received Date: 1 April 2019
Revised Date: 29 May 2019

Figures(6)

A novel easily-scalable "top-down" method was used to prepare graphite cathode materials with chara-cteristics of few layers, small size and defect-free, which further increases the embedding sites of ions and breaks the inherent capacity limitation of graphite, so as to improve the electrochemical performance of aluminum ion batteries. Scanning electron microscope (SEM), transmission electron microscope (TEM) and X-ray diffraction (XRD) were used to characterize the properties of graphite materials, indicating that the proposed "top-down" method is able to realize the stripping of graphite without destroying the structure and achieve effective control of the thickness and size of graphite layer by adjusting the ball milling time. Electrochemical test results showed that the discharge capacities of G-48 reached 93 mAh·g^-1 under a current density of 3C and still retained 68 mAh·g^-1 under a high current density of 10C with excellent cycling performance. In addition, the preparation process is simple and low cost, which provides a good foundation for promoting the commercial application of the high-capacity and long-life aluminum ion batteries.
- electrochemistry,
- aluminum ion battery,
- graphite,
- cathode materials,
- ball-milling,
- top-down
1. [1]
  Yoshino A. Angew. Chem. Int. Ed., 2012, 51(24):5798-5800 doi: 10.1002/anie.201105006
2. [2]
  Wang S, Jiao S Q, Tian D H, et al. Adv. Mater., 2017, 29(16):1606349 doi: 10.1002/adma.201606349
3. [3]
  Zhang M, Song X H, Ou X W, et al. Energy Storage Mater., 2019, 16:65-84 doi: 10.1016/j.ensm.2018.04.023
4. [4]
  Zhang X L, Tang Y B, Zhang F, et al. Adv. Energy Mater., 2016, 6(11):1502588 doi: 10.1002/aenm.201502588
5. [5]
  LIU Yu-Ping, LI Yan-Guang. Chin. Sci. Bull., 2015(18):1723-1724
6. [6]
  Das S K. Angew. Chem. Int. Ed., 2018, 57(51):16606-16617 doi: 10.1002/anie.201802595
7. [7]
  Hu Y X, Luo B, Ye D L, et al. Adv. Mater., 2017, 29(48):1606132 doi: 10.1002/adma.201606132
8. [8]
  LIN Hua, CHEN Kang-Hua, SHUAI Yi, et al. Chinese Journal of Power Sources, 2018, 42(1):46-49 doi: 10.3969/j.issn.1002-087X.2018.01.013
9. [9]
  Das S K, Mahapatra S, Lahan H. J. Mater. Chem. A, 2017, 5(14):6347-6367 doi: 10.1039/C7TA00228A
10. [10]
  Zhang Y, Liu S Q, Ji Y J, et al. Adv. Mater., 2018, 30(38):1706310 doi: 10.1002/adma.201706310
11. [11]
  Lin M C, Gong M, Lu B A, et al. Nature, 2015, 520(4):325-328
12. [12]
  Wang D Y, Wei C Y, Lin M C, et al. Nat. Commun., 2017, 8:14283 doi: 10.1038/ncomms14283
13. [13]
  Wu Y P, Gong M, Lin M C, et al. Adv. Mater., 2016, 28(41):9218-9222 doi: 10.1002/adma.201602958
14. [14]
  Yu X Z, Wang B, Gong D C, et al. Adv. Mater., 2017, 29(4):1604118 doi: 10.1002/adma.201604118
15. [15]
  Gao Y R, Zhu C Q, Chen Z Z, et al. J. Phys. Chem. C, 2017, 121(13):7131-7138 doi: 10.1021/acs.jpcc.7b00888
16. [16]
  Sun H B, Wang W, Yu Z J, et al. Chem. Commun., 2015, 51(59):11892-11895 doi: 10.1039/C5CC00542F
17. [17]
  Zhang L Y, Chen L, Luo H, et al. Adv. Energy Mater., 2017, 7(15):1700034 doi: 10.1002/aenm.201700034
18. [18]
  Wang P, Chen H S, Li N, et al. Energy Storage Mater., 2018, 13:103-111 doi: 10.1016/j.ensm.2018.01.001
19. [19]
  Li Z S, Zhang L, Chen X, et al. Electrochim. Acta, 2019, 296:8-17 doi: 10.1016/j.electacta.2018.11.002
20. [20]
  Han J L, Chen G R, Yan T T, et al. Chem. Eng. J., 2018, 347:273-279 doi: 10.1016/j.cej.2018.04.100
21. [21]
  Yan T T, Liu J, Lei H, et al. Environ. Sci.:Nano, 2018, 5(11):2722-2730 doi: 10.1039/C8EN00629F
22. [22]
  Duan H Y, Yan T T, Chen G R, et al. Chem. Commun., 2017, 53(54):7465-7468 doi: 10.1039/C7CC03424E
23. [23]
  Chen H, Guo F, Liu Y J, et al. Adv. Mater., 2017, 29(12):1605958 doi: 10.1002/adma.201605958
24. [24]
  Chen H, Xu H Y, Wang S Y, et al. Sci. Adv., 2017, 3(12):eaao7233 doi: 10.1126/sciadv.aao7233
25. [25]
  Xu J T, Shui J L, Wang J L, et al. ACS Nano, 2014, 8(10):10920-10930 doi: 10.1021/nn5047585
26. [26]
  HUANG Bin, DENG Hai-Jin, LI Ming, et al. Transactions of Materials and Heat Treatment, 2005, 26(6):20-24
27. [27]
  Wang S, Jiao S Q, Wang J X, et al. ACS Nano, 2017, 11(1):469-477 doi: 10.1021/acsnano.6b06446
1. [1]
  Qingtang ZHANG , Xiaoyu WU , Zheng WANG , Xiaomei WANG . Performance of nano Li₂FeSiO₄/C cathode material co-doped by potassium and chlorine ions. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1689-1696. doi: 10.11862/CJIC.20240115
2. [2]
  Lingbang Qiu , Jiangmin Jiang , Libo Wang , Lang Bai , Fei Zhou , Gaoyu Zhou , Quanchao Zhuang , Yanhua Cui . 原位电化学阻抗谱监测长寿命热电池Nb₁₂WO₃₃正极材料的高温双放电机制. Acta Physico-Chimica Sinica, 2025, 41(5): 100040-. doi: 10.1016/j.actphy.2024.100040
3. [3]
  Xiangyu CAO , Jiaying ZHANG , Yun FENG , Linkun SHEN , Xiuling ZHANG , Juanzhi YAN . Synthesis and electrochemical properties of bimetallic-doped porous carbon cathode material. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 509-520. doi: 10.11862/CJIC.20240270
4. [4]
  Yuyao Wang , Zhitao Cao , Zeyu Du , Xinxin Cao , Shuquan Liang . Research Progress of Iron-based Polyanionic Cathode Materials for Sodium-Ion Batteries. Acta Physico-Chimica Sinica, 2025, 41(4): 100035-. doi: 10.3866/PKU.WHXB202406014
5. [5]
  Jianbao Mei , Bei Li , Shu Zhang , Dongdong Xiao , Pu Hu , Geng Zhang . Enhanced Performance of Ternary NASICON-Type Na_3.5-xMn_0.5V_1.5-xZr_x(PO₄)₃/C Cathodes for Sodium-Ion Batteries. Acta Physico-Chimica Sinica, 2024, 40(12): 2407023-. doi: 10.3866/PKU.WHXB202407023
6. [6]
  Pengyang FAN , Shan FAN , Qinjin DAI , Xiaoying ZHENG , Wei DONG , Mengxue WANG , Xiaoxiao HUANG , Yong ZHANG . Preparation and performance of rich 1T-MoS₂ nanosheets for high-performance aqueous zinc ion battery cathode materials. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 675-682. doi: 10.11862/CJIC.20240339
7. [7]
  Yuanchao LI , Weifeng HUANG , Pengchao LIANG , Zifang ZHAO , Baoyan XING , Dongliang YAN , Li YANG , Songlin WANG . Effect of heterogeneous dual carbon sources on electrochemical properties of LiMn_0.8Fe_0.2PO₄/C composites. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 751-760. doi: 10.11862/CJIC.20230252
8. [8]
  Xiaoning TANG , Shu XIA , Jie LEI , Xingfu YANG , Qiuyang LUO , Junnan LIU , An XUE . Fluorine-doped MnO₂ with oxygen vacancy for stabilizing Zn-ion batteries. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1671-1678. doi: 10.11862/CJIC.20240149
9. [9]
  Zihan Lin , Wanzhen Lin , Fa-Jie Chen . Electrochemical Modifications of Native Peptides. University Chemistry, 2025, 40(3): 318-327. doi: 10.12461/PKU.DXHX202406089
10. [10]
  Cen Zhou , Biqiong Hong , Yiting Chen . Application of Electrochemical Techniques in Supramolecular Chemistry. University Chemistry, 2025, 40(3): 308-317. doi: 10.12461/PKU.DXHX202406086
11. [11]
  Yongming Zhu , Huili Hu , Yuanchun Yu , Xudong Li , Peng Gao . Construction and Practice on New Form Stereoscopic Textbook of Electrochemistry for Energy Storage Science and Engineering: Taking Basic Course of Electrochemistry as an Example. University Chemistry, 2024, 39(8): 44-47. doi: 10.3866/PKU.DXHX202312086
12. [12]
  Kuaibing Wang , Honglin Zhang , Wenjie Lu , Weihua Zhang . Experimental Design and Practice for Recycling and Nickel Content Detection from Waste Nickel-Metal Hydride Batteries. University Chemistry, 2024, 39(11): 335-341. doi: 10.12461/PKU.DXHX202403084
13. [13]
  Linbao Zhang , Weisi Guo , Shuwen Wang , Ran Song , Ming Li . Electrochemical Oxidation of Sulfides to Sulfoxides. University Chemistry, 2024, 39(11): 204-209. doi: 10.3866/PKU.DXHX202401009
14. [14]
  Hongyi LI , Aimin WU , Liuyang ZHAO , Xinpeng LIU , Fengqin CHEN , Aikui LI , Hao HUANG . Effect of Y(PO₃)₃ double-coating modification on the electrochemical properties of Li[Ni_0.8Co_0.15Al_0.05]O₂. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1320-1328. doi: 10.11862/CJIC.20230480
15. [15]
  Jianfeng Yan , Yating Xiao , Xin Zuo , Caixia Lin , Yaofeng Yuan . Comprehensive Chemistry Experimental Design of Ferrocenylphenyl Derivatives. University Chemistry, 2024, 39(4): 329-337. doi: 10.3866/PKU.DXHX202310005
16. [16]
  Yifei Cheng , Jiahui Yang , Wei Shao , Wanqun Zhang , Wanqun Hu , Weiwei Li , Kaiping Yang . Learning Goes Beyond the Written Word: Practical Insights from the “Leaf Electroplating” Popular Science Experiment. University Chemistry, 2024, 39(9): 319-327. doi: 10.3866/PKU.DXHX202310033
17. [17]
  Bing WEI , Jianfan ZHANG , Zhe CHEN . Research progress in fine tuning of bimetallic nanocatalysts for electrocatalytic carbon dioxide reduction. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 425-439. doi: 10.11862/CJIC.20240201
18. [18]
  Zhuo Wang , Xue Bai , Kexin Zhang , Hongzhi Wang , Jiabao Dong , Yuan Gao , Bin Zhao . MOF模板法合成氮掺杂碳材料用于增强电化学钠离子储存和去除. Acta Physico-Chimica Sinica, 2025, 41(3): 2405002-. doi: 10.3866/PKU.WHXB202405002
19. [19]
  Zhihuan XU , Qing KANG , Yuzhen LONG , Qian YUAN , Cidong LIU , Xin LI , Genghuai TANG , Yuqing LIAO . Effect of graphene oxide concentration on the electrochemical properties of reduced graphene oxide/ZnS. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1329-1336. doi: 10.11862/CJIC.20230447
20. [20]
  Qin ZHU , Jiao MA , Zhihui QIAN , Yuxu LUO , Yujiao GUO , Mingwu XIANG , Xiaofang LIU , Ping NING , Junming GUO . Morphological evolution and electrochemical properties of cathode material LiAl_0.08Mn_1.92O₄ single crystal particles. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1549-1562. doi: 10.11862/CJIC.20240022

Get Citation

PDF

XML

Metrics

PDF Downloads(5)
Abstract views(1303)
HTML views(159)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142