Citation: GUO Dong-Jing, HU Mei-Qin, SHEN Hao-Yu, ZHANG Jian, SUN Jie, XU Yi-Ming. Sulfonated Aluminum Phthalocyanine Modified Amino Functionalized Magnetic Materials for Photosensitized Degradation of Bisphenol A[J]. Chinese Journal of Inorganic Chemistry, ;2019, 35(8): 1379-1386. doi: 10.11862/CJIC.2019.168 shu

Sulfonated Aluminum Phthalocyanine Modified Amino Functionalized Magnetic Materials for Photosensitized Degradation of Bisphenol A

1.
Ningbo Institute of Technology, Zhejiang University, Ningbo, Zhejiang 315100, China
2.
Ningbo Institute of Materials Technology & Engineering, Chinese Academy of Sciences, Ningbo, Zhejiang 315201, China
3.
Department of Chemistry, Zhejiang University, Hangzhou 310027, China

Corresponding author: HU Mei-Qin, mqhu@nit.zju.edu.cn
Received Date: 17 March 2019
Revised Date: 10 May 2019

Figures(11)

Amino-functionalized Fe₃O₄ magnetic material (NH₂@nFe₃O₄) was prepared via a solvothermal method, followed by impregnation with Al(Ⅲ) phthalocyanine sulfonate (AlPcS). The characterization of material with Fourier transform infrared spectroscopy, diffuse reflectance, X-ray diffraction, scanning electron microscopy, transmission electron microscopy, and vibrating magnetometer show that AlPcS mainly combines with NH₂@nFe₃O₄ through electrostatic interaction. The average particle size and saturation magnetization of AlPcS-NH₂@nFe₃O₄ were 127 nm, and 75.3 emu·g^-1, respectively. Under visible light and air, this functionalized magnetic material has high photosensitization activity for degradation of bisphenol A (BPA), an environmental endocrine disruptor in weak alkaline aqueous solution. The photosensitization activity of composite changed with the content of AlPcS, and 3.4%(w/w) AlPcS-NH₂@nFe₃O₄ showed the best photosensitization activity. After 60 min of reaction, the degradation rate of 20.0 mg·L^-1 BPA was up to 96%, and it still remained above 93% after ten-repeated use. The reaction mechanism was discussed by NaN₃ quenching experiment. It is confirmed that ¹O₂ is the main active species in the photosensitization process.
- magnetic photocatalyst,
- phthalocyanine,
- bisphenol A,
- visible light,
- degradation
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