Citation: HAN Dan-Dan, ZHAO Yuan, SHEN Ye, DING Yuan-Sheng, CHENG Zhen-Yu, JING Xiao-Yan, ZHANG Xue-Yi. Layered Co₃O₄/Ti Nanosheet Flexible Electrode with Low Transfer Resistance for Supercapacitor[J]. Chinese Journal of Inorganic Chemistry, ;2019, 35(8): 1485-1492. doi: 10.11862/CJIC.2019.165 shu

Layered Co₃O₄/Ti Nanosheet Flexible Electrode with Low Transfer Resistance for Supercapacitor

1.
College of Chemistry and Pharmaceutical Engineering, Jilin Institute of Chemical Technology, Jilin, Jilin 132022, China
2.
College of Materials Science and Chemical Engineering, Harbin Engineering University, Harbin 150001, China
3.
Jilin Hospital of Integrated Traditional Chinese and Western Medicine, Jilin, Jilin 132012, China

Corresponding author: HAN Dan-Dan, luckhan2006@163.com
Received Date: 28 March 2019
Revised Date: 17 May 2019

Figures(7)

The layered Co₃O₄ nanosheets with porous nature on Ti mesh were adopted to optimize the transfer resistance by a facile hydrothermal method. The synthesized materials were characterized using X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM) and electrochemical techniques. The results showed that the materials consisted of well-arranged micrometer length rectangular 2D flakes with uniform pore distribution. This unique microstructure obtained the electrode lower transfer resistance, higher structure stability, and better electrochemical performance for supercapacitor. The 2D porous layered Co₃O₄ nanosheet could achieve a relatively good capacitance retention of 91.8% at a current density of 100 mA·g^-1 after 1 000 cycles and a low transfer resistance (R_ct) of 0.29 Ω. These remarkable supercapacitive performances are attributed to the rationally 2D layered structure on flexible Ti mesh substrate, high utilization ratio of active materials of the flexible Co₃O₄/Ti electrode.
- flexible electrode,
- layered Co₃O₄,
- porous nanosheets,
- transfer resistance,
- supercapacior
1. [1]
  Guo D, Luo Y Z, Yu X Z, et al. Nano Energy, 2014, 8:174-182 doi: 10.1016/j.nanoen.2014.06.002
2. [2]
  Nishide H, Oyaizu K. Science, 2008, 319:737-738 doi: 10.1126/science.1151831
3. [3]
  Simon P, Gogotsi Y. Nat. Mater., 2008, 7:845-854 doi: 10.1038/nmat2297
4. [4]
  Wang G P, Zhang L, Zhang J J. Chem. Soc. Rev., 2012, 41:797-828 doi: 10.1039/C1CS15060J
5. [5]
  Chen L F, Huang Z H, Liang H W, et al. Adv. Funct. Mater., 2014, 24:5104-5111 doi: 10.1002/adfm.201400590
6. [6]
  Ling M, Qian X Y, Zhu D Z, et al. Chin. Chem. Lett., 2019, https://doi.org/10.1016/j.cclet.2019.03.010.
7. [7]
  Kumbhar V S, Kim D H. Electrochim. Acta, 2018, 271:284-296 doi: 10.1016/j.electacta.2018.03.147
8. [8]
  Xue D F, Zhu D Z, Xiong W, et al. ACS Sustainable Chem. Eng., 2019, 7:7024-7034 doi: 10.1021/acssuschemeng.8b06774
9. [9]
  Hu Q Q, Gu Z X, Zheng X T, et al. Chem. Eng. J., 2016, 304:223-231 doi: 10.1016/j.cej.2016.06.097
10. [10]
  Zhang Z Y, Liu S S, Xiao F, et al. ACS Sustainable Chem. Eng., 2017, 5:529-536 doi: 10.1021/acssuschemeng.6b01879
11. [11]
  Jiang J, Liu J P, Huang X T, et al. Cryst. Growth Des., 2010, 10:70-75 doi: 10.1021/cg9001835
12. [12]
  Qiu K, Lu Y, Cheng J, et al. Electrochim. Acta, 2015, 157:62-68 doi: 10.1016/j.electacta.2014.12.035
13. [13]
  Wang X H, Yao S W, Wu X X, et al. RSC Adv., 2015, 5:17938-17944 doi: 10.1039/C4RA14450C
14. [14]
  Liu T, Zhang L Y, You W, et al. Small, 2018, 14:1702407 doi: 10.1002/smll.201702407
15. [15]
  Li Z P, Yu X Y, Paik U. J. Power Sources, 2016, 310:41-46 doi: 10.1016/j.jpowsour.2016.01.105
16. [16]
  Qorbani M, Naseri N, Moshfegh A Z. ACS Appl. Mater. Interfaces, 2015, 7:11172-11179 doi: 10.1021/acsami.5b00806
17. [17]
  Meher S K, Rao G R. J. Phys. Chem. C, 2011, 115:15646-15654 doi: 10.1021/jp201200e
18. [18]
  Xu Y Q, Wang Z L, Tan L, et al. Ind. Eng. Chem. Res., 2018, 57:5259-5267 doi: 10.1021/acs.iecr.8b00170
19. [19]
  Wei G J, Zhou Z, Zhao X X, et al. ACS Appl. Mater. Interfaces, 2018, 10:23721-23730 doi: 10.1021/acsami.8b04026
20. [20]
  Chen D H, Peng L L, Yuan Y F, et al. Nano Lett., 2017, 17:3907-3913 doi: 10.1021/acs.nanolett.7b01485
21. [21]
  Sennu P, Aravindan V, Lee Y S. J. Power Sources, 2016, 306:248-257 doi: 10.1016/j.jpowsour.2015.12.029
22. [22]
  Wang Y, Huang J, Xiao Y J, et al. Carbon, 2019, 147:146-153 doi: 10.1016/j.carbon.2019.02.082
23. [23]
  Yu L Y, Hu L F, Anasori B, et al. ACS Energy Lett., 2018, 3:1597-1603 doi: 10.1021/acsenergylett.8b00718
24. [24]
  Aloqaylia S, Ranaweeraa C K, Wanga Z, et al. Energy Storage Mater., 2017, 8:68-76 doi: 10.1016/j.ensm.2017.05.006
25. [25]
  Xu R, Lin J M, Wu J H, et al. Appl. Surf. Sci., 2018, 434:861-870 doi: 10.1016/j.apsusc.2017.10.174
26. [26]
  An K L, Zheng Y, Xu X X, et al. J. Solid State Chem., 2019, 270:539-546 doi: 10.1016/j.jssc.2018.12.021
27. [27]
  Shakir D, Shahid M, Rana U A, et al. Electrochim. Acta, 2014, 129:28-32 doi: 10.1016/j.electacta.2014.02.082
28. [28]
  Saray M T, Hosseini H. Electrochim. Acta, 2016, 222:505-517 doi: 10.1016/j.electacta.2016.11.003
29. [29]
  Chen C, Zhou J J, Li Y L, et al. J. Solid State Chem., 2019, 271:239-245 doi: 10.1016/j.jssc.2018.12.060
30. [30]
  Luo G X, Teh K S, Xia Y, et al. J. Alloys Compd., 2018, 767:1126-1132 doi: 10.1016/j.jallcom.2018.07.188
31. [31]
  Feng C, Zhang J F, He Y, et al. ACS Nano, 2015, 9:1730-1739 doi: 10.1021/nn506548d
32. [32]
  Pan G X, Xia X H, Cao F, et al. Electrochim. Acta, 2015, 173:385-392 doi: 10.1016/j.electacta.2015.05.078
33. [33]
  Xiao Z Y, Fan L L, Xu B, et al. ACS Appl. Mater. Interfaces, 2017, 9:41827-41836 doi: 10.1021/acsami.7b10309
34. [34]
  Liao Q Y, Li N, Jin S X, et al. ACS Nano, 2015, 9:5310-5317 doi: 10.1021/acsnano.5b00821
35. [35]
  Rakhi R B, Chen W, Hedhili M N, et al. ACS Appl. Mater. Interfaces, 2014, 6:4196-4206 doi: 10.1021/am405849n
36. [36]
  Wang X W, Li M X, Chang Z, et al. ACS Appl. Mater. Interfaces, 2015, 7:2280-2285 doi: 10.1021/am5062272
37. [37]
  Huang M, Li F, Ji J Y, et al. CrystEngComm, 2014, 14:2878-2884
38. [38]
  Gao M, Wang W K, Rong Q, et al. ACS Appl. Mater. Interfaces, 2018, 10:23163-23173 doi: 10.1021/acsami.8b07082
39. [39]
  Guo W, Hou L L, Hou B, et al. J. Alloys Compd., 2017, 708:524-530 doi: 10.1016/j.jallcom.2017.02.276
40. [40]
  Wang H, Ren Q, Brett D J L, et al. J. Power Sources, 2017, 343:76-82 doi: 10.1016/j.jpowsour.2017.01.042
41. [41]
  Wu X, Han Z C, Zheng X, et al. Nano Energy, 2017, 31:410-417 doi: 10.1016/j.nanoen.2016.11.035
42. [42]
  Ouyang Y, Huang R J, Xia X F, et al. Chem. Eng. J., 2019, 355:416-427 doi: 10.1016/j.cej.2018.08.142
1. [1]
  Min LUO , Xiaonan WANG , Yaqin ZHANG , Tian PANG , Fuzhi LI , Pu SHI . Porous spherical MnCo₂S₄ as high-performance electrode material for hybrid supercapacitors. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 413-424. doi: 10.11862/CJIC.20240205
2. [2]
  Xing Xiao , Yunling Jia , Wanyu Hong , Yuqing He , Yanjun Wang , Lizhi Zhao , Huiqin An , Zhen Yin . Sulfur-defective ZnIn2S4 nanosheets decorated by TiO2 nanosheets with exposed {001} facets to accelerate charge transfer for efficient photocatalytic hydrogen evolution. Chinese Journal of Structural Chemistry, 2024, 43(12): 100474-100474. doi: 10.1016/j.cjsc.2024.100474
3. [3]
  Fei ZHOU , Xiaolin JIA . Co₃O₄/TiO₂ composite photocatalyst: Preparation and synergistic degradation performance of toluene. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2232-2240. doi: 10.11862/CJIC.20240236
4. [4]
  Tian TIAN , Meng ZHOU , Jiale WEI , Yize LIU , Yifan MO , Yuhan YE , Wenzhi JIA , Bin HE . Ru-doped Co₃O₄/reduced graphene oxide: Preparation and electrocatalytic oxygen evolution property. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 385-394. doi: 10.11862/CJIC.20240298
5. [5]
  Mingjiao Lu , Zhixing Wang , Gui Luo , Huajun Guo , Xinhai Li , Guochun Yan , Qihou Li , Xianglin Li , Ding Wang , Jiexi Wang . Boosting the performance of LiNi_0.90Co_0.06Mn_0.04O₂ electrode by uniform Li₃PO₄ coating via atomic layer deposition. Chinese Chemical Letters, 2024, 35(5): 108638-. doi: 10.1016/j.cclet.2023.108638
6. [6]
  Xiuzheng Deng , Yi Ke , Jiawen Ding , Yingtang Zhou , Hui Huang , Qian Liang , Zhenhui Kang . Construction of ZnO@CDs@Co₃O₄ sandwich heterostructure with multi-interfacial electron-transfer toward enhanced photocatalytic CO₂ reduction. Chinese Chemical Letters, 2024, 35(4): 109064-. doi: 10.1016/j.cclet.2023.109064
7. [7]
  Linping Li , Junhui Su , Yanping Qiu , Yangqin Gao , Ning Li , Lei Ge . Design and fabrication of ternary Au/Co3O4/ZnCdS spherical composite photocatalyst for facilitating efficient photocatalytic hydrogen production. Chinese Journal of Structural Chemistry, 2024, 43(12): 100472-100472. doi: 10.1016/j.cjsc.2024.100472
8. [8]
  Jingxuan Liu , Shiqi Zhao , Xiang Wu . Flexible electrochemical capacitor based NiMoSSe electrode material with superior cycling and structural stability. Chinese Chemical Letters, 2024, 35(7): 109059-. doi: 10.1016/j.cclet.2023.109059
9. [9]
  Hailang JIA , Hongcheng LI , Pengcheng JI , Yang TENG , Mingyun GUAN . Preparation and performance of N-doped carbon nanotubes composite Co₃O₄ as oxygen reduction reaction electrocatalysts. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 693-700. doi: 10.11862/CJIC.20230402
10. [10]
  Yuchen Wang , Yaoyu Liu , Xiongfei Huang , Guanjie He , Kai Yan . Fe nanoclusters anchored in biomass waste-derived porous carbon nanosheets for high-performance supercapacitor. Chinese Chemical Letters, 2024, 35(8): 109301-. doi: 10.1016/j.cclet.2023.109301
11. [11]
  Juan CHEN , Guoyu YANG . A porous-layered aluminoborate built by mixed oxoboron clusters and AlO₄ tetrahedra. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 193-200. doi: 10.11862/CJIC.20240341
12. [12]
  Yan Fan , Jiao Tan , Cuijuan Zou , Xuliang Hu , Xing Feng , Xin-Long Ni . Unprecedented stepwise electron transfer and photocatalysis in supramolecular assembly derived hybrid single-layer two-dimensional nanosheets in water. Chinese Chemical Letters, 2025, 36(4): 110101-. doi: 10.1016/j.cclet.2024.110101
13. [13]
  Xiaodan Wang , Yingnan Liu , Zhibin Liu , Zhongjian Li , Tao Zhang , Yi Cheng , Lecheng Lei , Bin Yang , Yang Hou . Highly efficient electrosynthesis of H₂O₂ in acidic electrolyte on metal-free heteroatoms co-doped carbon nanosheets and simultaneously promoting Fenton process. Chinese Chemical Letters, 2024, 35(7): 108926-. doi: 10.1016/j.cclet.2023.108926
14. [14]
  Peng Jia , Yunna Guo , Dongliang Chen , Xuedong Zhang , Jingming Yao , Jianguo Lu , Liqiang Zhang . In-situ imaging electrocatalysis in a solid-state Li-O₂ battery with CuSe nanosheets as air cathode. Chinese Chemical Letters, 2024, 35(5): 108624-. doi: 10.1016/j.cclet.2023.108624
15. [15]
  Dong-Xue Jiao , Hui-Li Zhang , Chao He , Si-Yu Chen , Ke Wang , Xiao-Han Zhang , Li Wei , Qi Wei . Layered (C5H6ON)2[Sb2O(C2O4)3] with a large birefringence derived from the uniform arrangement of π-conjugated units. Chinese Journal of Structural Chemistry, 2024, 43(6): 100304-100304. doi: 10.1016/j.cjsc.2024.100304
16. [16]
  Hui Li , Yanxing Qi , Jia Chen , Juanjuan Wang , Min Yang , Hongdeng Qiu . Synthesis of amine-pillar[5]arene porous adsorbent for adsorption of CO₂ and selectivity over N₂ and CH₄. Chinese Chemical Letters, 2024, 35(11): 109659-. doi: 10.1016/j.cclet.2024.109659
17. [17]
  Ziyi Zhu , Yang Cao , Jun Zhang . CO2-switched porous metal-organic framework magnets. Chinese Journal of Structural Chemistry, 2024, 43(2): 100241-100241. doi: 10.1016/j.cjsc.2024.100241
18. [18]
  Xinyu Huai , Jingxuan Liu , Xiang Wu . Cobalt-Doped NiMoO4 Nanosheet for High-performance Flexible Supercapacitor. Chinese Journal of Structural Chemistry, 2023, 42(10): 100158-100158. doi: 10.1016/j.cjsc.2023.100158
19. [19]
  Husitu Lin , Shuangkun Zhang , Dianfa Zhao , Yongkang Wang , Wei Liu , Fan Yang , Jianjun Liu , Dongpeng Yan , Zhanpeng Wu . Flexible polyphosphazene nanocomposite films: Enhancing stability and luminescence of CsPbBr₃ perovskite nanocrystals. Chinese Chemical Letters, 2025, 36(4): 109795-. doi: 10.1016/j.cclet.2024.109795
20. [20]
  Binyang Qin , Mengqi Wang , Shimei Wu , Yining Li , Chilin Liu , Yufei Zhang , Haosen Fan . Carbon dots confined nanosheets assembled NiCo₂S₄@CDs cross-stacked architecture for enhanced sodium ion storage. Chinese Chemical Letters, 2024, 35(7): 108921-. doi: 10.1016/j.cclet.2023.108921

Get Citation

PDF

XML

Metrics

PDF Downloads(5)
Abstract views(797)
HTML views(42)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Layered Co3O4/Ti Nanosheet Flexible Electrode with Low Transfer Resistance for Supercapacitor

Metrics

通讯作者: 陈斌, bchen63@163.com

Layered Co₃O₄/Ti Nanosheet Flexible Electrode with Low Transfer Resistance for Supercapacitor