Citation: WANG Bei-Bei, CAI Hong-Xin, MEI Xue-Ao, ZHANG Xiu-Xiu, WU Wei-Na, WANG Yuan, CHEN Zhong. Sn(Ⅳ)/Ag(Ⅰ) Complexes of N-((Quinolin-8-yl)methylene)salicylhydrazide: Syntheses, Crystal Structures and DNA Interaction[J]. Chinese Journal of Inorganic Chemistry, ;2019, 35(7): 1295-1300. doi: 10.11862/CJIC.2019.157 shu

Sn(Ⅳ)/Ag(Ⅰ) Complexes of N-((Quinolin-8-yl)methylene)salicylhydrazide: Syntheses, Crystal Structures and DNA Interaction

1.
College of Chemistry and Chemical Engineering, Henan Key Laboratory of Coal Green Conversion, Henan Polytechnic University, Jiaozuo, Henan 454000, China
2.
School of Physics and Electronic Information Engineering, Henan Polytechnic University, Jiaozuo, Henan 454000, China
3.
School of Materials and Mechanical and Electrical Engineering, Jiangxi Science and Technology Normal University, Nanchang 330013, China

Corresponding author: CAI Hong-Xin, me2001@hpu.edu.cn WU Wei-Na, wuwn08@hpu.edu.cn
Received Date: 27 January 2019
Revised Date: 1 May 2019

Figures(4)

Two complexes, namely, [Sn(L)Ph₂Cl]·0.25CH₃OH (1) and[Ag(HL)(NO₃)]·CH₃OH (2) based on HL (HL=N-((quinolin-8-yl)methylene)salicylhydrazide) were synthesized and characterized by X-ray diffraction analyses. The result shows that the Sn(Ⅳ) ion in complex 1 coordinates with one anionic hydrazone ligand with ON₂ donor set, one chloride ion and two carbon atoms coming from two phenyl groups, thus giving a distorted octahedral coordination geometry. The Ag(Ⅰ) ion in complex 2 that displays a distorted square pyramid coordination geometry is surrounded by one tridentate hydrazone ligand and one bidentate nitrate anions. In addition, the fluorescence spectra indicate that the interactions of the complexes with DNA are stronger than ligand HL.
- quinoline,
- complex,
- crystal structure,
- DNA interaction
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沈阳化工大学材料科学与工程学院沈阳 110142