Citation: YU Zhu, BAI Jian, WANG Han-Hui, CAO Ying, ZHU Dun-Ru. Crystal Structures of Three Complexes Built from Pyridyl-Substituted Phenol-Based Compartmental Ligand[J]. Chinese Journal of Inorganic Chemistry, ;2019, 35(7): 1312-1320. doi: 10.11862/CJIC.2019.143 shu

Crystal Structures of Three Complexes Built from Pyridyl-Substituted Phenol-Based Compartmental Ligand

YU Zhu ^1,# ,
BAI Jian ^1,# ,
WANG Han-Hui ¹ ,
CAO Ying ¹ ,
ZHU Dun-Ru ^1,2,,

1.
College of Chemical Engineering, State Key Laboratory of Materials-Oriented Chemical Engineering, Nanjing Tech University, Nanjing 211816, China
2.
State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210023, China

Corresponding author: ZHU Dun-Ru, zhudr@njtech.edu.cn

Received Date: 29 March 2019
Revised Date: 16 April 2019

Figures(6)

A novel binuclear calcium complex[Ca₂L₂(NO₃)₂] (1) and a mononuclear cadmium complex[Cd(HL)(NO₃)₂] (2) have been successfully synthesized by using 2-(N, N-di(2-pyridylmethyl)aminomethyl)-6-aldehydo-4-methylphenol (HL) as a ligand. Complex 2 can be transformed to a binuclear cadmium complex[Cd₂L₂(NO₃)₂]·H₂O (3) under basic conditions. Complexes 1~3 have been characterized by FT-IR, ESI-MS, elemental analysis and single-crystal X-ray diffraction. Both 1 and 3 crystallize in monoclinic system, but with space group P2₁/c and C2/c, respectively, while 2 in triclinic system with space group P1. X-ray crystallography analysis reveals that 1 has a bi-calcium unit[Ca₂O₂] bridged by two phenolato O atoms, and each eight-coordinated Ca(Ⅱ) cation shows a distorted dodecahedron configuration[CaN₃O₅] with three N atoms and one phenolato O atom from one L^-, one phenolato O atom and an aldehyde O atom from another L^- ligand, and two O atoms from one nitrate. 2 is a mononuclear cadmium complex and Cd(Ⅱ) cation is eight-coordinated by three N atoms and one phenol O atom from HL ligand and four O atoms from two nitrates to show a distorted dodecahedron configuration[CdN₃O₅], whereas the aldehyde group does not take part in coordination. 3 contains a bi-cadmium unit[Cd₂O₂] bridged by two phenolato O atoms, and each seven-coordinated Cd(Ⅱ) cation shows a distorted monocapped trigonal prism configuration[CdN₃O₄] with three N atoms and one phenolato O atom from one L^-, one phenolato O atom and an aldehyde O atom from another L^- ligand, and one O atom from one nitrate.
- synthesis,
- calcium complex,
- cadmium complex,
- transformation,
- crystal structure
1. [1]
  Fenton D E. Inorg. Chem. Commun., 2002, 5:537-547 doi: 10.1016/S1387-7003(02)00477-X
2. [2]
  Vigato P A, Tamburini S. Coord. Chem. Rev., 2008, 252:1871-1995 doi: 10.1016/j.ccr.2007.10.030
3. [3]
  Koval I A, Gamez P, Belle C, et al. Chem. Soc. Rev., 2006, 35:814-840 doi: 10.1039/b516250p
4. [4]
  Jarenmark M, Carlsson H, Nordlander E. C. R. Chim., 2007, 10:433-462 doi: 10.1016/j.crci.2007.02.015
5. [5]
  Peralta R A, Bortoluzzi A J, Xavier F R, et al. Inorg. Chem., 2010, 49:11421-11438 doi: 10.1021/ic101433t
6. [6]
  Xavier F R, Neves A, Casellato A, et al. Inorg. Chem., 2009, 48:7905-7921 doi: 10.1021/ic900831q
7. [7]
  Das B, Daver H, Singh A, et al. Eur. J. Inorg. Chem., 2014:2204-2212
8. [8]
  Das B, Daver H, Barman S K, et al. Inorg. Biochem., 2014, 132:6-17 doi: 10.1016/j.jinorgbio.2013.08.001
9. [9]
  Smith S J, Peralta R A, Hanson G R, et al. Inorg. Chem., 2012, 51:2065-2078 doi: 10.1021/ic201711p
10. [10]
  Traar P, Schröckeneder A, Judmaier M E, et al. Eur. J. Inorg. Chem., 2010:5718-5727
11. [11]
  Sheng Z, Berto T C, Dahl E W, et al. J. Am. Chem. Soc., 2013, 135:4902-4905 doi: 10.1021/ja309782m
12. [12]
  Reim J, Krebs B. J. Chem. Soc. Dalton Trans., 1997:3793-3804
13. [13]
  Torelli S, Belle C, Hamman S, et al. Inorg. Chem., 2002, 41:3983-3989 doi: 10.1021/ic025599d
14. [14]
  Mukherjee J, Mukherjee R. Inorg. Chim. Acta, 2002, 337:429-438 doi: 10.1016/S0020-1693(02)01106-4
15. [15]
  Koval I A, Huisman M, Stassen A F, et al. Eur. J. Inorg. Chem., 2004:4036-4045
16. [16]
  Belle C, Beguin C, Gautier-Luneau I, et al. Inorg. Chem., 2002, 41:479-491 doi: 10.1021/ic010534g
17. [17]
  Torelli S, Belle C, Gautier-Luneau I, et al. Inorg. Chem., 2000, 39:3526-3536 doi: 10.1021/ic991450z
18. [18]
  Than R, Feldmann A A, Krebs B. et al. Coord. Chem. Rev., 1999, 182:211-241 doi: 10.1016/S0010-8545(98)00234-3
19. [19]
  Merkel M, Moller N, Piacenza M, et al. Chem. Eur. J., 2005, 11:1201-1209 doi: 10.1002/chem.200400768
20. [20]
  Thirumavalavan M, Akilan P, Kandaswamy M, et al. Inorg. Chem., 2003, 42:3308-3317 doi: 10.1021/ic020633+
21. [21]
  Wang R X, Gao D Z, Ye F, et al. Acta Crystallogr. Sect. E:Struct. Rep. Online, 2012, E68:o1672-o1673
22. [22]
  YAN Jian. Thesis for the Master of Nanjing University of Technology. 2007.
23. [23]
  GAO Da-Zhi, WANG Ruo-Xu, YE Fan, et al. Chinese J. Inorg. Chem., 2013, 29:2438-2444
24. [24]
  WU Di, YU Zhu, GAO Da-Zhi, et al. Chinese J. Inorg. Chem., 2015, 31:1619-1625
25. [25]
  Koval I A, Pursche D, Stassen A F, et al. Eur. J. Inorg. Chem., 2003:1669-1674
26. [26]
  Alvarez S, Alemany P, Casanova D, et al. Coord. Chem. Rev., 2005, 249:1693-1708 doi: 10.1016/j.ccr.2005.03.031
27. [27]
  Koval I A, Huisman M, Stassen A F, et al. Inorg. Chim. Acta, 2004, 357:294-300 doi: 10.1016/S0020-1693(03)00422-5
28. [28]
  You Z L, Zhu H L. Z. Anorg. Allg. Chem., 2006, 632:140-146 doi: 10.1002/(ISSN)1521-3749
29. [29]
  Jiang J C, Chu Z L, Huang W, et al. Inorg. Chem., 2010, 49:5897-5911 doi: 10.1021/ic100349d
30. [30]
  Zhang Y, Wu Y, He X, et al. Acta Crystallogr. Sect. C:Cryst. Struct. Commun., 2018, C74:256-262
31. [31]
  Koval I A, Huisman M, Stassen A F, et al. Eur. J. Inorg. Chem., 2004:591-600
1. [1]
  Peng Meng , Qian-Cheng Luo , Aidan Brock , Xiaodong Wang , Mahboobeh Shahbazi , Aaron Micallef , John McMurtrie , Dongchen Qi , Yan-Zhen Zheng , Jingsan Xu . Molar ratio induced crystal transformation from coordination complex to coordination polymers. Chinese Chemical Letters, 2024, 35(4): 108542-. doi: 10.1016/j.cclet.2023.108542
2. [2]
  Lulu DONG , Jie LIU , Hua YANG , Yupei FU , Hongli LIU , Xiaoli CHEN , Huali CUI , Lin LIU , Jijiang WANG . Synthesis, crystal structure, and fluorescence properties of Cd-based complex with pcu topology. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 809-820. doi: 10.11862/CJIC.20240171
3. [3]
  Xiaoling WANG , Hongwu ZHANG , Daofu LIU . Synthesis, structure, and magnetic property of a cobalt(Ⅱ) complex based on pyridyl-substituted imino nitroxide radical. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 407-412. doi: 10.11862/CJIC.20240214
4. [4]
  Lu LIU , Huijie WANG , Haitong WANG , Ying LI . Crystal structure of a two-dimensional Cd(Ⅱ) complex and its fluorescence recognition of p-nitrophenol, tetracycline, 2, 6-dichloro-4-nitroaniline. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1180-1188. doi: 10.11862/CJIC.20230489
5. [5]
  Yao HUANG , Yingshu WU , Zhichun BAO , Yue HUANG , Shangfeng TANG , Ruixue LIU , Yancheng LIU , Hong LIANG . Copper complexes of anthrahydrazone bearing pyridyl side chain: Synthesis, crystal structure, anticancer activity, and DNA binding. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 213-224. doi: 10.11862/CJIC.20240359
6. [6]
  Xiumei LI , Linlin LI , Bo LIU , Yaru PAN . Syntheses, crystal structures, and characterizations of two cadmium(Ⅱ) coordination polymers. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 613-623. doi: 10.11862/CJIC.20240273
7. [7]
  Chao LIU , Jiang WU , Zhaolei JIN . Synthesis, crystal structures, and antibacterial activities of two zinc(Ⅱ) complexes bearing 5-phenyl-1H-pyrazole group. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1986-1994. doi: 10.11862/CJIC.20240153
8. [8]
  Yan XU , Suzhi LI , Yan LI , Lushun FENG , Wentao SUN , Xinxing LI . Structure variation of cadmium naphthalene-diphosphonates with the changing rigidity of N-donor auxiliary ligands. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 395-406. doi: 10.11862/CJIC.20240226
9. [9]
  Xiaoxia WANG , Ya'nan GUO , Feng SU , Chun HAN , Long SUN . Synthesis, structure, and electrocatalytic oxygen reduction reaction properties of metal antimony-based chalcogenide clusters. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1201-1208. doi: 10.11862/CJIC.20230478
10. [10]
  Yinling HOU , Jia JI , Hong YU , Xiaoyun BIAN , Xiaofen GUAN , Jing QIU , Shuyi REN , Ming FANG . A rhombic Dy₄-based complex showing remarkable single-molecule magnet behavior. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 605-612. doi: 10.11862/CJIC.20240251
11. [11]
  Kaimin WANG , Xiong GU , Na DENG , Hongmei YU , Yanqin YE , Yulu MA . Synthesis, structure, fluorescence properties, and Hirshfeld surface analysis of three Zn(Ⅱ)/Cu(Ⅱ) complexes based on 5-(dimethylamino) isophthalic acid. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1397-1408. doi: 10.11862/CJIC.20240009
12. [12]
  Huan ZHANG , Jijiang WANG , Guang FAN , Long TANG , Erlin YUE , Chao BAI , Xiao WANG , Yuqi ZHANG . A highly stable cadmium(Ⅱ) metal-organic framework for detecting tetracycline and p-nitrophenol. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 646-654. doi: 10.11862/CJIC.20230291
13. [13]
  Jia JI , Zhaoyang GUO , Wenni LEI , Jiawei ZHENG , Haorong QIN , Jiahong YAN , Yinling HOU , Xiaoyan XIN , Wenmin WANG . Two dinuclear Gd(Ⅲ)-based complexes constructed by a multidentate diacylhydrazone ligand: Crystal structure, magnetocaloric effect, and biological activity. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 761-772. doi: 10.11862/CJIC.20240344
14. [14]
  Ruikui YAN , Xiaoli CHEN , Miao CAI , Jing REN , Huali CUI , Hua YANG , Jijiang WANG . Design, synthesis, and fluorescence sensing performance of highly sensitive and multi-response lanthanide metal-organic frameworks. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 834-848. doi: 10.11862/CJIC.20230301
15. [15]
  Xiumei LI , Yanju HUANG , Bo LIU , Yaru PAN . Syntheses, crystal structures, and quantum chemistry calculation of two Ni(Ⅱ) coordination polymers. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 2031-2039. doi: 10.11862/CJIC.20240109
16. [16]
  Yukun CHEN , Kexin FENG , Bolun ZHANG , Wentao SONG , Jianjun ZHANG . Syntheses, crystal structures, and diametrically opposed mechanically-stimulated luminescence response of two Mg(Ⅱ) metal-organic frameworks. Chinese Journal of Inorganic Chemistry, 2025, 41(6): 1227-1234. doi: 10.11862/CJIC.20240448
17. [17]
  Xinting XIONG , Zhiqiang XIONG , Panlei XIAO , Xuliang NIE , Xiuying SONG , Xiuguang YI . Synthesis, crystal structures, Hirshfeld surface analysis, and antifungal activity of two complexes Na(Ⅰ)/Cd(Ⅱ) assembled by 5-bromo-2-hydroxybenzoic acid ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1661-1670. doi: 10.11862/CJIC.20240145
18. [18]
  Jing WU , Puzhen HUI , Huilin ZHENG , Pingchuan YUAN , Chunfei WANG , Hui WANG , Xiaoxia GU . Synthesis, crystal structures, and antitumor activities of transition metal complexes incorporating a naphthol-aldehyde Schiff base ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2422-2428. doi: 10.11862/CJIC.20240278
19. [19]
  Zhaodong WANG . In situ synthesis, crystal structure, and magnetic characterization of a trinuclear copper complex based on a multi-substituted imidazo[1,5-a]pyrazine scaffold. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 597-604. doi: 10.11862/CJIC.20240268
20. [20]
  Meirong HAN , Xiaoyang WEI , Sisi FENG , Yuting BAI . A zinc-based metal-organic framework for fluorescence detection of trace Cu²⁺. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1603-1614. doi: 10.11862/CJIC.20240150

Get Citation

PDF

XML

Metrics

PDF Downloads(4)
Abstract views(454)
HTML views(83)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142