Citation: DING Yu-Jie, JIN Xing, LIU Qian, QIAN Gui-Xiang, Abdullah M. Asiri, Hadi M. Marwani. Phase-Controlled Synthesis of Fluoride Scandium Nanocrystals with Properties of Upconversion Luminescence[J]. Chinese Journal of Inorganic Chemistry, ;2019, 35(6): 947-954. doi: 10.11862/CJIC.2019.134 shu

Phase-Controlled Synthesis of Fluoride Scandium Nanocrystals with Properties of Upconversion Luminescence

1.
College of Biochemical Engineering, Anhui Polytechnic University, Wuhu, Anhui 241000, China
2.
Chemistry Department, Faculty of Science, King Abdulaziz University, Jeddah 21589, Saudi Arabia

Corresponding author: DING Yu-Jie, dyj@ahpu.edu.cn
Received Date: 17 December 2018
Revised Date: 25 April 2019

Figures(8)

The fluorine scandium nanocrystals (NCs) with different morphologies, phase structures and properties of upconversion luminescence (UCL) were synthesized through changing the reaction conditions such as the composition, the amount of the surfactant or the reaction time. The change of the ratio of surfactant oleic acid (OA)/oleylamine (OM) made the crystal structure change from cubic ScF₃:Yb, Er to orthorhombic KSc₂F₇:Yb, Er NCs with the enhanced UCL, while the morphology transformed from small to bulky. The UCL of the KSc₂F₇ NCs could be tuned from blue through white, and then to dominant purple emissions by changing doped element under the excitation of 980 nm laser.
- upconversion,
- fluorine scandium nanocrystals,
- phase transition
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