Citation: ZHAO Yi-Ming, YANG Ji-Kai, MA Fu-Zhe, CHEN Zhang-Xiao-Xiong, WEI Zi-Juan, ZHANG Yu-Fei, CHENG Ming, YANG Xue, XIAO Nan, WANG Guo-Zheng, WANG Xin, HUANG Ke-Ke. Preparation and Photoelectrochemical Catalytic Properties of Porous Silicon/TiO₂ Nanowires Photoanodes[J]. Chinese Journal of Inorganic Chemistry, ;2019, 35(4): 613-620. doi: 10.11862/CJIC.2019.088 shu

Preparation and Photoelectrochemical Catalytic Properties of Porous Silicon/TiO₂ Nanowires Photoanodes

1.
School of Science, Changchun University of Science and Technology, Changchun 130022, China
2.
Department of Nephrology, The First Hospital of Jilin University, Changchun 130021, China
3.
State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, Changchun 130012, China

Corresponding author: YANG Ji-Kai, jikaiyang0625@163.com MA Fu-Zhe, mafuzhe2002@163.com
Received Date: 15 October 2018
Revised Date: 5 March 2019

Figures(7)

n-Type porous silicon were prepared by metal-assisted chemical etching (MACE) and then the porous Si/TiO₂ nanowires photoanodes were prepared by hydrothermal synthesis. Samples were characterized by scanning electron microscope (SEM) and X-ray diffraction (XRD). The results showed that the macrospore size of the porous Si increases from about 0.1 to 0.4 μm with the increasing of etching time. Porous Si/TiO₂ nanowires corresponded primarily to rutile phase and slight traces of anatase. The results showed that porous Si/TiO₂ nanowires sample with etching for 35 min had the highest anti-reflectivity the corresponding photoanode showed the best photocurrent (photocurrent density) under simulated solar light. In addition, the photoelectric catalysis results showed that porous Si/TiO₂ nanowires with etching for 35 min at 1.5 V showed the best catalytic activities, which is attributed to the anti-reflection, heterogeneous effect and window effect.
- silicon,
- hydrothermal synthesis,
- water splitting,
- photolysis
1. [1]
  Fujishima A, Honda K. Nature, 1972, 238(5385):37-38
2. [2]
  Kümmerer K. J. Environ. Manage., 2009, 90(8):2354-2366 doi: 10.1016/j.jenvman.2009.01.023
3. [3]
  Asahi R, Morikawa T, Ohwaki T, et al. Science, 2001, 293(5528):269-271 doi: 10.1126/science.1061051
4. [4]
  Liao J H, Shi L Y, Yuan S, et al. J. Phys. Chem. C, 2009, 113(43):18778-18783 doi: 10.1021/jp905720g
5. [5]
  Albu S P, Ghicov A, Macak J M, et al. Nano Lett., 2007, 7(5):1286-1289 doi: 10.1021/nl070264k
6. [6]
  Lee K, Kim D, Roy P, et al. J. Am. Chem. Soc., 2010, 132(5):1478-1479 doi: 10.1021/ja910045x
7. [7]
  Zhu K, Neale N R, Miedaner A, et al. Nano Lett., 2007, 7(1):69-74 doi: 10.1021/nl062000o
8. [8]
  Liu Z Y, Zhang X T, Nishimoto S, et al. J. Phys. Chem. C, 2008, 112(1):253-259 doi: 10.1021/jp0772732
9. [9]
  Baram N, Ein-Eli Y. J. Phys. Chem. C, 2010, 114(21):9781-9790 doi: 10.1021/jp911687w
10. [10]
  Hou Y, Li X Y, Zhao Q D, et al. Environ. Sci. Technol., 2010, 44(13):5098-5103 doi: 10.1021/es100004u
11. [11]
  CHEN Yi, SHI Li-Yi, YUAN Shuai. Journal of Inorganic Materials, 2009, 24(4):680-684
12. [12]
  Chen X, Mao S S. Chem. Rev., 2007, 107(7):2891-2959 doi: 10.1021/cr0500535
13. [13]
  Hoffmann M R, Martin S T, Choi W, et al. Chem. Rev., 1995, 95(1):69-96 doi: 10.1021/cr00033a004
14. [14]
  Endo M, Strano M S, Ajayan P M. Topics in Applied Physics: Vol.111. Jorio A. Ed., Berlin, Heidelberg: Springer, 2007: 13-62
15. [15]
  Peng K Q, Wang X, Lee S T. Appl. Phys. Lett., 2008, 92(16):163103 doi: 10.1063/1.2909555
16. [16]
  Goodey A P, Eichfeld S M, Lew K K, et al. J. Am. Chem. Soc., 2007, 129(41):12344-12345 doi: 10.1021/ja073125d
17. [17]
  Nakato Y, Ueda T, Egi Y, et al. J. Electrochem. Soc., 1987, 134(2):353-358 doi: 10.1149/1.2100459
18. [18]
  Mills A, Davies R H, Worsley D. Chem. Soc. Rev., 1993, 22(6):417-425 doi: 10.1039/cs9932200417
19. [19]
  Garnett E C, Yang P. J. Am. Chem. Soc., 2008, 130(29):9224-9225 doi: 10.1021/ja8032907
20. [20]
  Li Y, Qian F, Xiang J, et al. Mater. Today, 2006, 9(10):18-27 doi: 10.1016/S1369-7021(06)71650-9
21. [21]
  Liu Y S, Ji G B, Wang J Y, et al. Nanoscale Res. Lett., 2012, 7(1):663 doi: 10.1186/1556-276X-7-663
22. [22]
  Goodey A P, Eichfeld S M, Lew K K, et al. J. Am. Chem. Soc., 2007, 129(41):12344-12345 doi: 10.1021/ja073125d
23. [23]
  Angelome P C, Andrini L, Calvo M E, et al. J. Phys. Chem. C, 2007, 111(29):10886-10893 doi: 10.1021/jp069020z
24. [24]
  Liu Y J, Szeifert J M, Feckl J M, et al. ACS Nano, 2010, 4(9):5373-5381 doi: 10.1021/nn100785j
25. [25]
  YU Li-Sheng. Physics of Semiconductor Heterojun-ctions. 2nd Ed.. Beijing:Science Press, 2006.
26. [26]
  Yu H T, Chen S, Quan X, et al. Appl. Catal. B, 2009, 90(1/2):242-248
27. [27]
  Hwang Y J, Boukai A, Yang P D. Nano Lett., 2008, 9(1):410-415
28. [28]
  Shi J, Hara Y, Sun C L, et al. Nano Lett., 2011, 11(8):3413-3419 doi: 10.1021/nl201823u
29. [29]
  Noh S Y, Sun K, Choi C, et al. Nano Energy, 2013, 2(3):351-360 doi: 10.1016/j.nanoen.2012.10.010
30. [30]
  KOU Yan-Qiang, YANG Ji-Kai, ZHU Ling-Xi, et al. Chem. J. Chinese Universities, 2015, 36(12):2485-2490 doi: 10.7503/cjcu20150378
31. [31]
  Peng K Q, Yan Y J, Gao S P, et al. Adv. Funct. Mater., 2003, 13(2):127-132 doi: 10.1002/adfm.200390018
32. [32]
  Huang Z P, Shimizu T, Senz S, et al. J. Phys. Chem. C, 2010, 114(24):10683-10690 doi: 10.1021/jp911121q
33. [33]
  Tsujino K, Matsumura M. Adv. Mater., 2005, 17(8):1045-1047 doi: 10.1002/(ISSN)1521-4095
34. [34]
  Xia W W, Zhu J, Wang H B, et al. CrystEngComm, 2014, 16(20):4289-4297 doi: 10.1039/C4CE00006D
35. [35]
  M T McDowell, M F Lichterman, A I Carim, et al. ACS Appl. Mater. Interfaces, 2015, 7(28):15189-15199 doi: 10.1021/acsami.5b00379
36. [36]
  Huang Z P, Geyer N, Werner P, et al. Adv. Mater., 2011, 23(2):285-308 doi: 10.1002/adma.v23.2
37. [37]
  Vazsonyi E, De Clercq K, Einhaus R, et al. Sol. Energy Mater. Sol. Cells, 1999, 57(2):179-188 doi: 10.1016/S0927-0248(98)00180-9
38. [38]
  Shankar K, Mor G K, Prakasam H E, et al. Nanotechnology, 2007, 18(6):065707 doi: 10.1088/0957-4484/18/6/065707
39. [39]
  Hinckley S, McCann J F, Haneman D. Solar Cells, 1986, 17(2/3):317-342
40. [40]
  Yu H T, Chen S, Quan X, et al. Appl. Catal. B, 2009, 90(1/2):242-248
41. [41]
  Yan J A, Yang L, Chou M Y. Phys. Rev. B, 2007, 76(11):115319 doi: 10.1103/PhysRevB.76.115319
42. [42]
  Cserveny S I. Int. J. Electron., 1968, 25(1):65-80 doi: 10.1080/00207216808938067
43. [43]
  Fulton C C, Lucovsky G, Nemanich R J. Appl. Phys. Lett., 2004, 84(4):580-582 doi: 10.1063/1.1639944
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通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Preparation and Photoelectrochemical Catalytic Properties of Porous Silicon/TiO2 Nanowires Photoanodes

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通讯作者: 陈斌, bchen63@163.com

Preparation and Photoelectrochemical Catalytic Properties of Porous Silicon/TiO₂ Nanowires Photoanodes