Citation: WU Yue-Tao, FAN Yu, LIU Yan-Li, XU Jia-Qiang. Amino-Functionalization and Enhanced Humidity Sensing Properties of MIL-125 Based on Quartz Crystal Microbalance Sensor[J]. Chinese Journal of Inorganic Chemistry, ;2019, 35(4): 635-642. doi: 10.11862/CJIC.2019.079 shu

Amino-Functionalization and Enhanced Humidity Sensing Properties of MIL-125 Based on Quartz Crystal Microbalance Sensor

WU Yue-Tao ¹ ,
FAN Yu ² ,
LIU Yan-Li ^1,, ,
XU Jia-Qiang ^2,,

1.
College of Material Science and Engineering, Hunan University, Changsha 410082, China
2.
NEST Lab, Department of Physics, Department of Chemistry, College of Sciences, Shanghai University, Shanghai 200444, China

Corresponding author: LIU Yan-Li, yanliliu@hnu.edu.cn XU Jia-Qiang, xujiaqiang@shu.edu.cn
Received Date: 8 November 2018
Revised Date: 14 February 2019

Figures(11)

The metal organic framework compounds MIL-125(Ti) and NH₂-MIL-125(Ti) were prepared and chara-cterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), Fourier transform infrared spectroscopy (FT-IR)and specific surface area (BET). The humidity sensing performances of the two materials based QCM sensors were studied by exposed to humidity range of 11%~97%RH (relative humidity). The experimental results show that the MIL-125(Ti) and NH₂-MIL-125(Ti) sensors have some advantages, such as high sensitivity, good repeatability, fast response/recovery and etc. Compared with MIL-125(Ti), the sensor modified by NH₂-MIL-125(Ti) exhibited higher response to humidity.when the indoor humidity was about 52%, the frequency shift of the NH₂-MIL-125(Ti) sensor to a 11% relative humidity was 57 Hz higher than MIL-125(Ti), indicating that the amino-functionalized material had a certain enhancement to the response of the humidity sensor. Furthermore, the adsorption enthalpys between water molecules and MIL-125(Ti) or NH₂-MIL-125(Ti) was obtained by Materials Studio, which proved that the amino functionalization could enhance the humidity sensitivity of MIL-125(Ti).
- metal-organic framework,
- quartz crystal microbalance,
- relative humidity,
- amino-functionalization,
- humidity sensor
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