Citation: FENG Yan, WU Jian-Bo, ZHANG Xiao-Ling, PENG Chao-Qun, WANG Ri-Chu. Preparation and Catalytic Performance for Oxygen Reduction of Nitrogen Doped MnCo₂O₄/N-KB[J]. Chinese Journal of Inorganic Chemistry, ;2019, 35(4): 569-579. doi: 10.11862/CJIC.2019.071 shu

Preparation and Catalytic Performance for Oxygen Reduction of Nitrogen Doped MnCo₂O₄/N-KB

School of Materials Science and Engineering, Central South University, Changsha 410083, China

Corresponding author: WANG Ri-Chu, wrc@csu.edu.cn
Received Date: 20 November 2018
Revised Date: 18 January 2019

Figures(8)

MnCo₂O₄/N-KB catalysts was prepared by hydrolysis-hydrothermal method, in which Mn(Ac)₂ and Co(Ac)₂ were used as precursors and nitrogen doped conductive carbon Ketjenblack (KB) was used as the carbon source. The microstructure of the MnCo₂O₄/N-KB catalysts and its catalytic performance for oxide reduction reaction were studied. The results showed that chemical coupling was formed between N-KB and MnCo₂O₄. It produced synergistic effect and effectively improved the oxygen reduction activity of MnCo₂O₄/N-KB catalyst. When the mass ratio of MnCo₂O₄ to N-KB was 1:9, the limiting current density of the reaction was 5.7 mA·cm^-2 and the half wave potential was close to 0.81 V. MnCo₂O₄/N-KB catalyst obtained the best electrocatalytic performance for oxygen reduction. Comparing to the commercial Pt/C catatlyst with a current density of 5.2 mA·cm^-2 and a half-wave potential 0.83 V, MnCo₂O₄/N-KB catalyst had a highly active oxygen reduction with higher ultimate current density and durability under the same capacity condition.
- oxygen reduction reaction,
- manganese cobalt spinel,
- hydrothermal synthesis,
- electrochemistry
1. [1]
  Pan Y M, Mei Z S, Yang Z H, et al. Chem. Eng. J., 2014, 242:397-403 doi: 10.1016/j.cej.2013.04.069
2. [2]
  Cheng F Y, Su Y, Liang J, et al. Chem. Mater., 2014, 22(3):898-905
3. [3]
  XUE Zhao-Hui, LIU Zhao-Lin, MA Fang-Wei, et al. Chinese J. Inorg. Chem., 2012, 28(4):691-697
4. [4]
  Wang M Y, Huang J R, Wang M, et al. Electrochem. Commun., 2013, 34:299-303 doi: 10.1016/j.elecom.2013.07.017
5. [5]
  Liang Y Y, Li Y G, Wang H L, et al. Nat. Mater., 2011, 10(10):780-786 doi: 10.1038/nmat3087
6. [6]
  Xu D Y, Mu C P, Wang B C, et al. Science China Materials, 2017, 60(10):947-954 doi: 10.1007/s40843-017-9094-5
7. [7]
  Ma Y J, Hui W, Key J L, et al. Int. J. Hydrogen Energy, 2014, 39(27):14777-14782 doi: 10.1016/j.ijhydene.2014.07.108
8. [8]
  Liu Q N, Yang T T, Du C C, et al. Nano Lett., 2018, 18(6):3723-3730 doi: 10.1021/acs.nanolett.8b00894
9. [9]
  Huang G, Xu S, Xu Z, et al. ACS Appl. Mater. Interfaces, 2014, 6(23):21325-21334 doi: 10.1021/am506292b
10. [10]
  Bai Z Y, Heng J M, Zhang Q, et al. Adv. Energy Mater., 2018, 8(34):1802390 doi: 10.1002/aenm.201802390
11. [11]
  Zhou L, Wu H B, Zhu T, et al. J. Mater. Chem., 2012, 22(3):827-829 doi: 10.1039/C1JM15054E
12. [12]
  Zhou L, Zhao D Y, Lou X W. Advanced Materials, 2012, 24(6):745-748 doi: 10.1002/adma.201104407
13. [13]
  Ning R, Tian J Q, Asiri A M, et al. Langmuir, 2013, 29(43):13146-13151 doi: 10.1021/la4031014
14. [14]
  Liang Y Y, Wang H L, Zhou J G, et al. J. Am. Chem. Soc., 2012, 134(7):3517-3523 doi: 10.1021/ja210924t
15. [15]
  Li J S, Zhou Z, Liu K, et al. J. Power Sources, 2017, 343:30-38 doi: 10.1016/j.jpowsour.2017.01.018
16. [16]
  Nam G, Park J, Sun T K, et al. Nano Lett., 2014, 14(4):1870-1876 doi: 10.1021/nl404640n
17. [17]
  Qu L T, Liu Y, Baek J B, et al. ACS Nano, 2010, 4(3):1321-1326 doi: 10.1021/nn901850u
18. [18]
  Huang Z, Pan H Y, Yang W J, et al. ACS Nano, 2018, 12(1):208-216 doi: 10.1021/acsnano.7b05832
19. [19]
  Khilari S, Pandit S, Das D, et al. Biosens. Bioelectron., 2014, 54:534-540 doi: 10.1016/j.bios.2013.11.044
20. [20]
  Xia W, Zou R Q, An L, et al. Energy Environ. Sci., 2015, 8(2):568-576 doi: 10.1039/C4EE02281E
21. [21]
  El-Deab, Mohamed S, Ohsaka T. Angew. Chem. Int. Ed., 2006, 118(36):6109-6112 doi: 10.1002/(ISSN)1521-3757
22. [22]
  Lee J S, Park G S, Kim S T, et al. Angew. Chem. Int. Ed., 2013, 52(3):1026-1030 doi: 10.1002/anie.201207193
23. [23]
  Yang X, Xu Y L, Zhang H, et al. Electrochim. Acta, 2013, 114:259-264 doi: 10.1016/j.electacta.2013.10.037
24. [24]
  Chen Z, Higgins D, Chen Z W. Carbon, 2010, 48(11):3057-3065 doi: 10.1016/j.carbon.2010.04.038
25. [25]
  Maldonado S, Morin S, Stevenson K J. Carbon, 2006, 44(8):1429-1437 doi: 10.1016/j.carbon.2005.11.027
26. [26]
  Lu X F, Wu D J, Li R Z, et al. J. Mater. Chem. A, 2014, 2(13):4706-4713 doi: 10.1039/C3TA14930G
27. [27]
  Ding R, Qi L, Jia M J, et al. J. Appl. Electrochem., 2013, 43(9):903-910 doi: 10.1007/s10800-013-0580-z
28. [28]
  Marco J F, Gancedo J R, Gracia M, et al. J. Solid State Chem., 2000, 153(1):74-81 doi: 10.1006/jssc.2000.8749
29. [29]
  Choudhury T, Saied S O, Sullivan J L, et al. J. Phys. D:Appl. Phys., 1989, 22(8):1185-1195 doi: 10.1088/0022-3727/22/8/026
30. [30]
  Pels J R, Kapteijn F, Moulijn J A, et al. Carbon, 1995, 33(11):1641-1653 doi: 10.1016/0008-6223(95)00154-6
31. [31]
  Kapteijn F, Moulijn J A, Matzner S, et al. Carbon, 1999, 37(7):1143-1150 doi: 10.1016/S0008-6223(98)00312-1
32. [32]
  Matter P H, Zhang L, Ozkan U S. J. Catal., 2006, 239(1):83-96 doi: 10.1016/j.jcat.2006.01.022
33. [33]
  Biniak S, Szymański G, Siedlewski J, et al. Carbon, 1997, 35(12):1799-1810 doi: 10.1016/S0008-6223(97)00096-1
34. [34]
  Zhu J K, Gao Q M. Microporous Mesoporous Mater., 2009, 124(1/2/3):144-152
35. [35]
  Li J F, Xiong S L, Liu Y R, et al. Nano Energy, 2013, 2(6):1249-1260 doi: 10.1016/j.nanoen.2013.06.003
36. [36]
  Gómez L E, Boix A V, Miró E E. Catal. Today, 2013, 216:246-253 doi: 10.1016/j.cattod.2013.05.010
37. [37]
  Ma S C, Sun L Q, Cong L N, et al. J. Phys. Chem. C, 2013, 117(49):25890-25897 doi: 10.1021/jp407576q
38. [38]
  Sing K S W. Pure Appl. Chem., 1985, 57(4):603-619 doi: 10.1351/pac198557040603
39. [39]
  Lee J S, Park G S, Lee H I, et al. Nano Lett., 2011, 11(12):5362-5366 doi: 10.1021/nl2029078
40. [40]
  Fu G T, Liu Z Y, Zhang J F, et al. Nano Res., 2016, 9(7):2110-2122 doi: 10.1007/s12274-016-1101-2
41. [41]
  Lin Z Y, Waller G H, Liu Y, et al. Nano Energy, 2013, 2(2):241-248 doi: 10.1016/j.nanoen.2012.09.002
42. [42]
  Ma Y Y, Wang R F, Wang H, et al. J. Power Sources, 2015, 280:526-532 doi: 10.1016/j.jpowsour.2015.01.139
43. [43]
  Liu R L, Wu D Q, Feng X L, et al. J. Am. Chem. Soc., 2011, 133(39):15221-15223 doi: 10.1021/ja204953k
44. [44]
  Cheng S A, Liu H, Logan B E. Electrochem. Commun., 2006, 8(3):489-494 doi: 10.1016/j.elecom.2006.01.010
45. [45]
  Mshoperi E, Fogel R, Limson J. Electrochim. Acta, 2014, 128:311-317 doi: 10.1016/j.electacta.2013.11.016
46. [46]
  Wang D W, Su D S. Energy Environ. Sci., 2014, 7(2):576-591 doi: 10.1039/c3ee43463j
47. [47]
  Li B, Ge X M, Goh F W T, et al. Nanoscale, 2015, 7:1830-1838 doi: 10.1039/C4NR05988C
48. [48]
  Restovic A, RíOs E, Barbato S, et al. J. Electroanal. Chem., 2002, 522(2):141-151 doi: 10.1016/S0022-0728(02)00639-3
49. [49]
  Morales U, Campero A, Solorza-Feria O. J. New Mater. Electrochem. Syst., 1999, 2:89-94
50. [50]
  Presuel-Moreno F J, Jakab M A. J. Electrochem. Soc., 2005, 152(9):B376-B387 doi: 10.1149/1.1997165
51. [51]
  De Koninck M, Marsan B. Electrochim. Acta, 2008, 53:7012-7021 doi: 10.1016/j.electacta.2008.02.002
1. [1]
  Xiaofeng Zhu , Bingbing Xiao , Jiaxin Su , Shuai Wang , Qingran Zhang , Jun Wang . Transition Metal Oxides/Chalcogenides for Electrochemical Oxygen Reduction into Hydrogen Peroxides. Acta Physico-Chimica Sinica, 2024, 40(12): 2407005-. doi: 10.3866/PKU.WHXB202407005
2. [2]
  Hailang JIA , Hongcheng LI , Pengcheng JI , Yang TENG , Mingyun GUAN . Preparation and performance of N-doped carbon nanotubes composite Co₃O₄ as oxygen reduction reaction electrocatalysts. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 693-700. doi: 10.11862/CJIC.20230402
3. [3]
  Hao XU , Ruopeng LI , Peixia YANG , Anmin LIU , Jie BAI . Regulation mechanism of halogen axial coordination atoms on the oxygen reduction activity of Fe-N₄ site: A density functional theory study. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 695-701. doi: 10.11862/CJIC.20240302
4. [4]
  Zihan Lin , Wanzhen Lin , Fa-Jie Chen . Electrochemical Modifications of Native Peptides. University Chemistry, 2025, 40(3): 318-327. doi: 10.12461/PKU.DXHX202406089
5. [5]
  Cen Zhou , Biqiong Hong , Yiting Chen . Application of Electrochemical Techniques in Supramolecular Chemistry. University Chemistry, 2025, 40(3): 308-317. doi: 10.12461/PKU.DXHX202406086
6. [6]
  Yongming Zhu , Huili Hu , Yuanchun Yu , Xudong Li , Peng Gao . Construction and Practice on New Form Stereoscopic Textbook of Electrochemistry for Energy Storage Science and Engineering: Taking Basic Course of Electrochemistry as an Example. University Chemistry, 2024, 39(8): 44-47. doi: 10.3866/PKU.DXHX202312086
7. [7]
  Bing WEI , Jianfan ZHANG , Zhe CHEN . Research progress in fine tuning of bimetallic nanocatalysts for electrocatalytic carbon dioxide reduction. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 425-439. doi: 10.11862/CJIC.20240201
8. [8]
  Linbao Zhang , Weisi Guo , Shuwen Wang , Ran Song , Ming Li . Electrochemical Oxidation of Sulfides to Sulfoxides. University Chemistry, 2024, 39(11): 204-209. doi: 10.3866/PKU.DXHX202401009
9. [9]
  Hongyi LI , Aimin WU , Liuyang ZHAO , Xinpeng LIU , Fengqin CHEN , Aikui LI , Hao HUANG . Effect of Y(PO₃)₃ double-coating modification on the electrochemical properties of Li[Ni_0.8Co_0.15Al_0.05]O₂. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1320-1328. doi: 10.11862/CJIC.20230480
10. [10]
  Jianfeng Yan , Yating Xiao , Xin Zuo , Caixia Lin , Yaofeng Yuan . Comprehensive Chemistry Experimental Design of Ferrocenylphenyl Derivatives. University Chemistry, 2024, 39(4): 329-337. doi: 10.3866/PKU.DXHX202310005
11. [11]
  Yifei Cheng , Jiahui Yang , Wei Shao , Wanqun Zhang , Wanqun Hu , Weiwei Li , Kaiping Yang . Learning Goes Beyond the Written Word: Practical Insights from the “Leaf Electroplating” Popular Science Experiment. University Chemistry, 2024, 39(9): 319-327. doi: 10.3866/PKU.DXHX202310033
12. [12]
  Kuaibing Wang , Honglin Zhang , Wenjie Lu , Weihua Zhang . Experimental Design and Practice for Recycling and Nickel Content Detection from Waste Nickel-Metal Hydride Batteries. University Chemistry, 2024, 39(11): 335-341. doi: 10.12461/PKU.DXHX202403084
13. [13]
  Jinyao Du , Xingchao Zang , Ningning Xu , Yongjun Liu , Weisi Guo . Electrochemical Thiocyanation of 4-Bromoethylbenzene. University Chemistry, 2024, 39(6): 312-317. doi: 10.3866/PKU.DXHX202310039
14. [14]
  Zhongyan Cao , Youzhi Xu , Menghua Li , Xiao Xiao , Xianqiang Kong , Deyun Qian . Electrochemically Driven Denitrative Borylation and Fluorosulfonylation of Nitroarenes. University Chemistry, 2025, 40(4): 277-281. doi: 10.12461/PKU.DXHX202407017
15. [15]
  Yang Lv , Yingping Jia , Yanhua Li , Hexiang Zhong , Xinping Wang . Integrating the Ideological Elements with the “Chemical Reaction Heat” Teaching. University Chemistry, 2024, 39(11): 44-51. doi: 10.12461/PKU.DXHX202402059
16. [16]
  Guowen Xing , Guangjian Liu , Le Chang . Five Types of Reactions of Carbonyl Oxonium Intermediates in University Organic Chemistry Teaching. University Chemistry, 2025, 40(4): 282-290. doi: 10.12461/PKU.DXHX202407058
17. [17]
  Ji-Quan Liu , Huilin Guo , Ying Yang , Xiaohui Guo . Calculation and Discussion of Electrode Potentials in Redox Reactions of Water. University Chemistry, 2024, 39(8): 351-358. doi: 10.3866/PKU.DXHX202401031
18. [18]
  Zhihuan XU , Qing KANG , Yuzhen LONG , Qian YUAN , Cidong LIU , Xin LI , Genghuai TANG , Yuqing LIAO . Effect of graphene oxide concentration on the electrochemical properties of reduced graphene oxide/ZnS. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1329-1336. doi: 10.11862/CJIC.20230447
19. [19]
  Lu XU , Chengyu ZHANG , Wenjuan JI , Haiying YANG , Yunlong FU . Zinc metal-organic framework with high-density free carboxyl oxygen functionalized pore walls for targeted electrochemical sensing of paracetamol. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 907-918. doi: 10.11862/CJIC.20230431
20. [20]
  Pengcheng Yan , Peng Wang , Jing Huang , Zhao Mo , Li Xu , Yun Chen , Yu Zhang , Zhichong Qi , Hui Xu , Henan Li . Engineering Multiple Optimization Strategy on Bismuth Oxyhalide Photoactive Materials for Efficient Photoelectrochemical Applications. Acta Physico-Chimica Sinica, 2025, 41(2): 100014-. doi: 10.3866/PKU.WHXB202309047

Get Citation

PDF

XML

Metrics

PDF Downloads(4)
Abstract views(971)
HTML views(130)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Preparation and Catalytic Performance for Oxygen Reduction of Nitrogen Doped MnCo2O4/N-KB

Metrics

通讯作者: 陈斌, bchen63@163.com

Preparation and Catalytic Performance for Oxygen Reduction of Nitrogen Doped MnCo₂O₄/N-KB