Citation: PAN Miao, HU Yuan-Yuan, ZHAO Zhuo, YAO Yong-Lin, ZHOU Hui-Dong, TONG Bi-Hai, ZHANG Qian-Feng. Beryllium Ion-Selective Phosphorescence Probes Based on 9-Crown-3 Ether Iridium Complexes[J]. Chinese Journal of Inorganic Chemistry, ;2019, 35(2): 293-299. doi: 10.11862/CJIC.2019.049 shu

Beryllium Ion-Selective Phosphorescence Probes Based on 9-Crown-3 Ether Iridium Complexes

Key Laboratory of Metallurgical Emission Reduction & Resources Recycling, Ministry of Education, Institute of Molecular Engineering and Applied Chemistry, School of Metallurgy Engineering, Anhui University of Technology, Maanshan, Anhui 243002, China

Corresponding author: TONG Bi-Hai, tongbihai@163.com ZHANG Qian-Feng, 1665604075@qq.com
Received Date: 19 September 2018
Revised Date: 3 December 2018

Figures(6)

Ionic iridium complex[Ir(BTZ9C3)₂(bpy)]PF₆ (1) and neutral iridium complex[Ir(BTZ9C3)₂(fppz)] (2) were synthesized with 4'-(2-benzothiazolyl)benzo-9-crown-3 ether(BTZ9C3) primary ligand and different ancillary ligands:2, 2'-bipyridine(bpy) and 3-trifluoromethyl-5-(2'-pyridyl)-1, 2-diazole(Hfppz). The structures of the complexes were characterized by NMR, high resolution mass spectrometry, and the single crystal structure of 1 was determined by X-ray structural analysis. All these complexes showed a strong Kelly phosphorescent emission. The photoluminescence spectra of complexes 1 and 2 in PMMA (1%(w/w)) showed emission maximum at 535 and 541 nm, respectively. Their quantum efficiencies were 10.8% and 45.0% and the luminescence lifetimes were 3.01 and 2.58 μs. By means of the cyclic voltammogram, the HOMO levels of complexes 1 and 2 were calculated to be -5.60 and -5.35 eV. Both complexes displayed a high selectivity for Be²⁺ among relevant metal ions, and exhibited luminescence enhancement effect in the presence of Be²⁺. The stoichiometric ratio of iridium complexes responding to Be²⁺ was determined to be 1:2, and the detection limit is down to 6.0 μmol·L^-1. The ionic iridium complex 1 has good anti-disturbance, however the neutral iridium complex 2 is greatly interfered by Al³⁺.
- 9-crown-3 derivatives,
- cyclometalated iridium(Ⅲ) complex,
- Be²⁺,
- phosphorescence probe
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