Citation: CHENG Shu-Yan, HAO Yan-Hong, KOU Jia-Wei, GAO Yang-Yan. Synthesis of Higher Alcohols from Syngas over Cu/Zn/Al Hydrotalcite-Derived Oxides Modified by Triethanolamine[J]. Chinese Journal of Inorganic Chemistry, ;2019, 35(2): 300-306. doi: 10.11862/CJIC.2019.041 shu

Synthesis of Higher Alcohols from Syngas over Cu/Zn/Al Hydrotalcite-Derived Oxides Modified by Triethanolamine

1.
Key Laboratory of Coal Science and Technology of Ministry of Education and Shanxi Province, Taiyuan University of Technology, Taiyuan 030024, China
2.
Department of Environmental Engineering, Shanxi University, Taiyuan 030013, China

Corresponding author: KOU Jia-Wei, koujiawei2015@163.com
Received Date: 11 October 2018
Revised Date: 30 November 2018

Figures(6)

The Cu/Zn/Al hydrotalcite-like precursor was prepared by co-precipitation method and modified by triethanolamine (TEA), and then the precursor was calcined to obtain TEA-modified Cu/Zn/Al catalysts. The catalysts were characterized by XRD, FTIR, H₂-TPR, CO-TPD and SEM techniques, and their catalytic activities for isobutanol synthesis were evaluated. The results revealed that TEA can change morphology of the catalysts and form flocculent structure on the surface of the catalysts. In addition, TEA can result in structural expansion of hydrotalcite-like precursor and thus lead to structural changes in the Cu/Zn/Al catalysts, which facilitate hydrogen reduction of CuO components and CO chemisorption on the surface of the catalysts. These changes promote isobutanol synthesis. The catalytic performance of the TEA-modified Cu/Zn/Al catalysts was optimal when addition ratio of TEA reached to n_TEA/n_Zn=0.5.
- triethanolamine,
- Cu/Zn/Al hydrotalcite-like compounds,
- syngas,
- isobutanol
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沈阳化工大学材料科学与工程学院沈阳 110142