Citation: LI Chen, WU Di, ZHANG Da-Shuai, WANG Li-Li, ZHANG Xiao-Peng, LIU Jian, ZHANG Su-Min, LI Tian-Lue, SHI Zai-Feng, LIN Qiang. Y³⁺/TiO₂ Photocatalysts: Preparation via Ball Milling Method and Marine Aquaculture Wastewater Treatment[J]. Chinese Journal of Inorganic Chemistry, ;2019, 35(3): 376-384. doi: 10.11862/CJIC.2019.035 shu

Y³⁺/TiO₂ Photocatalysts: Preparation via Ball Milling Method and Marine Aquaculture Wastewater Treatment

LI Chen ¹ ,
WU Di ¹ ,
ZHANG Da-Shuai ¹ ,
WANG Li-Li ¹ ,
ZHANG Xiao-Peng ^1,2,, ,
LIU Jian ³ ,
ZHANG Su-Min ¹ ,
LI Tian-Lue ¹ ,
SHI Zai-Feng ^1,, ,
LIN Qiang ¹

1.
Key Laboratory of Water Pollution Treatment & Resource Reuse, Hainan Normal University, Haikou 571127, China
2.
State Key Laboratory of Pollution Control and Resource Reuse, Nanjing University, Nanjing 210023, China
3.
College of Chemical Engineering, Nanjing Forestry University, Nanjing 210037, China

Corresponding author: ZHANG Xiao-Peng, zxp_inorganic@126.com SHI Zai-Feng, zaifengshi@163.com
Received Date: 26 September 2018
Revised Date: 3 December 2018

Figures(11)

Y³⁺ modified TiO₂ photocatalysts were prepared by ball milling method. The structures and properties of the photocatalysts were characterized by UV-visible diffuse reflectance spectroscopy (UV-Vis DRS), X-ray photoelectron spectroscopy (XPS), X-ray powder diffraction (XRD) and scanning electron microscopy (SEM). The photocatalytic activities were evaluated by the degradation of methylene blue (MB) aqueous solution under UV light, and the ball milling processes were optimized. Then Y³⁺/TiO₂ photocatalysts prepared at the best conditions were coated on the plastic balls with different diameters. These balls were applied to treat shrimp wastewater under UV and visible light and COD_Cr (chemical oxygen demand) and 3D fluorescence spectroscopy were detected during the photocatalytic experiments. The results showed that when the molar ratio of Y³⁺ was 2%, milling time was 4 h, ball-to-powder weight ratio was 4:1 and milling rate was 500 r·min^-1, the reaction rate constant of MB degradation can reach up to 0.111 3 min^-1 which was 4.2 times as fast as pure TiO₂. From the UV-Vis DRS, XPS, N₂ absorption-desorption, XRD, SEM results, the band gap of 2%Y³⁺/TiO₂ decreased to 3.05 eV. All Y³⁺/TiO₂ samples showed a redshift of absorption compared to pure TiO₂ and it led to visible light absorption response. The content of surface oxygen vacancy had a significant increase and the BET specific area increased to 104 m² g^-1. Pure TiO₂ and 2%Y³⁺/TiO₂ were used as photocatalysts to treat shrimp wastewater, COD_Cr removal rates were 14.7% and 18.8% under visible light, respectively. Moreover, COD_Cr removal rates were 26.9% and 37.5% under UV light, respectively. The photocatalytic efficiencies of three types of plastic ball with diameters of 1, 2 and 3 cm were investigated. The results showed that the performance of 2 cm balls was best and COD_Cr removal rate was 38.5%.
- ball milling method,
- rare earth yttrium modification,
- UV light irradiation,
- visible light irradiation,
- photocatalytic degradation
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1.
沈阳化工大学材料科学与工程学院沈阳 110142

Y3+/TiO2 Photocatalysts: Preparation via Ball Milling Method and Marine Aquaculture Wastewater Treatment

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通讯作者: 陈斌, bchen63@163.com

Y³⁺/TiO₂ Photocatalysts: Preparation via Ball Milling Method and Marine Aquaculture Wastewater Treatment