Citation: WANG Cheng, HUANG Hong-Xia, XIAO Yang, LIANG Da-Ming. Preparation and Oxygen Catalytic Performance of g-C₃N₄/Double Perovskite Composites[J]. Chinese Journal of Inorganic Chemistry, ;2019, 35(2): 254-262. doi: 10.11862/CJIC.2019.033 shu

Preparation and Oxygen Catalytic Performance of g-C₃N₄/Double Perovskite Composites

Guangxi Key Laboratory of Electrochemical and Magneto-Chemical Functional Materials, Guilin University of Technology, Guilin, Guangxi 541004, China

Corresponding author: HUANG Hong-Xia, hhxhunan@126.com
Received Date: 13 September 2018
Revised Date: 6 December 2018

Figures(13)

Double perovskite Sr₂Ni_xCo_2-xO₆ (x=0.2, 0.4, 0.6, 0.8) with different Ni doping ratios were prepared by sol-gel method, and nanoparticles g-C₃N₄ with layered structure was prepared by thermal decomposition. Synthesis of double perovskite and g-C₃N₄ composite that were used as bifunctional catalysts, which were prepared into bifunctional electrodes, and used to test its catalytic activity for oxygen reduction reaction (ORR) and oxygen evolution reaction (OER). Then, the doping ratio (x=0.4) of Ni in double perovskite with the best oxygen catalytic activity was selected to be composited with a certain weight ratio of g-C₃N₄, testing the catalytic activity of the composite catalysts. The results show that the composite catalysts were obviously better than the single catalysts. When the amount of g-C₃N₄ added was 30% of the mass of the double perovskite, the maximum current densities of the catalytic ORR was 395.7 mA·cm^-2 (-0.6 V vs Hg/HgO), the catalytic OER was 372.0 mA·cm^-2 (1 V vs Hg/HgO). This indicates that the synergistic catalysis of g-C₃N₄ and Sr₂Ni_0.4Co_1.6O₆ could improve the catalytic activity of the double perovskite.
- double perovskite,
- g-C₃N₄,
- oxygen catalysis,
- bifunctional oxygen electrode
1. [1]
  Jacobson M Z. Energy Environ. Sci., 2009, 2(2):148-173 doi: 10.1039/B809990C
2. [2]
  Wang Y, Chen K S, Mishler J, et al. Appl. Energy, 2011, 88(4):981-1007 doi: 10.1016/j.apenergy.2010.09.030
3. [3]
  Lee D U, Xu P, Cano Z P, et al. J. Mater. Chem. A, 2016, 4(19):7107-7134 doi: 10.1039/C6TA00173D
4. [4]
  Young K H, Ouchi T H, Nei J, et al. Batteries, 2017, 3(4):34 doi: 10.3390/batteries3040034
5. [5]
  Karim N A, Kamarudin S K, Loh K S. Energy Convers. Manage., 2017, 145:293-307 doi: 10.1016/j.enconman.2017.05.003
6. [6]
  WANG Ying, ZHANG Li-Min, HU Tian-Jun. Acta Chim. Sinica, 2015, 73(4):316-325
7. [7]
  You S J, Gong X B, Wang W, et al. Adv. Energy Mater., 2016, 6(1):1501497 doi: 10.1002/aenm.201501497
8. [8]
  Huang Q S, Zhou P J, Yang H, et al. Electrochim. Acta, 2017, 232:339-347 doi: 10.1016/j.electacta.2017.02.163
9. [9]
  Li X, Wang H J, Yu H, et al. J. Power Sources, 2014, 260:1-5 doi: 10.1016/j.jpowsour.2014.03.001
10. [10]
  Singh P, Buttry D A. J. Phys. Chem. C, 2012, 116(19):10656-10663 doi: 10.1021/jp301676n
11. [11]
  Alia S M, Zhang G, Kisailus D, et al. Adv. Funct. Mater., 2010, 20(21):3742-3746 doi: 10.1002/adfm.201001035
12. [12]
  ZHUANG Shu-Xin, LÜ Jian-Xian, LU Mi, et al. Prog. Chem., 2015, 27(4):436-447
13. [13]
  Bie S Y, Zhu Y Q, Su J M, et al. J. Mater. Chem. A, 2015, 3(44):22448-22453 doi: 10.1039/C5TA05271H
14. [14]
  Zhou Q J, Cheng Y, Li W D, et al. Mater. Res. Bull., 2016, 74:129-133 doi: 10.1016/j.materresbull.2015.09.023
15. [15]
  Falcón H, Barbero J A, Araujo G, et al. Appl. Catal. B, 2004, 53(1):37-45
16. [16]
  Brieuc F, Dezanneau G, Hayoun M, et al. Solid State Ionics, 2017, 309:187-191 doi: 10.1016/j.ssi.2017.07.017
17. [17]
  Ohkuma H, Uechi I, Imanishi N, et al. J. Power Sources, 2013, 223:319-324 doi: 10.1016/j.jpowsour.2012.09.028
18. [18]
  YU Wen-Wan, HUANG Hong-Xia, WANG Cheng. Chinese J. Inorg. Chem., 2018, 34(3):475-482
19. [19]
  Sun N, Liu H X, Yu Z Y, et al. Ionics, 2016, 22:869-876 doi: 10.1007/s11581-015-1606-9
20. [20]
  Zhao K, Li L W, Zheng A Q, et al. Appl. Energy, 2017, 197:393-404 doi: 10.1016/j.apenergy.2017.04.049
21. [21]
  Zhao H, Chen C, Chen D J, et al. Carbon, 2015, 90:122-129 doi: 10.1016/j.carbon.2015.04.013
22. [22]
  Chen X F, Zhang J S, Fu X Z, et al. J. Am. Chem. Soc., 2009, 131(33):11658-11659 doi: 10.1021/ja903923s
23. [23]
  Wu Y X, Wang T H, Zhang Y D, et al. Sci. Rep., 2016, 6:24314 doi: 10.1038/srep24314
24. [24]
  Liao G Z, Chen S, Quan X, et al. J. Mater. Chem., 2012, 22(6):2721-2726 doi: 10.1039/C1JM13490F
25. [25]
  WU Yan-Bo, BI Jun, WEI Bin-Bin. Acta Phys.-Chim. Sin., 2015, 31:315-321 doi: 10.3866/PKU.WHXB201412164
26. [26]
  Holzwarth U, Gibson N. Nat. Nanotechnol., 2011, 6(9):534 doi: 10.1038/nnano.2011.145
27. [27]
  Yin X, Hong L. Appl. Catal. A, 2009, 371(1):153-160
28. [28]
  Dang X M, Zhang X F, Chen Y T, et al. J. Nanopart. Res., 2015, 17(2):93 doi: 10.1007/s11051-014-2808-1
29. [29]
  Fabbri E, Mohamed R, Levecque P, et al. ChemElectroChem, 2014, 1(2):338-342 doi: 10.1002/celc.201300157
30. [30]
  Wu Z L, Sun L P, Xia T, et al. J. Power Sources, 2016, 334:86-93 doi: 10.1016/j.jpowsour.2016.10.013
31. [31]
  Cheriti M, Kahoul A. Mater. Res. Bull., 2012, 47(1):135-141 doi: 10.1016/j.materresbull.2011.09.016
1. [1]
  Yingqi BAI , Hua ZHAO , Huipeng LI , Xinran REN , Jun LI . Perovskite LaCoO₃/g-C₃N₄ heterojunction: Construction and photocatalytic degradation properties. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 480-490. doi: 10.11862/CJIC.20240259
2. [2]
  Haitao Wang , Lianglang Yu , Jizhou Jiang , Arramel , Jing Zou . S-Doping of the N-Sites of g-C₃N₄ to Enhance Photocatalytic H₂ Evolution Activity. Acta Physico-Chimica Sinica, 2024, 40(5): 2305047-0. doi: 10.3866/PKU.WHXB202305047
3. [3]
  Xuejiao Wang , Suiying Dong , Kezhen Qi , Vadim Popkov , Xianglin Xiang . Photocatalytic CO₂ Reduction by Modified g-C₃N₄. Acta Physico-Chimica Sinica, 2024, 40(12): 2408005-0. doi: 10.3866/PKU.WHXB202408005
4. [4]
  Guangming YIN , Huaiyao WANG , Jianhua ZHENG , Xinyue DONG , Jian LI , Yi'nan SUN , Yiming GAO , Bingbing WANG . Preparation and photocatalytic degradation performance of Ag/protonated g-C₃N₄ nanorod materials. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1491-1500. doi: 10.11862/CJIC.20240086
5. [5]
  Min WANG , Dehua XIN , Wei ZHANG , Haiying YANG , Yuchun WANG , Zhaorong LIU , Meng SHI , Le SHI . Preparation and full-spectrum catalytic degradation performance of nitrogen vacancy g-C₃N₄/Bi/BiOBr/BiOI heterojunction material. Chinese Journal of Inorganic Chemistry, 2025, 41(11): 2283-2298. doi: 10.11862/CJIC.20250109
6. [6]
  Hui Wang , Abdelkader Labidi , Menghan Ren , Feroz Shaik , Chuanyi Wang . Recent Progress of Microstructure-Regulated g-C₃N₄ in Photocatalytic NO Conversion: The Pivotal Roles of Adsorption/Activation Sites. Acta Physico-Chimica Sinica, 2025, 41(5): 100039-0. doi: 10.1016/j.actphy.2024.100039
7. [7]
  Jiayao Wang , Guixu Pan , Ning Wang , Shihan Wang , Yaolin Zhu , Yunfeng Li . Preparation of donor-π-acceptor type graphitic carbon nitride photocatalytic systems via molecular level regulation for high-efficient H₂O₂ production. Acta Physico-Chimica Sinica, 2025, 41(12): 100168-0. doi: 10.1016/j.actphy.2025.100168
8. [8]
  Jianyu Qin , Yuejiao An , Yanfeng Zhang . In Situ Assembled ZnWO₄/g-C₃N₄ S-Scheme Heterojunction with Nitrogen Defect for CO₂ Photoreduction. Acta Physico-Chimica Sinica, 2024, 40(12): 2408002-0. doi: 10.3866/PKU.WHXB202408002
9. [9]
  Kai Han , Guohui Dong , Ishaaq Saeed , Tingting Dong , Chenyang Xiao . Morphology and photocatalytic tetracycline degradation of g-C3N4 optimized by the coal gangue. Chinese Journal of Structural Chemistry, 2024, 43(2): 100208-100208. doi: 10.1016/j.cjsc.2023.100208
10. [10]
  Lanxin Wang , Kaiwei Liang , Xuelian Yu , Guocheng Lv , Libing Liao . Facile method for creating frustrated Lewis pairs in g-C₃N₄ to enhance photocatalytic nitrogen fixation performance. Chinese Chemical Letters, 2026, 37(1): 110572-. doi: 10.1016/j.cclet.2024.110572
11. [11]
  Tianjun Ni , Hui Zhang , Liping Zhou , Roujie Ma , Yanyu Wang , Zhijun Yang , Dan Luo , Nithima Khaorapapong , Xingtao Xu , Yusuke Yamauchi , Dong Liu . Atomic cobalt catalysts on 3D interconnected g-C₃N₄ support for activation of peroxymonosulfate: The importance of Co-N coordination effect. Chinese Chemical Letters, 2025, 36(9): 110659-. doi: 10.1016/j.cclet.2024.110659
12. [12]
  Guixu Pan , Zhiling Xia , Ning Wang , Hejia Sun , Zhaoqi Guo , Yunfeng Li , Xin Li . Preparation of high-efficient donor-π-acceptor system with crystalline g-C3N4 as charge transfer module for enhanced photocatalytic hydrogen evolution. Chinese Journal of Structural Chemistry, 2024, 43(12): 100463-100463. doi: 10.1016/j.cjsc.2024.100463
13. [13]
  Zheng Liu , Yuqing Bian , Graham Dawson , Jiawei Zhu , Kai Dai . Rational constructing of Zn_0.5Cd_0.5S-diethylenetriamine/g-C₃N₄ S-scheme heterojunction with enhanced photocatalytic H₂O₂ production. Chinese Chemical Letters, 2025, 36(9): 111272-. doi: 10.1016/j.cclet.2025.111272
14. [14]
  Wenda WANG , Jinku MA , Yuzhu WEI , Shuaishuai MA . Waste biomass-derived carbon modified porous graphite carbon nitride heterojunction for efficient photodegradation of oxytetracycline in seawater. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 809-822. doi: 10.11862/CJIC.20230353
15. [15]
  Hualin Jiang , Wenxi Ye , Huitao Zhen , Xubiao Luo , Vyacheslav Fominski , Long Ye , Pinghua Chen . Novel 3D-on-2D g-C₃N₄/AgI._x._y heterojunction photocatalyst for simultaneous and stoichiometric production of H₂ and H₂O₂ from water splitting under visible light. Chinese Chemical Letters, 2025, 36(2): 109984-. doi: 10.1016/j.cclet.2024.109984
16. [16]
  Yanghanbin Zhang , Dongxiao Wen , Wei Sun , Jiahe Peng , Dezhong Yu , Xin Li , Yang Qu , Jizhou Jiang . State-of-the-art evolution of g-C3N4-based photocatalytic applications: A critical review. Chinese Journal of Structural Chemistry, 2024, 43(12): 100469-100469. doi: 10.1016/j.cjsc.2024.100469
17. [17]
  Wang Wang , Yucheng Liu , Shengli Chen . Use of NiFe Layered Double Hydroxide as Electrocatalyst in Oxygen Evolution Reaction: Catalytic Mechanisms, Electrode Design, and Durability. Acta Physico-Chimica Sinica, 2024, 40(2): 2303059-0. doi: 10.3866/PKU.WHXB202303059
18. [18]
  Weicheng Feng , Jingcheng Yu , Yilan Yang , Yige Guo , Geng Zou , Xiaoju Liu , Zhou Chen , Kun Dong , Yuefeng Song , Guoxiong Wang , Xinhe Bao . Regulating the High Entropy Component of Double Perovskite for High-Temperature Oxygen Evolution Reaction. Acta Physico-Chimica Sinica, 2024, 40(6): 2306013-0. doi: 10.3866/PKU.WHXB202306013
19. [19]
  Deqi Fan , Yicheng Tang , Yemei Liao , Yan Mi , Yi Lu , Xiaofei Yang . Two birds with one stone: Functionalized wood composites for efficient photocatalytic hydrogen production and solar water evaporation. Chinese Chemical Letters, 2024, 35(9): 109441-. doi: 10.1016/j.cclet.2023.109441
20. [20]
  Yachao HUANG , Chuanwang ZENG , Guiyong LIU , Jinming ZENG , Chao LIU , Xiaopeng QI . Oxygen vacancies and phosphorus doping enhanced metal-organic framework derived nitrogen-doped carbon-coated Co₃O₄ bifunctional electrocatalyst. Chinese Journal of Inorganic Chemistry, 2025, 41(11): 2251-2260. doi: 10.11862/CJIC.20250133

Get Citation

PDF

XML

Metrics

PDF Downloads(7)
Abstract views(2672)
HTML views(318)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Preparation and Oxygen Catalytic Performance of g-C3N4/Double Perovskite Composites

Metrics

通讯作者: 陈斌, bchen63@163.com

Preparation and Oxygen Catalytic Performance of g-C₃N₄/Double Perovskite Composites