Citation: WANG Cheng, HUANG Hong-Xia, XIAO Yang, LIANG Da-Ming. Preparation and Oxygen Catalytic Performance of g-C₃N₄/Double Perovskite Composites[J]. Chinese Journal of Inorganic Chemistry, ;2019, 35(2): 254-262. doi: 10.11862/CJIC.2019.033 shu

Preparation and Oxygen Catalytic Performance of g-C₃N₄/Double Perovskite Composites

Guangxi Key Laboratory of Electrochemical and Magneto-Chemical Functional Materials, Guilin University of Technology, Guilin, Guangxi 541004, China

Corresponding author: HUANG Hong-Xia, hhxhunan@126.com
Received Date: 13 September 2018
Revised Date: 6 December 2018

Figures(13)

Double perovskite Sr₂Ni_xCo_2-xO₆ (x=0.2, 0.4, 0.6, 0.8) with different Ni doping ratios were prepared by sol-gel method, and nanoparticles g-C₃N₄ with layered structure was prepared by thermal decomposition. Synthesis of double perovskite and g-C₃N₄ composite that were used as bifunctional catalysts, which were prepared into bifunctional electrodes, and used to test its catalytic activity for oxygen reduction reaction (ORR) and oxygen evolution reaction (OER). Then, the doping ratio (x=0.4) of Ni in double perovskite with the best oxygen catalytic activity was selected to be composited with a certain weight ratio of g-C₃N₄, testing the catalytic activity of the composite catalysts. The results show that the composite catalysts were obviously better than the single catalysts. When the amount of g-C₃N₄ added was 30% of the mass of the double perovskite, the maximum current densities of the catalytic ORR was 395.7 mA·cm^-2 (-0.6 V vs Hg/HgO), the catalytic OER was 372.0 mA·cm^-2 (1 V vs Hg/HgO). This indicates that the synergistic catalysis of g-C₃N₄ and Sr₂Ni_0.4Co_1.6O₆ could improve the catalytic activity of the double perovskite.
- double perovskite,
- g-C₃N₄,
- oxygen catalysis,
- bifunctional oxygen electrode
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沈阳化工大学材料科学与工程学院沈阳 110142

Preparation and Oxygen Catalytic Performance of g-C3N4/Double Perovskite Composites

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通讯作者: 陈斌, bchen63@163.com

Preparation and Oxygen Catalytic Performance of g-C₃N₄/Double Perovskite Composites