Citation: HUANG Qing-Li, WANG Li-Li, LI Ting, WU Yong-Ping. Synthesis, Growth Mechanism and Application in Anticancer of CuS Hollow Spheres[J]. Chinese Journal of Inorganic Chemistry, ;2019, 35(2): 314-322. doi: 10.11862/CJIC.2019.032 shu

Synthesis, Growth Mechanism and Application in Anticancer of CuS Hollow Spheres

Research Facility Center for Morphology of Xuzhou Medical University, Xuzhou, Jiangsu 221004, China

Corresponding author: HUANG Qing-Li, qlhuang@yzu.edu.cn; qlhuang@xzhmu.edu.cn
Received Date: 21 June 2018
Revised Date: 20 November 2018

Figures(9)

Cage-like hollow morphologies of copper sulfide nanostructures have been selectively synthesized using cupric nitrate trihydrate (Cu(NO₃)₂·3H₂O), oxalic acid (H₂C₂O₄) and sodium sulphide nonahydrate (Na₂S·9H₂O) as starting materials in water solution by a self sacrificing templates hydrothermal method. X-ray diffraction (XRD), field scanning electron microscopy (FESEM), transmission electron microscopy (TEM) and high-resolution transmission electron microscopy (HRTEM) were used to characterize the products. The possible formation mechanism of CuS hollow spheres was proposed. The photo-thermal conversion experiments were also done. The results showed that hollow CuS exhibited high photo-thermal efficiency and high anticancer activity under NIR irradiation.
- hydrothermal synthesis,
- crystal growth,
- radicals,
- reaction mechanisms
1. [1]
  Gai S L, Yang G X, Yang P P, et al. Nano Today, 2018, 19:146-187
2. [2]
  Shao J D, Xie H H, Wang H Y, et al. ACS Appl. Mater. Interfaces, 2018, 10:1155-1163 doi: 10.1021/acsami.7b17117
3. [3]
  Barabadi H, Ovais M, Shinwari Z K, et al. Green Chem. Lett. Rev., 2017, 10:285-314
4. [4]
  Feng W, Nie W, Cheng Y H, et al. Nanomed. Nanotechnol. Biol. Med., 2015, 11:901-912
5. [5]
  Pugazhendhi A, Edison T N J, Karuppusamy I, et al. Int. J. Pharm., 2018, 539:104-111 doi: 10.1016/j.ijpharm.2018.01.034
6. [6]
  Lv J L, Yi Y H, Wu G Q, et al. Mater. Lett., 2017, 187:148-150 doi: 10.1016/j.matlet.2016.10.087
7. [7]
  Du J Y, Liu J F, Gong P W, et al. Mater. Lett., 2017, 196:165-167
8. [8]
  Sobhani Z, Behnam M A, Emami F, et al. Int. J. Nanomed., 2017, 12:4509-4517
9. [9]
  Wang S G, Li K, Chen Y, et al. Biomaterials, 2015, 39:206-217 doi: 10.1016/j.biomaterials.2014.11.009
10. [10]
  Zhou M, Zhang R, Huang M A, et al. J. Am. Chem. Soc., 2010, 132:15351-15358 doi: 10.1021/ja106855m
11. [11]
  Li S M, Zhang Z, Yan L, et al. J. Supercrit. Fluids, 2017, 123:11-17
12. [12]
  Song G S, Wang Q, Wang Y, et al. Adv. Funct. Mater., 2013, 23:4281-4292 doi: 10.1002/adfm.v23.35
13. [13]
  ZHAO Wei, RONG Jia-Chen, LIU Nian-Qi, et al. Chinese J. Inorg. Chem., 2018, 34(3):454-460
14. [14]
  Liu J, Xue D F. J. Cryst. Growth, 2009, 311:500-503 doi: 10.1016/j.jcrysgro.2008.09.025
15. [15]
  Rokade A A, Jin Y E, Park S S. Mater. Chem. Phys., 2018, 207:465-469
16. [16]
  Roy P, Mondal K, Srivastava S K. Cryst. Growth Des., 2008, 8:1530-1534 doi: 10.1021/cg700780k
17. [17]
  JIA Bo, YANG Liu, QU Peng, et al. Bulletin of The Chinese Ceramic Society, 2015, 34(2):454-460
18. [18]
  Luo J, Yu N, Xiao Z Y, et al. J. Alloys Compd., 2015, 648:98-103 doi: 10.1016/j.jallcom.2015.05.220
19. [19]
  Hu H M, Zheng Q, Deng C H, et al. Mater. Chem. Phys., 2015, 154:10-15 doi: 10.1016/j.matchemphys.2014.11.078
20. [20]
  Huang K J, Zhang J Z, Fan Y. J. Alloys Compd., 2015, 625:158-163 doi: 10.1016/j.jallcom.2014.11.137
21. [21]
  Shuai X M, Shen W Z, Li X T, et al. Mater. Sci. Eng. B, 2018, 227:74-79
22. [22]
  Lee Y I. Mater. Chem. Phys., 2016, 180:104-113 doi: 10.1016/j.matchemphys.2016.05.048
23. [23]
  Hu X S, Shen Y, Xu L H, et al. J. Alloys Compd., 2016, 674:289-294 doi: 10.1016/j.jallcom.2016.03.047
24. [24]
  Heydari H, Moosavifard S E, Elyasi S, et al. Appl. Surf. Sci., 2017, 394:425-430
25. [25]
  Shi B, Liu W, Zhu K, et al. Chem. Phys. Lett., 2017, 677:70-74 doi: 10.1016/j.cplett.2017.03.051
26. [26]
  Shu Q W, Li C M, Gao P F. RSC Adv., 2015, 5:17458-17465 doi: 10.1039/C4RA14609C
27. [27]
  Kim W B, Lee S H, Cho M, et al. Sens. Actuators B, 2017, 249:161-167 doi: 10.1016/j.snb.2017.04.089
28. [28]
  WANG Xiang-Yan, WANG Zhi-Qiang, TIAN Han-Min, et al. Chinese J. Inorg. Chem., 2009, 25(11):1893-1897 doi: 10.3321/j.issn:1001-4861.2009.11.001
29. [29]
  YUAN Xiao-Wei, YANG Qian, LIU Qi, et al. Chinese J. Inorg. Chem., 2010, 26(2):285-292
30. [30]
  YI Guan-Gui, XIAO Yong, HE Wei-Qi, et al. Chinese J. Inorg. Chem., 2010, 27(1):162-166
31. [31]
  Luo X L, Li C Y, Yang D S, et al. Mater. Chem. Phys., 2015, 151:252-258 doi: 10.1016/j.matchemphys.2014.11.062
32. [32]
  YAO Xun, LI Ming-Gao, XIE Yan-Chun, et al. Chinese J. Inorg. Chem., 2018, 34(6):1086-1094
33. [33]
  Li S M, Cheng W J, Liu X T, et al. J. Supercrit. Fluids, 2018, 133:429-436 doi: 10.1016/j.supflu.2017.11.007
34. [34]
  Anderson B D, Tracy J B. Nanoscale, 2014, 6:12195-12216
35. [35]
  Zhu H, Wang J, Wu D. Inorg. Chem., 2009, 48:7099-7104 doi: 10.1021/ic900201p
36. [36]
  Wu D X, Duan J F, Zhang C Y, et al. J. Phys. Chem. C, 2013, 117:9121-9128
37. [37]
  Yan C L, Tian Q W, Yang S P. RSC Adv., 2017, 7:37887-37897 doi: 10.1039/C7RA05468H
38. [38]
  Han L, Zhang Y, Chen X W, et al. J. Mater. Chem. B, 2016, 4:105-112
39. [39]
  Han L, Hao Y N, Wei X, et al. ACS Biomater. Sci. Eng., 2017, 12:3230-3235
40. [40]
  Guo L R, Yan D D, Yang D F, et al. ACS Nano, 2014, 8:5670-5681
41. [41]
  Li L H, Rashidi L H, Yao M Y, et al. Photodiagn. Photodyn. Ther., 2017, 19:5-14 doi: 10.1016/j.pdpdt.2017.04.001
42. [42]
  Bruskov V I, Malakhova L V, Masalimov Z K, et al. Nucleic Acids Res., 2002, 30(6):1354-1363
1. [1]
  Zhengzheng LIU , Pengyun ZHANG , Chengri WANG , Shengli HUANG , Guoyu YANG . Synthesis, structure, and electrochemical properties of a sandwich-type {Co₆}-cluster-added germanotungstate. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1173-1179. doi: 10.11862/CJIC.20240039
2. [2]
  Juan CHEN , Guoyu YANG . A porous-layered aluminoborate built by mixed oxoboron clusters and AlO₄ tetrahedra. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 193-200. doi: 10.11862/CJIC.20240341
3. [3]
  Han ZHANG , Jianfeng SUN , Jinsheng LIANG . Hydrothermal synthesis and luminescent properties of broadband near-infrared Na₃CrF₆ phosphor. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 349-356. doi: 10.11862/CJIC.20240098
4. [4]
  Ping LI , Geng TAN , Xin HUANG , Fuxing SUN , Jiangtao JIA , Guangshan ZHU , Jia LIU , Jiyang LI . Green synthesis of metal-organic frameworks with open metal sites for efficient ammonia capture. Chinese Journal of Inorganic Chemistry, 2025, 41(10): 2063-2068. doi: 10.11862/CJIC.20250020
5. [5]
  Zhijia Zhang , Shihao Sun , Yuefang Chen , Yanhao Wei , Mengmeng Zhang , Chunsheng Li , Yan Sun , Shaofei Zhang , Yong Jiang . Epitaxial growth of Cu_2-xSe on Cu (220) crystal plane as high property anode for sodium storage. Chinese Chemical Letters, 2024, 35(7): 108922-. doi: 10.1016/j.cclet.2023.108922
6. [6]
  Ping Wang , Chunmao Chen , Hongwei Ren , Erhong Duan . A review of carbon dots in synthesis strategies, photoluminescence mechanisms, and applications in wastewater treatment. Chinese Chemical Letters, 2025, 36(9): 110725-. doi: 10.1016/j.cclet.2024.110725
7. [7]
  Matvey K. Shurikov , Yuliana A. Kolesnikova , Darya E. Votkina , Pavel A. Abramov , Taisiya S. Sukhikh , Galina V. Romanenko , Sergey L. Veber , Dmitry E. Gorbunov , Nina P. Gritsan , Giuseppe Resnati , Evgeny V. Tretyakov , Vadim Yu. Kukushkin , Pavel S. Postnikov , Pavel V. Petunin . Engineering optical anisotropy in paramagnetic organic crystals: Dichroism of nitronyl nitroxide radicals. Chinese Journal of Structural Chemistry, 2025, 44(9): 100653-100653. doi: 10.1016/j.cjsc.2025.100653
8. [8]
  Zhongjie Song , Nannan Zhang , Jun Yu , Huiyu Sun , Zhengying Wu , Yukou Du . Growth of Ce-doped NiCo-LDHs on tin dioxide-modified nickel foam as oxygen evolution reaction catalyst electrode. Chinese Chemical Letters, 2026, 37(1): 111804-. doi: 10.1016/j.cclet.2025.111804
9. [9]
  Shuaiwen Li , Zihui Chen , Feng Yang , Wanqing Yue . The age of vanadium-based nanozymes: Synthesis, catalytic mechanisms, regulation and biomedical applications. Chinese Chemical Letters, 2024, 35(4): 108793-. doi: 10.1016/j.cclet.2023.108793
10. [10]
  Shengfei Dong , Ziyu Liu , Xiaoyi Yang . Hydrothermal liquefaction of biomass for jet fuel precursors: A review. Chinese Chemical Letters, 2024, 35(8): 109142-. doi: 10.1016/j.cclet.2023.109142
11. [11]
  Mengxiang Zhu , Tao Ding , Yunzhang Li , Yuanjie Peng , Ruiping Liu , Quan Zou , Leilei Yang , Shenglei Sun , Pin Zhou , Guosheng Shi , Dongting Yue . Graphene controlled solid-state growth of oxygen vacancies riched V₂O₅ catalyst to highly activate Fenton-like reaction. Chinese Chemical Letters, 2024, 35(12): 109833-. doi: 10.1016/j.cclet.2024.109833
12. [12]
  Kuanhong Cao , Sainan Chu , Yuanhua Ding , Shanming Lu , Lei Yu , Juan Du . Sustainable Se/C catalysts from carbohydrates: Unlocking oxidative deoximation reaction with high turnover numbers via free radical mechanisms. Chinese Chemical Letters, 2026, 37(1): 111486-. doi: 10.1016/j.cclet.2025.111486
13. [13]
  Pengfei Li , Chulin Qu , Fan Wu , Hu Gao , Chengyan Zhao , Yue Zhao , Zhen Shen . Robust free-base and metalated corrole radicals with reduction-induced emission. Chinese Chemical Letters, 2025, 36(2): 110292-. doi: 10.1016/j.cclet.2024.110292
14. [14]
  Jindan Zhang , Zhenghong Li , Chi Li , Mengqi Zhu , Shicheng Tang , Kaicong Cai , Zhibin Cheng , Chulong Liu , Shengchang Xiang , Zhangjing Zhang . Revealing a new doping mechanism of spiro-OMeTAD with tBP participation through the introduction of radicals into HTM. Chinese Chemical Letters, 2025, 36(3): 110046-. doi: 10.1016/j.cclet.2024.110046
15. [15]
  Xuan Song , Teng Fu , Yajie Yang , Yahan Kuang , Xiuli Wang , Yu-Zhong Wang . Spatial-confinement combustion strategy enabling free radicals chemiluminescence direct-measurement in flame-retardant mechanism. Chinese Chemical Letters, 2025, 36(5): 110699-. doi: 10.1016/j.cclet.2024.110699
16. [16]
  Yusong Bi , Rongzhen Zhang , Kaikai Niu , Shengsheng Yu , Hui Liu , Lingbao Xing . Construction of a three-step sequential energy transfer system with selective enhancement of superoxide anion radicals for photocatalysis. Chinese Chemical Letters, 2025, 36(5): 110311-. doi: 10.1016/j.cclet.2024.110311
17. [17]
  Jingjing Zhang , Fei Yang , Liying Zhang , Ran Li , Guo Wang , Yanqing Xu , Wei Wei . Stable radicals in bacteria composites hybridized by a doubly-strapped perylene diimide for near-infrared photothermal conversion. Chinese Chemical Letters, 2025, 36(7): 110627-. doi: 10.1016/j.cclet.2024.110627
18. [18]
  Ying Zhao , Yao He , Jian-Xin Yang , Wen-Jie Liu , Dan Tian , Francisco Aznarez , Le-Le Gong , Li-Long Dang , Lu-Fang Ma . Controllable self-assembly and photothermal conversion of metalla[2]catenanes induced by synergistic effect of free radicals and stacking interactions. Chinese Chemical Letters, 2025, 36(12): 111460-. doi: 10.1016/j.cclet.2025.111460
19. [19]
  Kebo Xie , Qian Zhang , Fei Ye , Jungui Dai . A multi-enzymatic cascade reaction for the synthesis of bioactive C-oligosaccharides. Chinese Chemical Letters, 2024, 35(6): 109028-. doi: 10.1016/j.cclet.2023.109028
20. [20]
  Liming Li , Yanchang Liu , Peng Kang , Donghui Feng , Yuguang Zhang , Hangxing Ren , Jianrong Zeng , He Zhu , Qiang Li , Xiaoya Cui . Scalable and rapid liquid synthesis of PtNi electrocatalyst for hydrogen evolution reaction. Chinese Chemical Letters, 2026, 37(2): 112022-. doi: 10.1016/j.cclet.2025.112022

Get Citation

PDF

XML

Metrics

PDF Downloads(6)
Abstract views(1857)
HTML views(198)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142