Citation: ZHOU Xin, YE Jing, WANG Zhi-Hua, JIN Su-Rong. Two Inorganic-Organic Hybrid Crystals Based on Polyoxometallates and Imidazole Compounds: Syntheses and Properties[J]. Chinese Journal of Inorganic Chemistry, ;2019, 35(1): 43-49. doi: 10.11862/CJIC.2019.023 shu

Two Inorganic-Organic Hybrid Crystals Based on Polyoxometallates and Imidazole Compounds: Syntheses and Properties

School of Chemistry, Chemical Engineering and Life Sciences, Wuhan University of Technology, Wuhan 430070, China

Corresponding author: JIN Su-Rong, jinsr@163.com
Received Date: 1 March 2018
Revised Date: 20 November 2018

Figures(12)

Two one-dimensional chain polyoxometallic cluster compounds connecting poly-acid anions with organic components benzimidazolyl phenol(bidp) or benzimidazole(bid) by hydrogen bond, electrostatic attraction and π-π stacking have been synthesized at room temperature, which are (Hbidp)₃(PMo₁₂O₄₀)·bidp (1) and (Hbid)₃(PMo₁₂O₄₀)·bid (2), and they have been unequivocally characterized by IR spectroscopy, complete elemental analysis and single crystal X-ray diffraction. The cyclic voltammogran indicted that compounds 1 and 2 have excellent redox properties. The photocatalytic performance of compounds 1 and 2 were investigated with photodegradation of methylene blue (MB) and rhodamine B (RhB) with UV irradiation.
- polyoxometalate,
- organic components,
- crystal structure,
- photocatalytic degradation
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沈阳化工大学材料科学与工程学院沈阳 110142