Citation: LI Xiang, ZHAO Huai-An, SU Jian, CHENG Jun-Yan, WANG Peng. Syntheses, Crystal Structures and Fluorescence Properties of Co(Ⅱ) Coordination Polymers Based on Anion Regulation Strategy[J]. Chinese Journal of Inorganic Chemistry, ;2019, 35(1): 109-115. doi: 10.11862/CJIC.2019.020 shu

Syntheses, Crystal Structures and Fluorescence Properties of Co(Ⅱ) Coordination Polymers Based on Anion Regulation Strategy

LI Xiang ¹ ,
ZHAO Huai-An ¹ ,
SU Jian ² ,
CHENG Jun-Yan ³ ,
WANG Peng ^1,,

1.
College of Chemical and Environmental Engineering, Shandong University of Science and Technology, Qingdao, Shandong 266590, China
2.
State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Collaborative Innovation Center of Advanced Microstructures, Nanjing University, Nanjing 210093, China
3.
College of Chemistry, Chemical Engineering and Materials Science, Shandong Normal University, Jinan 250014, China

Corresponding author: WANG Peng, pengwang@sdust.edu.cn
Received Date: 3 October 2018
Revised Date: 20 November 2018

Figures(8)

Two coordination polymers [Co(L) Cl₂]_n (1) and [Co(L)₂(SCN)₂]_n (2) were obtained by using 4-methyl-2, 6-bis(pyridin-3-ylethynyl) aniline (L) and Co(Ⅱ) salts in CH₂Cl₂/MeOH mixed solvent under room temperature. The complexes 1 and 2 were characterized by IR, elemental analysis and X-ray single crystal diffraction. The structural analysis revealed that complex 1 has 1D chain structure and 2 has 2D plane structure. The reason of the structure difference was anion choice because the L in both of the coordination complexes adopts almost same trans-N, N donor configuration. Complex 1 has four-coordinated Co(Ⅱ)) which coordinated to two L molecules, while complex 2 has six-coordinated Co(Ⅱ) which coordinated to four L molecules. The XRD and fluorescence property of two complexes were investigated. Compared to the emission spectrum of L, the emission maximum of the complex 1 was red shift and 2 was blue shift.
- pyridine ligand,
- anion regulation,
- Co (Ⅱ) coordinate complexes,
- crystal structure
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