Citation: YU Min, XUAN Fang, LIU Guang-Xiang. Syntheses, Crystal Structures and Photoluminescent Properties of Two Zinc(Ⅱ) Coordination Polymers Derived from 4, 4'-((1H-Imidazol-1-yl) methylene) dibenzoic Acid[J]. Chinese Journal of Inorganic Chemistry, ;2019, 35(1): 133-140. doi: 10.11862/CJIC.2019.018 shu

Syntheses, Crystal Structures and Photoluminescent Properties of Two Zinc(Ⅱ) Coordination Polymers Derived from 4, 4'-((1H-Imidazol-1-yl) methylene) dibenzoic Acid

Nanjing Key Laboratory of Advanced Functional Materials, School of Environmental Science, Nanjing Xiaozhuang University, Nanjing 211171, China

Corresponding author: LIU Guang-Xiang, njuliugx@126.com
Received Date: 30 July 2018
Revised Date: 30 October 2018

Figures(10)

Two zinc(Ⅱ) coordination polymers, [Zn(HIMB)₂]_n (1) and {[Zn(IMB)]·1.5H₂O}_n (2), (H₂IMB=4, 4'-((1H-imidazol-1-yl) methylene) dibenzoic acid), have been synthesized and characterized by IR spectroscopy, elemental analyses, thermogravimetric analysis (TGA), powder X-ray diffraction (PXRD), and single-crystal X-ray diffraction. Complex 1 crystallizes in orthorhombic, space group C222₁ with a=0.935 2(3) nm, b=2.583 3(8) nm, c=1.396 4(4) nm, V=3.373 6(18) nm³, M_r=707.98, D_c=1.394 g·cm^-3, F(000)=1 456, μ=0.786 mm^-1 and Z=4. The final R₁=0.048 6 and wR₂=0.120 1 for 2 794 observed reflections when I>2σ(I). Complex 2 belongs to tetragonal, space group I4₁/acd with a=1.853 5(2) nm, b=1.853 5(2) nm, c=4.309 7(5) nm, V=14.806 (4) nm³, M_r=412.69, D_c=1.481 g·cm^-3, F(000)=6 752, μ=0.136 0 mm^-1 and Z=32. The final R₁=0.043 7 and wR₂=0.117 1 for 3 615 observed reflections when I>2σ(I). Structural analyses reveal that complex 1 shows a 2D→2D polycatenane of 2-fold interpenetrated sql layer, whereas complex 2 possesses a 3D 2-fold interpenetrated (3, 6)-connected net with the point symbol of (6¹¹.8⁴)(6³)₂. The results show that the solvent plays a significant role in the structure of the final products.
- zinc (Ⅱ) coordination polymer,
- bifunctional ligand,
- crystal structure,
- luminescence
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