Citation: RONG Jie-Wei, ZHANG Wen-Wei. Syntheses, Structures and Photoluminescent Properties of Metal-Organic Frameworks Based on Triangle Flexible Multi-Carboxylic Ligand[J]. Chinese Journal of Inorganic Chemistry, ;2018, 34(12): 2307-2315. doi: 10.11862/CJIC.2018.281 shu

Syntheses, Structures and Photoluminescent Properties of Metal-Organic Frameworks Based on Triangle Flexible Multi-Carboxylic Ligand

RONG Jie-Wei ^1,2 ,
ZHANG Wen-Wei ^2,,

1.
School of Chemical and Materials Engineering, Huainan Normal University, Huainan, Anhui 232038, China
2.
State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210023, China

Corresponding author: ZHANG Wen-Wei, wwzhang@nju.edu.cn
Received Date: 30 August 2018
Revised Date: 23 October 2018

Figures(7)

Two novel metal-organic frameworks {[Zn₃(TCPB)₂(4, 4'-BPY)]·DMF·3H₂O}_n (1) with trinuclear zinc cluster units and {[Co_1.5(TCPB)(DMF)(H₂O)]·DMF}_n (2) with trinuclear cobalt cluster SBUs, have been prepared under solvothermal conditions based on flexible 1, 3, 5-tri(4-carboxyphenoxy) benzene ligand (H₃TCPB) with the help of ancillary bridging N-donor pyridyl linker 4, 4'-bipyridine (4, 4'-BPY), and characterized by single crystal X-ray diffraction, IR spectra, elemental analyses, thermogravimetric analyses (TGA) and powder X-ray diffraction (PXRD). The single crystal X-ray diffraction analysis reveals that complex 1 crystallizes in triclinic space group P1 and exhibits three-dimensional (3D) (3, 8)-connected network with Schläfli symbol of {4³}₂·{4⁶·6¹⁸·8⁴}·{6}, complex 2 also belongs to the triclinic system with space group of P1 and shows two-dimensional (2D) (3, 6)-connected net-like layered framework with Schläfli symbol of {4³}₄·{4⁶·6¹⁸·8⁴}. In addition, the study of the solid state photoluminescent property of complex 1 indicates that it emits light blue fluorescence arising from TCPB^3- and 4, 4'-BPY ligands at room temperature, while complex 2 is non-emissive under similar conditions.
- flexible carboxylic ligand,
- metal-organic framework,
- crystal structure,
- photoluminescence
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