Citation: PENG Yan-Fen, LIU Tian-Bao, WU Qiu-Yan, YAO Guo-Jian, XU Dong-Dong. Syntheses, Structures of Three Zn(Ⅱ) Coordination Polymers Based on Flexible 4-Substituted Bis(1, 2, 4-triazole) Ligand[J]. Chinese Journal of Inorganic Chemistry, ;2018, 34(12): 2245-2253. doi: 10.11862/CJIC.2018.280 shu

Syntheses, Structures of Three Zn(Ⅱ) Coordination Polymers Based on Flexible 4-Substituted Bis(1, 2, 4-triazole) Ligand

College of Chemical and Material Engineering, Chizhou University, Chizhou, Anhui 247000, China

Corresponding author: PENG Yan-Fen, pengyanfen1978@126.com
Received Date: 11 June 2018
Revised Date: 23 October 2018

Figures(7)

Three new coordination polymers, {[Zn(μ₂-btre)(μ₂-adc)]·H₂O}_n (1·H₂O), [Zn₂(μ₂-btre)(μ₂-1, 4-bdc)₂(H₂O)₂]_n (2) and[Zn(μ₂-btre)(μ₂-1, 2-bdc)]_n (3) were synthesized at room temperature condition and characterized by IR spectra, elemental analyses, single-crystal and powder X-ray diffractions (btre=1, 2-bis(1, 2, 4-triazol-4-yl) ethane, adc=1, 3-adamantanedicarboxylate, 1, 4-bdc=1, 4-benzenedicarboxylate, 1, 2-bdc=1, 2-benzenedicarboxylate). Structural analyses reveal that complex 1 exhibits a 2D (4, 4) network, and the adjacent 2D (4, 4) networks are connected into 3D network by strong π-π interactions. The structure of 2 and 3 are 3D and 2D (4, 4) network, respectively. Thermal stabilities and the solid-state luminescence at room temperature of 1, 2 and 3 were investigated.
- 1, 2-bis (1, 2, 4-triazol-4-yl) ethane,
- π-π interaction,
- (4, 4) network,
- luminescence
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