Citation: YAN Jing-Sen, AI Li-Mei, WANG Qiang, WANG Ze-Qing, E Yong-Sheng, LIU Hai-Bin. Synthesis, Characterization and Esterification Application of Acid-Functionalized Ternary Heteropolyanion-Based Ionic Liquids with Temperature-Responsive Behaviour[J]. Chinese Journal of Inorganic Chemistry, ;2018, 34(12): 2179-2187. doi: 10.11862/CJIC.2018.272 shu

Synthesis, Characterization and Esterification Application of Acid-Functionalized Ternary Heteropolyanion-Based Ionic Liquids with Temperature-Responsive Behaviour

School of Biomedical & Chemical Engineering, Liaoning Institute of Science and Technology, Benxi, Liaoning 117004, China

Corresponding author: YAN Jing-Sen, yanjs910@163.com
Received Date: 13 August 2018
Revised Date: 28 September 2018

Figures(6)

A series of vanadium-substituted ternary heteropoly acids with Keggin structure were synthesized by acidification-ether extraction method. Furthermore, the heteropolyanion-based ionic liquids with functional sulfonic acid group, [PyPs]_3+nPW_12-nV_nO₄₀ (n=1, 2, 3), were synthesized by an ion exchange method. The products were characterized by nuclear magnetic resonance spectroscopy (NMR), element analysis, Fourier transform infrared spectrophotometry (FT-IR), UV-Vis spectrophotometry, X-ray diffraction (XRD), thermogravimetry-differential scanning calorimetry (TG-DSC) and potentiometric titration measurements. The catalytic ability and reusability of the ionic liquid catalysts were evaluated in esterification reaction of chloroacetic acid with n-pentyl alcohol. The results show that the ionic liquid catalyst was an amorphous structural compound with temperature responsive characteristics, in which Keggin structure and high acid strength of ionic liquid catalyst remain. The catalyst formed a homogeneous mixture with the reactants at the reaction temperature, but precipitated with biphase separation when the reaction ends and reaction temperature was lowered, and so could be easily separated from the products by a simple filtration. Sulfonic acid functionalized heteropolyanion-based ionic liquids exhibited higher ester catalytic activity than heteropoly acids and unsulfonated heteropolyanion-based ionic liquids. Under the optimized reaction conditions, the conversion rate of[PyPS]₄PW₁₁VO₄₀ (PyPS is 1-(3-sulfonate) propyl pyridine) to chloroacetic acid could reach 97.6%, and the conversion rate was 91.9% after repeated reaction four times, but the structure of the catalyst had no change significantly.
- catalysis,
- esterification,
- heteropoly acid,
- temperature-responsive ionic liquid,
- synthesis,
- characterization
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