Citation: MO Yi-Jie, GUO Rui-Hua, AN Sheng-Li, GUO Le-Le, ZHANG Jie-Yu, ZHOU Guo-Zhi. High Specific Area Cerium Oxide: Synthesis and Effect on Catalytic Performance of Pt-Based Catalysts[J]. Chinese Journal of Inorganic Chemistry, ;2018, 34(11): 1991-1999. doi: 10.11862/CJIC.2018.247 shu

High Specific Area Cerium Oxide: Synthesis and Effect on Catalytic Performance of Pt-Based Catalysts

MO Yi-Jie ^1,2 ,
GUO Rui-Hua ^1,2,3,, ,
AN Sheng-Li ^1,2 ,
GUO Le-Le ^1,2 ,
ZHANG Jie-Yu ³ ,
ZHOU Guo-Zhi ³

1.
School of Material and Metallurgy, Inner Mongolia University of Science & Technology, Baotou, Inner Mongolia 014010, China
2.
Inner Mongolia Key Laboratory of Advanced Ceramic Materials and Devices, Baotou, Inner Mongolia 014010, China
3.
College of Materials Science and Engineering, Shanghai University, Shanghai 200072, China

Corresponding author: GUO Rui-Hua, grh7810@163.com
Received Date: 24 June 2018
Revised Date: 15 August 2018

Figures(11)

A broom-like CeO₂ with a specific surface area of 175 m²·g^-1 and a pore size of 2~4 nm was synthesized by hydrothermal method. The Pt-CeO₂/RGO catalyst was prepared by the microwave-assisted ethylene glycol reduction chloroplatinic acid method, and the effect of the addition of broom-like CeO₂ on the electrocatalytic performance of Pt-based catalysts was investigated. The prepared CeO₂ and catalyst were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), N₂ adsorption-desorption, and X-ray photoelectron spectroscopy (XPS). The electrochemical performance of catalysts was tested by electrochemical workstation. The results showed that the CeO₂ in the catalyst remains in the form of a broom, and the Pt nanoparticles are evenly distributed on the surface of graphene carrier. When the mass ratio of RGO to CeO₂(m_RGO:m_CeO₂) is 1:2, the electrocatalytic performance of the Pt-CeO₂/RGO catalyst with broom-like CeO₂ is the best, the electrochemical active surface area was 102.83 m²·g^-1, the peak current density of ethanol oxidation was 757.17 A·g^-1, the steady-state current density of 1 000 s was 108.17 A·g^-1, the charge transfer resistance of the catalytic oxidation reaction of ethanol is the smallest and the activation energy is the lowest.
- direct ethanol fuel cell,
- anode catalyst,
- broom-like CeO₂,
- catalytic performance,
- stability
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