Citation: CHEN Qi, XU Bing-Jie, XU Bao-Song, LIU Peng-Fei, HAN Zhao, QIU Ben. Effects of Hydroxyl Groups on Dispersibility of Silicon Nitride Powder in Aqueous Media[J]. Chinese Journal of Inorganic Chemistry, ;2018, 34(11): 2073-2080. doi: 10.11862/CJIC.2018.244 shu

Effects of Hydroxyl Groups on Dispersibility of Silicon Nitride Powder in Aqueous Media

CHEN Qi ¹ ,
XU Bing-Jie ¹ ,
XU Bao-Song ¹ ,
LIU Peng-Fei ¹ ,
HAN Zhao ^1,2,, ,
QIU Ben ¹

1.
School of Metallurgical Engineering, Anhui University of Technology, Ma'anshan, Anhui 243002, China
2.
Key Laboratory of Metallurgical Emission Reduction & Resources Recycling, Ministry of Education, Ma'anshan, Anhui 243002, China

Corresponding author: HAN Zhao, authanzhao@foxmail.com
Received Date: 4 July 2018
Revised Date: 10 August 2018

Figures(9)

The surface of silicon nitride (Si₃N₄) powder was efficiently hydroxylated via application of nitric acid to improve dispersibility in aqueous media.Hydroxylated powder results in more stable colloidal dispersion in aqueous media compared to native powder.Results of Fourier transform infrared spectroscopy and X-ray photoelectron spectroscopy show that hydroxyl group content of Si₃N₄ powder significantly increased with hydroxyl modification.This is helpful in preventing Si₃N₄ powder from aggregating in aqueous media.In addition, thermogravimetric analysis indicates that hydroxyl group content of hydroxylated Si₃N₄ powder was 68.8% higher than that of native powder.Furthermore, surface hydrophilicity of Si₃N₄ powder is enhanced with hydroxyl modification, and powder dispersibility is improved with an increase in hydroxyl content.
- silicon nitride,
- hydroxylation,
- surface modification,
- dispersibility
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