Citation: ZHANG Hai-Xia, HAN Wang-Kang, ZHANG Feng-Li, HE Wei, GE Fang-Yuan, WANG Ya-Qin, YAN Xiao-Dong, GU Zhi-Guo. Halide Triggered Spin State Switching of Iron(Ⅱ) Tetrahedral Cages[J]. Chinese Journal of Inorganic Chemistry, ;2018, 34(11): 2063-2072. doi: 10.11862/CJIC.2018.233 shu

Halide Triggered Spin State Switching of Iron(Ⅱ) Tetrahedral Cages

1.
Key Laboratory of Synthetic and Biological Colloids, Ministry of Education, School of Chemical and Material Engineering, Jiangnan University, Wuxi, Jiangsu 214122, China
2.
International Joint Research Center for Photoresponsive Molecules and Materials, School of Chemical and Material Engineering, Jiangnan University, Wuxi, Jiangsu 214122, China

Corresponding author: GU Zhi-Guo, zhiguogu@jiangnan.edu.cn
Received Date: 22 June 2018
Revised Date: 18 July 2018

Figures(6)

Three iron(Ⅱ) tetrahedral cages 1~3 with solid state spin-crossover properties were rational constructed.Single crystal X-ray diffraction analysis confirmed the edge-capped capsule, which were assembled from six imidazole Schiff-base ligands and four iron(Ⅱ) ions.The metal centers occupy the vertices and each linker situates at the edges of the tetrahedron.The inner cavities of these cages are surrounded by imidazole groups, while the periphery is decorated by substituted phenyl rings.One of the counter anions is encapsulated at the central cavities and shows strong anion binding interactions with the cages.Interestingly, the iron(Ⅱ) cages in solution can change their spin states from low-spin (LS) to high-spin (HS) upon addition of halide, since tremendous change of solution color and absorption intensity of characteristic broad absorption MLCT bands when addition of halide (Cl^- and Br^-) to the CH₃CN solution of the cages.
- metal-organic cage,
- spin-crossover,
- halide,
- host-guest,
- spin state switching
1. [1]
2. [2]
  (a) Khusniyarov M M.Chem. Eur. J., 2016, 22: 15178-15191
  (b)Guionneau P.Dalton. Trans., 2014, 43: 382-393
  (c)Kahn O, Martinez C J.Scienc., 1998, 279: 44-48
  (d)Rosner B, Milek M, Witt A, et al.Angew. Chem. Int. Ed., 2015, 54: 12976-12980
  (e)Zenere K A, Duyker S G, Trzop E, et al.Chem. Sci., 2018, 9(25): 5623-5629
3. [3]
  (a) Samanta S, Demesko S, Dechert S, et al.Angew. Chem. Int. Ed., 2015, 54: 583-587
  (b)Dommaschk M, Schutt C, Venkataramani S, et al.Dalton. Trans., 2014, 43: 17395-17405
4. [4]
  (a) Shores M P, Klug C M, Fiedler S R.Spin-Crossover Materials: Properties and Applications. Halcrow M A Ed., Oxford: Wiley-Blackwel., 2013: 281-301
  (b)Weber B, Walker F A.Inorg. Chem., 2007, 46: 6794-6803
5. [5]
  (a) Hasegawa Y, Kume S, Nishihara H.Dalton. Trans., 2009, 2: 280-284
  (b)Heitmann G, Schütt C, Herges R.Eur. J. Org. Chem., 2016, 22: 3817-3823
  (c)Venkataramani S, Jana U, Dommaschk M, et al.Scienc., 2011, 331: 445-448
  (d)Thies S, Sell H, Schütt C, et al.J. Am. Chem. Soc., 2011, 133: 16243-16250
6. [6]
  (a) Schmitz M, Seibel M, Kelm H, et al.Angew. Chem. Int. Ed., 2014, 53: 5988-5992
  (b)Wilson R K, Brooker S.Dalton. Trans., 2013, 42: 12075-12078
  (c)Miller J S, Min K S.Angew. Chem. Int. Ed., 2009, 48: 262-272
7. [7]
  (a) Young M C, Liew E, Ashby J, et al.Chem. Commun., 2013, 49: 6331-6333
  (b)Ono K, Yoshizawa M, Akita M, et al.J. Am. Chem. Soc., 2009, 131: 2782-2783
  (c)Ni Z, Shores M P.J. Am. Chem. Soc., 2009, 131: 32-33
  (d)Ni Z, McDaniel A M, Shores M P.Chem. Sci., 2010, 1: 615-621
  (e)Ni Z, Shores M P.Inorg. Chem., 2010, 49: 10727-10735
8. [8]
  (a) Rissanen K.Chem. Soc. Rev., 2017, 46: 2638-2648
  (b)Zarra S, Wood D M, Roberts D A, et al.Chem. Soc. Rev., 2015, 44: 419-432
  (c)Ahmad N, Younus HA, Chughtai A H, et al.Chem. Soc. Rev., 2015, 44: 9-25
  (d)Ramsay W J, Ronson T K, Clegg J K, et al.Angew. Chem. Int. Ed., 2013, 52: 13439-13443
  (e)Ward M D, Hunter C A, Williams N H.Chem. Lett., 2017, 46: 2-9
  (f)Metherell A J, Cullen W, Williams N H, et al.Chem. Eur. J., 2018, 24: 1554-1560
9. [9]
  (a) Struch N, Bannwarth C, Ronson T K, et al.Angew. Chem. Int. Ed., 2017, 56: 4930-4935
  (b)Bilbeisi R A, Zarra S, Feltham H L, et al.Chem. Eur. J., 2013, 19: 8058-8062
10. [10]
  (a) Ren D H, Qiu D, Pang C Y, et al.Chem. Commun., 2015, 51: 788-791
  (b)Zhang F L, Chen Q J, Qin L F, et al.Chem. Commun., 2016, 52: 4796-4799
11. [11]
  SAINT-Plus, Version 6.02, Bruker Analytical X-ray System, Madison, WI, 1999.
12. [12]
  Sheldrick G M.SADABS, Bruker Analytical X-ray Systems, Madison, WI, 1996.
13. [13]
  Sheldrick G M.SHELXTL-97, University of G?ttingen, G?ttingen, Germany, 1997.
14. [14]
  van der Sluis P, Spek A L. Acta Crystallogr. Sect. A:Found. Crystallogr., 1990, A46:194-201
15. [15]
  Spek A L. Acta Crystallogr. Sect. D:Biol. Crystallogr., 2009, D65:148-155
16. [16]
  Brooker S. Chem. Soc. Rev., 2015, 44:2880-2892 doi: 10.1039/C4CS00376D
17. [17]
  Paul R L, Argent S P, Jeffery J C, et al. Dalton. Trans., 2004, 21:3453-3458
18. [18]
  (a) Vostrikova K E, Luneau D, Wemsdorfer W, et al.J. Am. Chem. Soc., 2000, 122: 718-719
  (b)Liu Y C, Hua S A, Cheng M C, et al.Chem. Eur. J., DOI: 10.1002/chem.201801325
19. [19]
  (a) Luo Y H, Nihei M, Wen G J, et al.Inorg. Chem., 2016, 55: 8147-8152
  (b)Nemec I, Herchel R, Travnicek Z.Dalton. Trans., 2015, 44: 4474-4484
20. [20]
  Darawsheh M, Barrios L A, Roubeau O, et al. Chem. Eur. J., 2016, 22:8635-8645 doi: 10.1002/chem.v22.25
21. [21]
  Mooibroek T J, Gamez P. CrystEngComm, 2013, 15:1802-1805 doi: 10.1039/c2ce26853a
1. [1]
  Qiaojia GUO , Junkai CAI , Chunying DUAN . Effects of anions on the structural regulation of Zn-salen-modified metal-organic cage. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2203-2211. doi: 10.11862/CJIC.20240209
2. [2]
  Shengyong Liu , Hui Li , Wei Zhang , Yan Zhang , Yan Dong , Wei Tian . Multiple host-guest and metal coordination interactions induce supramolecular assembly and structural transition. Chinese Chemical Letters, 2025, 36(6): 110465-. doi: 10.1016/j.cclet.2024.110465
3. [3]
  Xian-Fa Jiang , Chongyun Shao , Zhongwen Ouyang , Zhao-Bo Hu , Zhenxing Wang , You Song . Generating electron spin qubit in metal-organic frameworks via spontaneous hydrolysis. Chinese Chemical Letters, 2024, 35(7): 109011-. doi: 10.1016/j.cclet.2023.109011
4. [4]
  Yinglian LI , Chengcheng ZHANG , Xinyu ZHANG , Xinyi WANG . Spin crossover in [Co(pytpy)₂]²⁺ complexes modified by organosulfonate anions. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1162-1172. doi: 10.11862/CJIC.20240087
5. [5]
  Shuai Liang , Wen-Jing Jiang , Ji-Xiang Hu . Achieving colossal anisotropic thermal expansion via synergism of spin crossover and rhombus deformation. Chinese Journal of Structural Chemistry, 2025, 44(2): 100430-100430. doi: 10.1016/j.cjsc.2024.100430
6. [6]
  Jie Yang , Xin-Yue Lou , Dihua Dai , Jingwei Shi , Ying-Wei Yang . Desymmetrized pillar[8]arenes: High-yield synthesis, functionalization, and host-guest chemistry. Chinese Chemical Letters, 2025, 36(1): 109818-. doi: 10.1016/j.cclet.2024.109818
7. [7]
  Jianmei Guo , Yupeng Zhao , Lei Ma , Yongtao Wang . Ultra-long room temperature phosphorescence, intrinsic mechanisms and application based on host-guest doping systems. Chinese Journal of Structural Chemistry, 2024, 43(9): 100335-100335. doi: 10.1016/j.cjsc.2024.100335
8. [8]
  Cheng He , Renlan Huang , Lingling Wei , Qiuhui He , Jinbo Liu , Jiao Chen , Ge Gao , Cheng Yang , Wanhua Wu . Uncovering the mask of sensitizers to switch on the TTA-UC emission by supramolecular host-guest complexation. Chinese Chemical Letters, 2025, 36(4): 110103-. doi: 10.1016/j.cclet.2024.110103
9. [9]
  Xiuwen Xu , Quan Zhou , Yacong Wang , Yunjie He , Qiang Wang , Yuan Wang , Bing Chen . Expanding the toolbox of metal-free organic halide perovskite for X-ray detection. Chinese Chemical Letters, 2024, 35(9): 109272-. doi: 10.1016/j.cclet.2023.109272
10. [10]
  Jinjin Yang , Chuanhui Zhu , Shuang Zhao , Tao Xia , Pengfei Tan , Yutian Zhang , Mei-Huan Zhao , Yijie Zeng , Man-Rong Li . Spin-orbit-controlled metal-insulator transition in metastable SrIrO₃ stabilized by physical and chemical pressures. Chinese Chemical Letters, 2025, 36(6): 109891-. doi: 10.1016/j.cclet.2024.109891
11. [11]
  Ran Zhu , Pan Zhang , Yitong Xu , Jiutong Ma , Qiong Jia . Design of host-guest interaction based molecularly imprinted polymers: Targeting recognition of the epitope of neuron-specific enolase via a SERS assay. Chinese Chemical Letters, 2025, 36(6): 110259-. doi: 10.1016/j.cclet.2024.110259
12. [12]
  Zhao-Xia Lian , Xue-Zhi Wang , Chuang-Wei Zhou , Jiayu Li , Ming-De Li , Xiao-Ping Zhou , Dan Li . Producing circularly polarized luminescence by radiative energy transfer from achiral metal-organic cage to chiral organic molecules. Chinese Chemical Letters, 2024, 35(8): 109063-. doi: 10.1016/j.cclet.2023.109063
13. [13]
  Mufan Cao , Long Pan , Yaping Wang , Xianwei Sui , Xiong Xiong Liu , Shengfa Feng , Pengcheng Yuan , Min Gao , Jiacheng Liu , Song-Zhu Kure-Chu , Takehiko Hihara , Yang Zhou , Zheng-Ming Sun . Mechanical-durable and humidity-resistant dry-processed halide solid-state electrolyte films for all-solid-state battery. Chinese Chemical Letters, 2025, 36(6): 110391-. doi: 10.1016/j.cclet.2024.110391
14. [14]
  Shu-Ran Xu , Fang-Xing Xiao . Metal halide perovskites quantum dots: Synthesis, and modification strategies for solar CO2 conversion. Chinese Journal of Structural Chemistry, 2023, 42(12): 100173-100173. doi: 10.1016/j.cjsc.2023.100173
15. [15]
  Jiajing Wu , Ru-Ling Tang , Sheng-Ping Guo . Three types of promising functional building units for designing metal halide nonlinear optical crystals. Chinese Journal of Structural Chemistry, 2024, 43(6): 100291-100291. doi: 10.1016/j.cjsc.2024.100291
16. [16]
  Jiayuan Liang , Xin Mi , Songhao Guo , Hui Luo , Kejun Bu , Tonghuan Fu , Menglin Duan , Yang Wang , Qingyang Hu , Rengen Xiong , Peng Qin , Fuqiang Huang , Xujie Lü . Pressure-induced emission in 0D metal halide (EATMP)SbBr5 by regulating exciton-phonon coupling. Chinese Journal of Structural Chemistry, 2024, 43(7): 100333-100333. doi: 10.1016/j.cjsc.2024.100333
17. [17]
  Yujuan Zhou , Kecheng Jie . Conformationally adaptive metal–organic cages for dynamic guest encapsulation. Chinese Chemical Letters, 2025, 36(6): 111007-. doi: 10.1016/j.cclet.2025.111007
18. [18]
  Ruotong Wei , Aokun Liu , Jian Kuang , Zhiwen Wang , Lu Yu , Changlin Tian . Probing the dynamic properties in the LLPS process via site-directed spin labeling-electron paramagnetic resonance (SDSL-EPR) spectroscopy. Chinese Chemical Letters, 2025, 36(4): 110029-. doi: 10.1016/j.cclet.2024.110029
19. [19]
  Ze Liu , Xiaochen Zhang , Jinlong Luo , Yingjian Yu . Application of metal-organic frameworks to the anode interface in metal batteries. Chinese Chemical Letters, 2024, 35(11): 109500-. doi: 10.1016/j.cclet.2024.109500
20. [20]
  Ying Li , Yanjun Xu , Xingqi Han , Di Han , Xuesong Wu , Xinlong Wang , Zhongmin Su . A new metal–organic rotaxane framework for enhanced ion conductivity of solid-state electrolyte in lithium-metal batteries. Chinese Chemical Letters, 2024, 35(9): 109189-. doi: 10.1016/j.cclet.2023.109189

Get Citation

PDF

XML

Metrics

PDF Downloads(1)
Abstract views(474)
HTML views(71)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142