Citation: SHI Zhong-Xiang, LU Yang, WANG Jing, GUAN Xin, SHI Jun, JIANG Hao. Preparation and Upconversion Luminescence Properties of Er³⁺/Yb³⁺ Co-doped NaY(WO₄)₂ Phosphors[J]. Chinese Journal of Inorganic Chemistry, ;2018, 34(11): 1975-1982. doi: 10.11862/CJIC.2018.229 shu

Preparation and Upconversion Luminescence Properties of Er³⁺/Yb³⁺ Co-doped NaY(WO₄)₂ Phosphors

SHI Zhong-Xiang ¹ ,
LU Yang ^2,, ,
WANG Jing ^1,, ,
GUAN Xin ³ ,
SHI Jun ¹ ,
JIANG Hao ¹

1.
Liaoning Key Laboratory for Fabrication and Application of Superfine Inorganic Powders, Dalian Jiaotong University, Dalian, Liaoning 116028, China
2.
Department of Chemical Engineering, Yingkou Institude of Technology, Yingkou, Liaoning 115014, China
3.
Department of chemical engineering, Chengde Petroleum College, Chengde, Hebei 067000, China

Corresponding author: LU Yang, 344465621@qq.com WANG Jing, wangjing@djtu.edu.cn
Received Date: 13 June 2018
Revised Date: 14 July 2018

Figures(8)

NaY(WO₄)₂ microparticles with tetragonal scheelite structure and Er³⁺/Yb³⁺ co-doped NaY(WO₄)₂ phosphors were synthesized by traditional hydrothermal method. The crystal structure, morphology and up-conversion luminescence properties of the samples were discussed detailedly via XRD, SEM, TEM, HRTEM, particle size distribution and up-conversion luminescence spectrum. The results indicated that the pH values played an important role in the synthesis of pure phase NaY(WO₄)₂ microparticles with regular morphology. As pH value increased, the morphology of the samples could generate a transition from octahedrons, quasi-cubes to plate particles and a possible morphological formation mechanism of NaY(WO₄)₂ was proposed. Er³⁺/Yb³⁺ co-doped NaY(WO₄)₂ samples show strong green (²H_11/2→⁴I_15/2 (525 nm) and ⁴S_3/2→⁴I_15/2 (553 nm) of Er³⁺) and weak red (650~680 nm:⁴F_9/2→⁴I_15/2 of Er³⁺) up-conversion emission under 980 nm laser diode excitation, and the two-photon process was confirmed to be responsible for the green and red up-conversion emissions. Moreover, by adjusting the doping concentration of Yb³⁺ in NaY(WO₄)₂:Er³⁺, Yb³⁺ phosphors, the color-tunable and high-purity green were exhibited by the CIE color coordinates of NaY(WO₄)₂:Er³⁺, Yb³⁺ phosphors.
- NaY(WO₄)₂,
- hydrothermal method,
- Er, Yb co-doped,
- up-conversion luminescence properties,
- two-photon process
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Preparation and Upconversion Luminescence Properties of Er3+/Yb3+ Co-doped NaY(WO4)2 Phosphors

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Preparation and Upconversion Luminescence Properties of Er³⁺/Yb³⁺ Co-doped NaY(WO₄)₂ Phosphors