Citation: LI Jian, SU Fei-Fei, GUO Rong, LIANG Zu-Pei, MA Shu-Lan. Photoluminescence and Detection of Hg(Ⅱ) Ions of Layered Yttrium Hydroxide Composite with Fluorescein[J]. Chinese Journal of Inorganic Chemistry, ;2018, 34(10): 1826-1832. doi: 10.11862/CJIC.2018.226 shu

Photoluminescence and Detection of Hg(Ⅱ) Ions of Layered Yttrium Hydroxide Composite with Fluorescein

LI Jian ¹ ,
SU Fei-Fei ² ,
GUO Rong ² ,
LIANG Zu-Pei ^1,, ,
MA Shu-Lan ^2,,

1.
Chemistry & Chemical and Environmental Engineering College, Weifang University, Weifang, Shandong 261061, China
2.
College of Chemistry, Beijing Normal University, Beijing 100875, China

Corresponding author: LIANG Zu-Pei, zupeiliang@163.com MA Shu-Lan, mashulan@bnu.edu.cn
Received Date: 17 May 2018
Revised Date: 28 June 2018

Figures(10)

The layered yttrium hydroxide (LYH) composite (FN/OS-LYH, where FN is fluorescein, 2-(6-hydroxy-3-oxo-(3H)-xanthen-9-yl)benzoic acid, and OS is the anionic surfactant of 1-octane sulfonic acid sodium) is synthesized. The photoluminescence property of the FN/OS-LYH and the application on detection of Hg(Ⅱ) ions of the delaminated FN/OS-LYH is studied. In solid state, pure FN salt shows no any emission, while the FN/OS-LYH composite displays yellow-green emission at 564 nm, and at delaminated state in formamide (FM), it displays a green emission at 540 nm (with 24 nm blue shift), in contrast to the 572 nm emission of free FN anions with a 32 nm blue shift. The delaminated FN/OS-LYH colloidal suspension exhibits high selectivity for Hg²⁺ over other ions (Mg²⁺, Ni²⁺, Co²⁺, Cu²⁺, Zn²⁺, Pb²⁺, and Cd²⁺) with fluorescence quenching. The detection limit of Hg²⁺ is determined to be 2.73×10^-7 mol·L^-1 and the quenching constant (K_sv) is 4.82×10² L·mol^-1.
- LRH composite,
- luminescence,
- delamination,
- ion detection,
- fluorescence recognition
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