Citation: MENG Yue, XIA Sheng-Jie, XUE Ji-Long, NI Sheng-Liang, NI Zhe-Ming. Synthesis and Photocatalytic Degradation Performance for Rhodamin B of Zn-Cr-Cu Composite Metal Oxides Derived from Layered Double Hydroxides[J]. Chinese Journal of Inorganic Chemistry, ;2018, 34(9): 1632-1640. doi: 10.11862/CJIC.2018.208 shu

Synthesis and Photocatalytic Degradation Performance for Rhodamin B of Zn-Cr-Cu Composite Metal Oxides Derived from Layered Double Hydroxides

1.
School of Life Sciences, Huzhou University, Huzhou, Zhejiang 313000, China
2.
College of Chemical Engineering, Zhejiang University of Technology, Hangzhou 310014, China

Corresponding author: XIA Sheng-Jie, xiasj@zjut.edu.cn NI Zhe-Ming, jchx@zjut.edu.cn
Received Date: 3 May 2018
Revised Date: 12 June 2018

Figures(13)

Novel complexes of Copper(Ⅱ) with Schiff-base intercalated zinc-chromium layered double hydroxides (ZnCr-SBCu-LDHs) were successfully prepared via coprecipitation. Zn-Cr-Cu composite metal oxides (ZnCr-SBCu-LDO) as an original photocatalytic material was derived from ZnCr-SBCu-LDHs after calcination at 500℃. The structure and properties of the photocatalytic materials were thoroughly characterized by powder X-ray diffraction (XRD), ultraviolet visible diffuse reflectance spectroscopy (UV-Vis DRS), scanning electron microscopy (SEM) and inductively coupled plasma-atomic emission spectrometry (ICP-AES). The activities of the photocata-lytic materials were investigated by photodegradation of cationic dye rhodamin B (RhB) which was hard to adsorb by LDHs. The effects of initial photocatalyst amount, initial pH, temperature of RhB solution and initial concentration of H₂O₂ on the photocatalytic efficiency were discussed. The results show that ZnCr-SBCu-LDO display higher photocatalytic activity for RhB degradation. The degradation efficiency of RhB solution (5 mg·L^-1) with ZnCr-SBCu-LDO (1 g·L^-1) reached 98.68% after 4 h irradiation, when the temperature was 25℃, the initial pH value was 7.40 and the initial concentration of H₂O₂ was 10 mmol·L^-1. In addition, the regeneration of the catalyst was studied and the mechanism of photocatalysis was preliminarily discussed.
- Cu(Ⅱ) schiff base complex,
- layered double hydroxides,
- composite metal oxides,
- photocatalysis,
- heterogeneous catalysis,
- rhodamin B,
- degradation mechanism
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